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Anomalous electrodeposition of Co-W coatings from a citrate electrolyte due to the formation of multinuclear heterometallic complexes in the solution

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Abstract

It is shown that the anomalous electrodeposition of Co-W coatings in a citrate electrolyte occurs as a result of the formation in the bulk of the solution of multinuclear heterometallic complexes with their structure (composition) defined by the solution and near-electrode layer pH values.

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Authors and Affiliations

  1. Institute of Applied Physics, Academy of Sciences of Moldova, ul. Akademiei 5, Chisinau, MD, 2028, Republic of Moldova

    S. S. Belevskii, S. P. Yushchenko & A. I. Dikusar

Authors
  1. S. S. Belevskii
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  2. S. P. Yushchenko
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  3. A. I. Dikusar
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Corresponding author

Correspondence to A. I. Dikusar.

Additional information

Original Russian Text © S.S. Belevskii, S.P. Yushchenko, A.I. Dikusar, 2012, published in Elektronnaya Obrabotka Materialov, 2012, No. 1, pp. 114–115.

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Belevskii, S.S., Yushchenko, S.P. & Dikusar, A.I. Anomalous electrodeposition of Co-W coatings from a citrate electrolyte due to the formation of multinuclear heterometallic complexes in the solution. Surf. Engin. Appl.Electrochem. 48, 97–98 (2012). https://doi.org/10.3103/S1068375512010036

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  • DOI: https://doi.org/10.3103/S1068375512010036

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