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Determining the mechanism of interaction between molecules of porphyrin and fullerene and gold nanoparticles, based on luminescence spectroscopy data

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Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

Gold nanoparticles are synthesized via laser ablation of a gold target in a liquid. The constants that characterize the efficiency of porphyrins and fullerenes bonding with gold nanoparticles are determined using a modified Stern–Volmer equation. The results from luminescence quenching measurements are presented. It is found that the efficiency of bonding depends on whether there are functional groups in the molecular fragments. Porphyrin containing para-bromphenyl groups at the meso positions of the porphyrin core has the highest affinity for the surfaces of gold nanoparticles.

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Authors and Affiliations

  1. Institute of Chemistry, St. Petersburg State University, St. Petersburg, 198504, Russia

    M. G. Evdokimova, A. S. Konev, A. V. Kazakova & A. V. Povolotskiy

  2. Center for Optical and Laser Materials Research, St. Petersburg State University, St. Petersburg, 198504, Russia

    A. V. Povolotckaia & I. E. Kolesnikov

Authors
  1. M. G. Evdokimova
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  2. A. S. Konev
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  3. A. V. Povolotckaia
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  4. I. E. Kolesnikov
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  5. A. V. Kazakova
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  6. A. V. Povolotskiy
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Corresponding author

Correspondence to M. G. Evdokimova.

Additional information

Original Russian Text © M.G. Evdokimova, A.S. Konev, A.V. Povolotckaia, I.E. Kolesnikov, A.V. Kazakova, A.V. Povolotskiy, 2017, published in Izvestiya Rossiiskoi Akademii Nauk, Seriya Fizicheskaya, 2017, Vol. 81, No. 12, pp. 1576–1580.

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Evdokimova, M.G., Konev, A.S., Povolotckaia, A.V. et al. Determining the mechanism of interaction between molecules of porphyrin and fullerene and gold nanoparticles, based on luminescence spectroscopy data. Bull. Russ. Acad. Sci. Phys. 81, 1391–1395 (2017). https://doi.org/10.3103/S1062873817120103

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  • DOI: https://doi.org/10.3103/S1062873817120103

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