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HomeDefect and Diffusion ForumDefect and Diffusion Forum Vol. 421Forming Hexagonal and Triangular Ultrathin WS2...

Forming Hexagonal and Triangular Ultrathin WS₂ Shapes by Controlling the Flow of Vapor

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Abstract:

This paper reports on the synthesis of thin films of tungsten disulfide (WS₂) by сhemical vapour deposition (CVD) using powders of sulfur and tungsten oxide obtained from tungsten metal powder. It is shown that the synthesized ultra-thin 2-dimensional (2D) films of WS₂ have appropriate structural and optical properties suitable for their application in the manufacturing of electronic and optoelectronic devices. Proposed method for the synthesis of 2D few-layered WS₂ can significantly accelerate the synthesis rate and will make it possible to control the stoichiometry and shapes of nanocrystals by controlling the amount of sulfur by magnetic mechanism. Moreover, obtained few-layered crystals demonstrate long-term stability to external factors, since the synthesis and the research carried out during the year. During this time, no signs of degradation of the TMDs structure were detected.

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Defect and Diffusion Forum Vol. 421

Info:

Periodical:

Defect and Diffusion Forum (Volume 421)

Pages:

149-160

DOI:

https://doi.org/10.4028/p-guvd0b

Citation:

Cite this paper

Online since:

December 2022

Authors:

Dauren A. Muratov*, Altynai A. Shaikenova, Renata R. Nemkayeva, Bagdat A. Rakymetov, Arman G. Umirzakov, Almaz L. Mereke

Keywords:

Chemical Vapour Deposition (CVD), Sulfurization, Transition-Metal Dichalcogenides (TMDs), Tungsten Disulfide (WS₂), Tungsten Oxide (WO₃) Powder

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[1] Q. H. Wang, K. Kalantar-Zadeh, A. Kis, J. N. Coleman, M. S. Strano. Electronics and optoelectronics of two-dimensional transition metal dichalcogenides. Nature nanotechnology. 7(11) (2012) 699-712. http: //.

DOI: 10.1038/nnano.2012.193

[2] L. Li, Y. Yu, G.J. Ye, et al., Black phosphorus field-effect transistors, Nature Nanotechnology. 9 (5) (2014) 372 - 377. http: //.

[3] K. Novoselov, Graphene: Mind the gap, Nat. Mater. 6 (10) (2007) 720-721. http: //.

[4] T. Weitao, Electrical, electronic and optical properties of MoS2 & WS2, (2017). Theses. 12. https://digitalcommons.njit.edu/theses/12.

[5] Y. Niu, S. Gonzalez-Abad, R. Frisenda, P. Marauhn, M. Drüppel, P. Gant, A. Castellanos-Gomez. Thickness-dependent differential reflectance spectra of monolayer and few-layer MoS2, MoSe2, WS2 and WSe2. Nanomaterials. 8(9) (2018) 725. http: //.

DOI: 10.3390/nano8090725

[6] H. Li, Y. Shi & L. J.Li. Synthesis and optoelectronic applications of graphene/transition metal dichalcogenides flat-pack assembly. Carbon. 127 (2018) 602-610. http: //.

DOI: 10.1016/j.carbon.2017.11.030

[7] D. Jariwala, V.K. Sangwan, L.J. Lauhon, Tobin J Marks, Mark C Hersam. Emerging device applications for semiconducting two-dimensional transition metal dichalcogenides, ACS Nano. 8 (2) (2014) 1102 - 1120. http: //.

DOI: 10.1021/nn500064s

[8] F. R. Sultanov, C. Daulbayev, B. Bakbolat, Z. A. Mansurov, A. A. Urazgaliyeva, R. Ebrahim S. S. Pei & K. P Huang. Microwave-enhanced chemical vapor deposition graphene nanoplatelets-derived 3D porous materials for oil/water separation. Carbon Letters. 30(1) (2020) 81-92. http: // DOI :10.1007/s42823-019-00073-5.

DOI: 10.1007/s42823-019-00073-5

[9] B. Radisavljevic, A. Radenovic, J. Brivio, V Giacometti, A Kis. Single-layer MoS2 transistors, Nat. Nanotechnol. 6 (3) (2011) 147 - 150. http: //.

DOI: 10.1038/nnano.2010.279

[10] B. H. Kim, H. Yoon, S. H. Kwon, D. W. Kim & Y. J. Yoon. Direct WS2 photodetector fabrication on a flexible substrate. Vacuum. 184 (2021) 109950. https://DOI.org/10.1016/j.vacuum.2020.109950.

DOI: 10.1016/j.vacuum.2020.109950

[11] X. Lin, F. Wang, X. Shan, Y. Miao, X. Chen, M. Yan & K. Zhang. High-performance photodetector and its optoelectronic mechanism of MoS2/WS2 vertical heterostructure. Applied Surface Science. 546 (2021). 149074. https://doi.org/10.1016/j.apsusc.2021.149074.

DOI: 10.1016/j.apsusc.2021.149074

[12] C. Daulbayev, F. Sultanov, B. Bakbolat & O. Daulbayev. 0D, 1D and 2D nanomaterials for visible photoelectrochemical water splitting. A review. International Journal of Hydrogen Energy, 45(58) (2020) 33325-33342. https://doi.org/10.1016/j.ijhydene.2020.09.101.

DOI: 10.1016/j.ijhydene.2020.09.101

[13] C.M. Orofeo, S. Suzuki, Y. Sekine, H. Hibino, Scalable synthesis of layer-controlled WS2 and MoS2 sheets by sulfurization of thin metal films, Appl. Phys. Lett. 105 (2014) 083112. http: //.

DOI: 10.1063/1.4893978

[14] T.Y. Chen, Y.H. Chang, C.L. Hsu, K.H. Wei, C.Y. Chiang, L.J. Li, Comparative study on MoS2 and WS2 for electrocatalytic water splitting, Int. J. Hydrogen Energy. 38 (2013) 12302–12309. http: //.

DOI: 10.1016/j.ijhydene.2013.07.021

[15] Fan, Y., Li, J., Hao, G., Luo, S., Tang, C., & Zhong, J. Synthesis, characterization of WS2 nanostructures by vapor phase deposition. Journal of Applied Physics, 117(6) (2015) 064302. http: //.

DOI: 10.1063/1.4907688

[16] Y. Zhang, Y. Zhang, Q. Ji, J. Ju, H. Yuan, J. Shi & Z. Liu. Controlled growth of high-quality monolayer WS2 layers on sapphire and imaging its grain boundary. ACS nano. 7(10) (2013). 8963-8971. http: //.

DOI: 10.1021/nn403454e

[17] B. Shi, D. Zhou, S. Fang, K. Djebbi, S. Feng, H. Zhao & D. Wang Facile and Controllable Synthesis of Large-Area Monolayer Drop-Casted WS Substrates 2 Flakes Based by Chemical on WO3 Precursor Vapor Deposition. 2D Materials and Van der Waals Heterostructures: Physics and Applications. 69 (2020). http: //.

DOI: 10.3390/nano9040578

[18] A. Shaikenova, R. Beisenov, D. Muratov. Chemical Vapor Deposition growth of WS2 crystals. Eurasian Physical Technical Journal, Vol.15, No.2(30), 2018, Karaganda, ISSN 1811-1165 (Print), ISSN 2413-2179. http://rep.ksu.kz//handle/data/5970.

[19] M. Demirtaş, C. Odacı, Y. Shehu, N. K. Perkgöz & F. Ay. Layer and size distribution control of CVD-grown 2D MoS2 using ALD-deposited MoO3 structures as the precursor. Materials Science in Semiconductor Processing. 108 (2020) 104880. http: //.

DOI: 10.1016/j.mssp.2019.104880

[20] C.J. Carmalt, I.P. Parkin, E.S. Peters, Atmospheric pressure chemical vapor deposition of WS2 thin films on glass, Polyhedron. 22 (2003) 1499–1505. http: //.

DOI: 10.1016/s0277-5387(03)00194-3

[21] W. Zeng, L. P. Feng, J. Su, H. X. Pan & Z. T Liu. Layer-controlled and atomically thin WS2 films prepared by sulfurization of atomic-layer-deposited WO3 films. Journal of Alloys and Compounds. 745 (2018) 834-839. https://doi.org/10.1016/j.jallcom.2018.02.046.

DOI: 10.1016/j.jallcom.2018.02.046

[22] R. Morrish, T. Haak, C.A. Wolden, Low-temperature synthesis of n-type WS2 thin films via H2S plasma sulfurization of WO3, Chem. Mater. 26 (13) (2014) 3986-3992. http: //.

DOI: 10.1021/cm501566h

[23] A. Splendiani, L. Sun, Y. Zhang, T. Li, J. Kim, C. Y. Chim & F. Wang. Emerging photoluminescence in monolayer MoS2. Nano letters. 10(4) (2010) 1271-1275. http: //.

DOI: 10.1021/nl903868w

[24] Q. Ji, Y. Zhang, T. Gao, Y. Zhang, D. Ma, M. Liu & Z. Liu. Epitaxial monolayer MoS2 on mica with novel photoluminescence. Nano letters. 13(8) (2013) 3870-3877. http: //.

DOI: 10.1021/nl401938t

[25] G. U. Özküçük, C. Odacı, E. Şahin, F. Ay & N. K. Perkgöz. Glass-assisted CVD growth of large-area MoS2, WS2 and MoSe2 monolayers on Si/SiO2 substrate. Materials Science in Semiconductor Processing. 105 (2020) 104679. https://doi.org/10.1016/j.mssp.2019.104679.

DOI: 10.1016/j.mssp.2019.104679

[26] S. Yeo, D. K. Nandi, R. Rahul, T. H. Kim, B. Shong, Y. Jang & H. Kim. Low-temperature direct synthesis of high quality WS2 thin films by plasma-enhanced atomic layer deposition for energy related applications. Applied Surface Science. 459 (2018) 596-605. https://doi.org/10.1016/j.apsusc.2018.07.210.

DOI: 10.1016/j.apsusc.2018.07.210

[27] B. Zheng & Y. Chen. Controllable growth of monolayer MoS2 and MoSe2 crystals using three-temperature-zone furnace. In IOP conference series: materials science and engineering. 274(1) (2017) 012085. IOP Publishing.

DOI: 10.1088/1757-899x/274/1/012085

[28] Y. Yin, F. Ren, Y.Wang, Z. Liu, J. Ao, M. Liang, J. Li. Direct van der Waals epitaxy of crack-free AlN Thin film on epitaxial WS2. Materials. 11(12) (2018) 2464. http: //.

DOI: 10.3390/ma11122464

[29] Y. Yu, P. W. Fong, S. Wang & C. Surya Fabrication of WS2/GaN PN Junction by Wafer-Scale WS2 Thin Film Transfer. Scientific reports. 6(1) (2016) 1 - 11. http: //.

DOI: 10.1038/srep37833

[30] G. Nazir, M. F. Khan, V. M. Iermolenko & J. Eom. Two-and four-probe field-effect and Hall mobilities in transition metal dichalcogenide field-effect transistors.RSC Advances. 6(65) (2016) 60787-60793. http: //.

DOI: 10.1039/c6ra14638d

[31] A.L. Elías, N. Perea-Lopez, A. Castro-Beltran, et al., Controlled synthesis and transfer of large-area WS2 sheets: from single layer to few layers, ACS Nano. 7 (6) (2013) 5235-5242. http: //.

DOI: 10.1021/nn400971k

[32] N.Liu, F. Fan, W. Xu, H. Zhang, Q. Zhou & X. Li. (2021). Synthesis of functional hollow WS2 particles with large surface area for Near-Infrared (NIR) triggered drug delivery. Journal of Alloys and Compounds, 875, 160034. https://doi.org/10.1016/j.jallcom.2021.160034.

DOI: 10.1016/j.jallcom.2021.160034

[33] A. Shaikenova, R. Beisenov, D. Muratov. Studying the mechanism of graphene formation by Chemical Vapor Deposition synthesis. Eurasian Physical Technical Journal, Vol.15, No.2(30), (2018) Karaganda, ISSN 1811-1165 (Print), ISSN 2413-2179. http://rep.ksu.kz//handle/data/5971.

[34] SiO2 Color Chart for thermally grown silicon dioxide HTE Labs. http://www.htelabs.com/appnotes/sio2_color_chart_thermal_silicon_dioxide.htm/, 2022 (accessed 30 March 2022).

[35] ICDD (PDF-2 Release 2016 RDB) (01-083-0950).

[36] ICDD (PDF-2 Release 2016 RDB 00-008-0237) (00-035-0651).

[37] B. Mahler, V. Hoepfner, K. Liao & G. A. Ozin. Colloidal synthesis of 1T-WS2 and 2H-WS2 nanosheets: applications for photocatalytic hydrogen evolution. Journal of the American Chemical Society, 136(40) (2014) 14121-14127. http: //.

DOI: 10.1021/ja506261t

[38] W. Zhao, Z. Ghorannevis, K. K. Amara, J. R. Pang, M. Toh, X. Zhang & G. Eda. Lattice dynamics in mono-and few-layer sheets of WS2 and Wse2. Nanoscale. 5(20) (2013) 9677-9683. http: //.

DOI: 10.1039/c3nr03052k

[39] S. M. Shinde, K. P. Dhakal, X. Chen, W. S. Yun, J. Lee, H. Kim & J. H. Ahn. Stacking-controllable interlayer coupling and symmetric configuration of multilayered MoS2. NPG Asia Materials. 10(2) (2018) 468 - 468. http: //.

DOI: 10.1038/am.2017.226

[40] L. Dong, Y. Wang, J. Sun, C. Pan, Q. Zhang, L. Gu. & J. Zhang. Facile access to shape-controlled growth of WS2 monolayer via environment-friendly method. 2D Materials. 6(1) (2018) 015007. http: //.

DOI: 10.1088/2053-1583/aae7eb

[41] S. Jo, N. Ubrig, H. Berger, A. B. Kuzmenko & A. F Morpurgo. Mono-and bilayer WS2 light-emitting transistors. Nano letters. 14(4) (2014) 2019-2025. http: //.

DOI: 10.1021/nl500171v