The Influence of Aminoalcohols on ZnO Films’ Structure
Abstract
:1. Introduction
2. Materials and Methods
2.1. Preparation of Samples
2.2. Instrumental Analysis
3. Results
3.1. Layer Morphology and Structural Properties
3.2. Raman Analysis of Layers on Different Substrates
3.3. Change in Spectral Properties Depending on the Stabilizer
4. Discussion
5. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
Abbreviations
ZnO | Zinc oxide |
Zn | Zinc |
MEA | Monoethanolamine |
DEA | Diethanolamine |
0.5 MEA | 5 % of monoethanolamine |
1 MEA | 10 % of monoethanolamine |
0.5 DEA | 5 % of diethanolamine |
1 DEA | 10 % of diethanolamine |
Si | Silicon |
AlO | Sapphire |
SiO | Quartz |
PL | Photoluminescence |
Zn | Zinc interstitial |
V | Oxygen vacancy |
V | Zinc vacancy |
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AlO | Si | |
---|---|---|
0.5 MEA | 90 ± 39 nm | 119 ± 38 nm |
1 MEA | 121 ± 40 nm | 82 ± 36 nm |
0.5 DEA | 116 ± 49 nm | 74 ± 34 nm |
1 DEA | 91 ± 40 nm | 72 ± 32 nm |
AlO | Si | SiO | |
---|---|---|---|
0.5 MEA | 18 ± 3 µm | 20 ± 3 µm | 15 ± 2 µm |
1 MEA | 17 ± 3 µm | 20 ± 3 µm | |
0.5 DEA | 11 ± 3 µm | 11 ± 3 µm | 10 ± 3 µm |
1 DEA | 5 ± 3 µm | 12 ± 3 µm |
AlO | a (Å) | c (Å) | c/a | (c/a) |
---|---|---|---|---|
0.5 MEA | 3.2455 | 5.1919 | 1.5997 | 0.0014 |
1 MEA | 3.2471 | 5.1982 | 1.6009 | 0.0013 |
0.5 DEA | 3.2354 | 5.1947 | 1.6056 | 0.0001 |
1 DEA | 3.2452 | |||
Si | a (Å) | c (Å) | c/a | (c/a) |
0.5 MEA | 3.2436 | 5.1910 | 1.6004 | 0.0017 |
1 MEA | 3.2432 | 5.1964 | 1.6022 | 0.0010 |
0.5 DEA | 3.2454 | 5.3327 | 1.6431 | 0.0021 |
1 DEA | 3.2447 | 5.3318 | 1.6432 | 0.0001 |
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Nowak, E.; Chłopocka, E.; Szybowicz, M.; Stachowiak, A.; Koczorowski, W.; Piechowiak, D.; Miklaszewski, A. The Influence of Aminoalcohols on ZnO Films’ Structure. Gels 2022, 8, 512. https://doi.org/10.3390/gels8080512
Nowak E, Chłopocka E, Szybowicz M, Stachowiak A, Koczorowski W, Piechowiak D, Miklaszewski A. The Influence of Aminoalcohols on ZnO Films’ Structure. Gels. 2022; 8(8):512. https://doi.org/10.3390/gels8080512
Chicago/Turabian StyleNowak, Ewelina, Edyta Chłopocka, Mirosław Szybowicz, Alicja Stachowiak, Wojciech Koczorowski, Daria Piechowiak, and Andrzej Miklaszewski. 2022. "The Influence of Aminoalcohols on ZnO Films’ Structure" Gels 8, no. 8: 512. https://doi.org/10.3390/gels8080512