CONTROLLED RADICAL POLYMERIZATION OF LAURYL METHACRYLATE IN THE BASE SYNTHETIC POLYALPHAOLEFIN OIL

E. V. Chernikova; Черникова Е. В.; M. S. Pavlova; Павлова М. С.; A. V. Plutalova; Плуталова А. В.; E. A. Litmanovich; Литманович Е. А.; A. L. Maksimov; Максимов А. Л.

doi:10.31857/S268695352260091X

CONTROLLED RADICAL POLYMERIZATION OF LAURYL METHACRYLATE IN THE BASE SYNTHETIC POLYALPHAOLEFIN OIL

Authors: Chernikova E.V.¹^,2^,3, Pavlova M.S.², Plutalova A.V.¹, Litmanovich E.A.¹, Maksimov A.L.³
Affiliations:
1. M.V. Lomonosov Moscow State University, Faculty of Chemistry
2. Mendeleev University of Chemical Technology, Higher Chemical College of the Russian Academy of Sciences
3. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Issue: Vol 512, No 1 (2023)
Pages: 39-45
Section: ХИМИЯ
URL: https://journals.rcsi.science/2686-9535/article/view/247179
DOI: https://doi.org/10.31857/S268695352260091X
EDN: https://elibrary.ru/QHDIYK
ID: 247179

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Abstract
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Abstract

Controlled radical polymerization of lauryl methacrylate in the base polyalphaolefin oil was performed first in the presence of 2-cyano-2-propyl dodecyl trithiocarbonate. It has been shown that polymerization proceeds to high monomer conversions and leads to the formation of a polymer with a narrow molecular weight distribution. At the same time, the reaction mixtures retain their transparency after polymerization is completed. The synthesized polymers have a thickening ability, which naturally increases with an increase in their number average molecular weight.

Keywords

higher alkyl methacylates, poly(laurylmethacrylate), reversible addition–fragmentation chain transfer (RAFT) polymerization, polymerization kinetics, viscosity modifier

References

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