Synthesis of the Hybrid Containing Two Organic Components Based on CuBr2

Li Ling Guo; Xue Song Zhang; Xian Wu; Han Xing Liu

doi:10.4028/www.scientific.net/AMR.197-198.367

Paper Titles

Preparation of N Doped ZnO Films by Magnetron Sputtering
p.348

Influence of Random Disorders on Anti-Plane Waveguiding Modes in a Two-Dimensional Phononic Crystal
p.352

The Surface Morphology and Mechanical Behavior Studies of DAST Crystal on (001) and (110) Faces
p.358

Preparation and Stabilization of High Conductivity Zn-Coated Tetra-Needle-Like ZnO Whiskers
p.362

Synthesis of the Hybrid Containing Two Organic Components Based on CuBr₂
p.367

Effect of Pre-Deformation and Ageing on Compressive Behavior of Ti-58.25wt%Ni Alloys at Room Temperature
p.375

Effect of Organic Bentonite on Rheological Properties of Paper Coating
p.383

Formation and Performance of Cerium Silane Mixture Conversion Coatings on AZ91 Magnesium Alloy
p.387

The Change of Amount and Twists Effect to Electrical Performance of Carbon-Coated Filaments
p.396

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 197-198Synthesis of the Hybrid Containing Two Organic...

Synthesis of the Hybrid Containing Two Organic Components Based on CuBr₂

Abstract:

A hybrid containing two organic components of n-butylamine and methylamine based on CuBr₂ was synthesized by reaction in solution. The influence of solvent and the feed ratio on the structure of the product were investigated. The structure and the thermostability of the hybrid were characterized using X-ray diffraction, chemical elemental analysis, infrared spectroscopy and thermogravimetric analysis. Comparing with the hybrid based on CuBr₂ containing only one organic component of n-butylamine, the hybrid containing two organic component s of n-butylamine and methylamine based on CuBr₂ also have layered perovskite structure and it can be synthesized with appropriate reaction conditions. The hybrid can illuminate blue light under the excitation of ultraviolet light.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 197-198)

Pages:

367-374

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.197-198.367

Citation:

Cite this paper

Online since:

February 2011

Authors:

Li Ling Guo, Xue Song Zhang, Xian Wu, Han Xing Liu

Keywords:

Layered Structure, Luminescence, Organic-Inorganic Perovskite-Type Hybrid

Export:

RIS, BibTeX

Price:

Permissions:

Request Permissions

References

[1] D.B. Mitzi: Templating and Structural Engineering inorganic-inorganic Perovskites，J. Chem. Soe. ，DaltonTrans, (2001), pp.1-12.

Google Scholar

[2] Mitzi D. B: Synthesis, Structure, and Properties of Organic-Inorganic Perovskites and Related Materials. Progress in inorganic chemistry, John Wiley & Sons, (1999), pp.1-121.

DOI: 10.1002/9780470166499.ch1

Google Scholar

[3] David B. Mitzi, K. Chondroudis, C.R. Kagan: Organic-Inorganic electronic. IBMJ. RES. & DEV. VOL. 45 NO. 1 JAN, (2001).

Google Scholar

[4] Liling Guo, Hanxing Liu: Preparation and Characterization of the Layered Hybrids (CnH2n+1NH3)2FeCl4. Journal of Physics and Chemistry of Solids, Vol. 68 (2007) , pp.1663-1673.

DOI: 10.1016/j.jpcs.2007.04.008

Google Scholar

[5] Liling Guo：Synthesis and Structures of the Layered Perovskite-type Organic-inorganic Hybrids (CnH2n+1NH3)2MCl4 Ph. D dissertation（2005）.

Google Scholar

[6] Gongdu Zhou, Lianyun Duan. The fundamental Structure Chemistry. Beijing, The Press of Beijing University (the third edition) (2002) p.178.

Google Scholar

[7] The data of bonding length are adopt from quantum calculation program Material Studio, (Accelrys Company, dmol3 modular).

Google Scholar