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HomeJournal of Biomimetics, Biomaterials and...Journal of Biomimetics, Biomaterials and...Effect of Citrate and Hexadecyltrimethylammonium...

Effect of Citrate and Hexadecyltrimethylammonium Bromide on the Formation of Hydroxyapatite Crystal in a Thermal Aqueous Solution

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Abstract:

To calrify the combined effect of soft template and biominormolecule on the formation of hydroxyapatite (HAp), the study on the growth of HAp regulated by citrate and(or) hexadecyltrimethylammonium bromide (CTAB) solution was developed in a thermal aqueous. The as-obtained products were characterized by XRD, FT-IR and TEM, altogether with HRTEM and ED. Plate-like HAp crystals in nanosize with relative weak crystallinity were obtained in the presence of citrate. Nano-needle shape HAp crystals were produced in the presence of CTAB. Rod-like HAp crystals in a uniform nanosize were formed under the regulation of CTAB and citrate, which showed the same orientation as that of CTAB only. However, the possible mechanism of the growth of HAp was discussed in detail. CTAB micelles worked as a soft template modified by citrate, which guided to form HAp crystals in different morphology. The study is benefit to control the formation of HAp for its bioapplication.

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Journal of Biomimetics, Biomaterials and Biomedical Engineering Vol. 22

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Periodical:

Journal of Biomimetics, Biomaterials and Biomedical Engineering (Volume 22)

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51-61

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https://doi.org/10.4028/www.scientific.net/JBBBE.22.51

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Online since:

March 2015

Authors:

Cong Zhang, Zhen Zhao Guo, Bo Xue, Chang Ren Zhou, Hong Li*

Keywords:

Citrate, Crystals, CTAB, Hydroxyapatite (HA)

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* - Corresponding Author

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