A New Method in Producing Ni Deposited Hydroxyapatite Composite by Modification of Electroless Deposition Technique

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Abstract:

Ni deposited Hydroxyapatite powder was prepared by electroless deposition technique without sensitization and activation treatments. The composition and phase of deposition were studied. The surface morphologies and composition of initial pure HA powder, as received Ni deposited HA powder and compacted Ni deposited HA powder after sintering were characterized by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) respectively. The phases in the powder before and after sintering were investigated by x-ray diffraction (XRD). From the experiment, with the increase of reduction agent, the plating time becomes shorter and optimal concentration of reduction agent and powder ratio is 3:1. The result shows that Ni succesfully deposited on HA powder and confirmed by EDX result. The Ni grain size distribution of 75nm to 250nm can be clearly observed on the HA surface from the micrograph after sintering. Decomposition of hydroxyapatite into α-TCP (α tricalcium phosphate) and TTCP (tetracalcium phosphate) did not occur in nickel deposited HA before and after sintering. On the other hand, a sharp Ni peak were detected

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99-104

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November 2014

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[1] M. Morales, R. Navarro, M. Almenara, J.M. Medina, C. Melian, C. Gutierrez. Effects of fibrin on the integration hydroxyapatite coating implants: experimental study in a rabbit model. Journal of Experimental Animal Science, Volume 42, Issue 2, August 2002, Pages 102-112.

DOI: 10.1016/s0939-8600(02)80012-8

Google Scholar

[2] M.H. Fathi, A. Hanifi, V. Mortazavi. Preparation and bioactivity evaluation of bone-like hydroxyapatite nanopowder . Journal of Materials Processing Technology, Volume 202, Issues 1–3, 20 June 2008, Pages 536-542.

DOI: 10.1016/j.jmatprotec.2007.10.004

Google Scholar

[3] M. Aminzare, A. Eskandari, M.H. Baroonian, A. Berenov, Z. Razavi Hesabi, M. Taheri, S.K. Sadrnezhaad. Hydroxyapatite nanocomposites: Synthesis, sintering and mechanical properties. Ceramics International, Volume 39, Issue 3, April 2013, Pages 2197-2206.

DOI: 10.1016/j.ceramint.2012.09.023

Google Scholar

[4] AyferKilicarslan, FatihToptan, IsilKerti. Electroless nickel–phosphorus coating on boron carbide particle., Materials Letters, Volume 76, 1 June 2012, Pages 11-14, ISSN 0167-577X.

DOI: 10.1016/j.matlet.2012.02.037

Google Scholar

[5] Yoram de Hazan, FranziskaKnies, DariuszBurnat, Thomas Graule, Yoko Yamada-Pittini, Christos Aneziris, MarenKraak. Homogeneous functional Ni–P/ceramic nanocomposite coatings via stable dispersions in electroless nickel electrolytes. Journal of Colloid and Interface Science. Volume 365, Issue 1, 1 January 2012, Pages 163-171, ISSN 0021-9797.

DOI: 10.1016/j.jcis.2011.09.032

Google Scholar

[6] Sh. Alirezaei, S.M. Monirvaghefi, M. Salehi, A. Saatchi. Effect of alumina content on surface morphology and hardness of Ni-PAl O2 3(a) electroless composite coatings. Surface and Coatings Technology 184 (2004) 170–175.

DOI: 10.1016/j.surfcoat.2003.11.013

Google Scholar

[7] S. Afroukhteh, C. Dehghaniann, M. Preparation of electroless Ni–P composite coatings containing nano-scattered alumina in presenceof polymeric surfactantEmamy. Progress in Natural Science: Materials International 2012; 22(4): 318–325.

DOI: 10.1016/j.pnsc.2012.06.006

Google Scholar

[8] Hui Wang, Jianfeng Jia, Hongzhang Song, Xing Hu, Hongwei Sun, Delin Yang. The preparation of Cu-coated Al2O3 composite powders by electroless plating. Ceramics International 37 (2011) 2181–2184.

DOI: 10.1016/j.ceramint.2011.03.013

Google Scholar

[9] H. Beygi, S.A. Sajjadi, S.M. Zebarjad. An optimization analysis on electroless deposition of Al2O3/Cu core-shell nanostructures. Applied Surface Science 261 (2012) 166– 173.

DOI: 10.1016/j.apsusc.2012.07.134

Google Scholar

[10] [ I. Mobasherpour, E. Salahi, M. Pazouki. Removal of nickel (II) from aqueous solutions by using nano-crystalline calcium hydroxyapatite. Journal of Saudi Chemical Society, Volume 15, Issue 2, April 2011, Pages 105-112, ISSN 1319-6103.

DOI: 10.1016/j.jscs.2010.06.003

Google Scholar

[11] I. Mobasherpour, E. Salahi, M. Pazouki. Comparative of the removal of Pb2+, Cd2+ and Ni2+ by nano crystallite hydroxyapatite from aqueous solutions: Adsorption isotherm study. Arabian Journal of Chemistry, Volume 5, Issue 4, October 2012, Pages 439-446, ISSN 1878-5352.

DOI: 10.1016/j.arabjc.2010.12.022

Google Scholar

[12] Lijing Dong, Zhiliang Zhu, YanlingQiu, Jianfu Zhao. Removal of lead from aqueous solution by hydroxyapatite/magnetite composite adsorbent. Chemical Engineering Journal, Volume 165, Issue 3, 15 December 2010, Pages 827-834, ISSN 1385-8947.

DOI: 10.1016/j.cej.2010.10.027

Google Scholar

[13] Mehmet Uysaln, Ramazan Karslioglu, AhmetAlp, Hatem Akbulut. The preparation of core–shell Al2O3/Ni compositepowdersby electroless plating. Ceramics International 39 (2013).

DOI: 10.1016/j.ceramint.2012.12.060

Google Scholar

[14] Glenn O. Malloy, Juan B. Hadju. Electroless Plating, fundamentals and Application. Noyes Publication, New York. (1990).

Google Scholar