Paper Titles

The Effects of Codoping Y₂O₃ on MgO Doped Spark Plasma Sintered Al₂O₃
p.74

Spark Plasma Sintering of Boron Carbide and Effects of Various Additives on Sintering and Material Properties
p.79

Microwave Absorbency Change of Zirconia Powder and Fiber during Vacuum Heating
p.85

Microwave Assisted Reaction Sintering of ZrSiO₄/α -Al₂O₃ Mixtures
p.91

Hybrid Foams, Colloids and Beyond: Advanced Ceramics through Integrative Chemistry
p.97

Panoscopic Assembling of Ceramic Materials for High Performance UV-Ray Shielding Application
p.107

Lightweight Hybrid Foam with Dimensional Stability
p.114

Ceramic/Polymeric Hybrids with Reduced Coefficients of Thermal Expansion
p.120

Dimension- and Direction-Controlled Gold Nanorods Deposited in Ordered Mesoporous Silica
p.126

HomeAdvances in Science and TechnologyAdvances in Science and Technology Vol. 63Hybrid Foams, Colloids and Beyond: Advanced...

Hybrid Foams, Colloids and Beyond: Advanced Ceramics through Integrative Chemistry

Article Preview

Abstract:

Today chemistry of materials and as such the ceramic field of research are addressed through more and more complex synthetic methodologies in order to optimize final material performances. The notion of complexity in chemical science is illustrated inhere through the concept of integrative chemistry. Particularly the integration between bi-liquid foams, sol-gel process, organo-silane functionnalization, lanthanides complexation and Pd heterogeneous nucleation is proposed as a non-exhaustive synthetic tool box to reach specific advanced ceramics. The first section is dealing with the synthesis of the first series of Si(HIPE) macrocellular foams where the oil volume fraction of the starting emulsion allows a nice tuning of the foams macroporosity. The second section is dealing with Europium complexation of diketone and malonamide hybrid Organo-Si(HIPE) leading to the Eu3+@Organo-Si(HIPE) luminescent foams, while the third part is dedicated to Pd heterogeneous nucleation within host hybrid foams. This last series of macrocellular ceramics are labeled Pd@Organo-Si(HIPE) which demonstrates good turn over number (TON) and turn over frequencies (TOF) when acting as supported catalysts for the Mizoroki-Heck coupling reactions. In the above mentioned foams the HIPE acronym is for High Internal Phase Emulsion.

You might also be interested in these eBooks

12th INTERNATIONAL CERAMICS CONGRESS PART B

Info:

Periodical:

Advances in Science and Technology (Volume 63)

Pages:

97-106

DOI:

https://doi.org/10.4028/www.scientific.net/AST.63.97

Citation:

Cite this paper

Online since:

October 2010

Authors:

Nicolas Brun, Simona Ungureanu, Florent Carn, Béatriz Julián-López, Rénal Backov

Keywords:

Biliquid Foam, Hybrid Material, Integrative Chemistry, Photonic S-Catalysis, Porous Ceramics, Sol-Gel Process

Export:

RIS, BibTeX

Price:

Permissions:

Request Permissions

[1] G.M. Whitesides and R.F. Ismagilov: Sience vol. 284 (1999), p.89.

[2] R. Backov: Soft Matter vol. 2 (2006), p.452.

[3] E. Prouzet, S. Ravaine, C. Sanchez and R. Backov: New J. Chem. vol. 32 (2008), p.1284.

[4] R. Backov: L'Acualité chimique vol. 329 (2009), p. III.

[5] C.J. Brinker and G.W. Scherrer, in : The physics and chemistry of sol-gel processing, Academic, san Diego (1990).

[6] F. Carn, M. -F. Achard, O. Babot, H. Deleuze, S. Réculusa and R. Backov: J. Mater. Chem. vol 15 (2005), p.3887.

DOI: 10.1039/b504336k

[7] M. Destribats, V. Schmitt and R. Backov: Langmuir vol. 26 (2010), p.1734.

[8] F. Carn, P. Masse, H. Sadaoui, B. Julian, H. Deleuze, S. Ravaine, C. Sanchez, D.R. Talham and R. Backov: Langmuir vol. 26 (2006), p.5469.

DOI: 10.1021/la060220b

[9] H. Serier, M. -F Achard, N. Steunou, J. Maquet, J. Livage, C. Leroy, O. Babot and R. Backov: Adv. Funct. Mat. Vol. 16 (2006), p.1745.

DOI: 10.1002/adfm.200600044

[10] L. Lecren, T. Toupance and R. Backov: Materials letters vol. 59 (2005), p.817.

[11] O. Regev, R. Backov and C. Faure: Chem. Mat. Vol. 16 (2004), p.5280.

[12] C. Boissière, D. Grosso, H. Amenitsch, A. Gibaud, A. Coupe, N. Bacile and C. Sanchez: Chem. Commun. (2003), p.2798.

[13] C. Sanchez and F. Ribot: New J. Chem. vol 18 (1994), p.1007.

[14] H. Zhang and A.I. Cooper: Soft Matter vol. 1 (2005), p.107.

[15] F. Carn, A. Colin, M-.F. Achard, M. Pirot, H. Deleuze and R. Backov: J. Mat. Chem. vol. 14 (2004), p.1370.

[16] T.G. Mason, J. Bibette and D.A. Weitz: J. Colloid Interface Sci. vol. 179 (1996), p.439.

[17] F. Carn, A. Colin , V. Schmidt, F. -L. Calderon and R. Backov: Colloids and Surfaces A: Physicochemical and Engineering Aspects vol. 263 (2005), p.341.

DOI: 10.1016/j.colsurfa.2004.12.034

[18] J. -M. Lehn: Angew. Chem. vol. 102 (1990), p.1347.

[19] N. Brun, B. Julian-Lopez, P. Hesemann, L. Guillaume, M. -F. Achard, H. Deleuze, C. Sanchez and R. Backov : Chem. Mater. Vol. 20 (2008), p.7117.

[20] S. Ungureanu, M. Birot, L. Guillaumme, H. Deleuze, O. Babot, B. Julian, M. -F. Achard, M. I. Popa, C. Sanchez and R. Backov: Chem. Mater. Vol. 19 (2007), p.5786.

DOI: 10.1021/cm701984t

[21] S. Ungureanu, H. Deleuze, M. I. Popa, C. Sanchez and R. Backov: Chem. Mater. vol. 20 (2008), p.6494.

[22] A. Desforges, H. Deleuze, O. Mondain-Monval and R. Backov: Ind. Eng. Chem. Res. vol. 44 (2005), p.8521.

DOI: 10.1021/ie040239e

[23] A. Desforges, R. Backov , H. Deleuze and O. Mondain-Monval: Adv. Funct. Mat. vol. 15 (2005), p.1689.

DOI: 10.1002/adfm.200500146

[24] O. Aksin, H. Turkmen, L. Artok, B. Cetinkaya, N. Chaoyinj, O. Buyukgungor, E.J. Ozkal: Organomet. Chem. vol. 691 (2006), p.30227.

[25] C.M. Cruddden, M. Satteesh and R. Lewis: J. Am. Chem. Soc. vol. 127 (2005), p.10045.

[26] H. Katayama, M. Nagao, F. Ozawa, M. Ikegami, T. Arai: J. Org. Chem. vol. 71 (2006), p.2699.

[27] C.C. Cassol, A.P. Umpierre, G. Machado, S.I. Wolke, J. Dupont: J. Am. Chem. Soc. vol 127 (2005), p.3298.