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Photodegradation of an Herbicide (2-methyl-4-chlorophenoxyacetic acid) in the Presence of “TiO2, SnO2, SnO2/TiO2 Nanoparticles – Polypropylene Fibrous Carrier” Systems

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Abstract:

Using electronic spectroscopy and fluorescence techniques, the degradation of 2-methyl-4-chlorophenoxyacetic acid has been researched in water under the excitation with UV radiation produced by a KrCl excimer lamp in the presence of “TiO2, SnO2, SnO2/TiO2 Nanoparticles – Polypropylene Fibrous Carrier” Systems. It has been determined that MCPA phototransformation is most efficient when using the “TiO2/SnO2 heteronanoparticles – carrier” system with the concentration of 25/6 mg/g. The results indicate that systems with applied semiconductor particles do not exhibit sorption properties towards МСРА molecules. Therefore, the change in the spectral characteristics of a МСРА water solution after time-exposure and exposure to radiation is only associated with the phototransformations of non-adsorbed МСРА molecules and with the emergence of their photodegradation products.

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Periodical:

Advanced Materials Research (Volume 1085)

Pages:

107-112

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1085.107

Citation:

Cite this paper

Online since:

February 2015

Authors:

Ilya A. Lysak*, Tatyana D. Malinovskaya, Olga N. Tchaikovskaya, Galina V. Lysak, Vyacheslav R. Artyushin

Keywords:

2-methyl-4-chlorophenoxyacetic acid, Photodegradation, Polypropylene Fibrous Carrier, Stanum Dioxide Nanoparticles, Titanium Dioxide Nanoparticles

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