Nucleation of Portlandite Clusters in Cement Paste at Very Early Stage of Hydration

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Abstract:

A very early stage of cement paste hydration is studied at microscopic level of description. Within context of nucleation theory the critical (and, thus, growable) size of clusters of calcium hydroxide (so-called portlandite) is estimated for chosen water to cement ratios at given temperature. Furthermore, also the barrier of portlandite nulceation is determined. It is shown that these static characteristics of process are practically unchanged contrary to number density of portlandite critical clusters formed in unit volume of mixture per unit time.

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Periodical:

Materials Science Forum (Volumes 636-637)

Pages:

1234-1238

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Online since:

January 2010

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[1] P. Demo and Z. Kožíšek: Thermochimica Acta Vol. 280-281 (1996), p.101.

Google Scholar

[2] P. Demo and Z. Kožíšek: Phys. Rev. Vol. B 48 (1993), p.3620.

Google Scholar

[3] P. Demo, Z. Kožíšek, and R. Šášík: Phys. Rev. Vol. E 59 (1999), p.5124.

Google Scholar

[4] E. M. Gartner, et al., in: Structure and Performance of Cements, edited by J. Bensted and P. Barnes, chapter 3, Spon Press, (2001).

Google Scholar

[5] H. F. W. Taylor: Cement Chemistry (2 nd edition, Thomas Telford, 2004).

Google Scholar

[6] O. Henning and V. Lach: Chemie ve stavebnictví (SNTL Praha, 1983, in Czech).

Google Scholar