Remoción de tartrazina en agua usando nanopartículas de hierro cerovalentes
Barra lateral del artículo
Publicado:
Jul 15, 2019
Palabras clave:
nanopartículas de hierro cerovalentes, remoción, colorante, tartrazina
Contenido principal del artículo
Resumen
Debido a la importancia de una alternativa en decoloración de aguas residuales provenientes de la industria de alimentos, se reporta la remoción del colorante tartrazina, utilizando nanopartículas de hierro cerovalentes. Las nanopartículas se prepararon por reducción química de cloruro férrico con borohidruro de sodio en medio inerte. Para evaluar la remoción, se emplearon concentraciones de 25, 50 100, 150 y 200 mg/L de nanopartículas, con tiempos de contacto en agua de 10, 20 y 30 minutos a pH de 3, 5, 7, 9 y 11. Las nanopartículas obtenidas se caracterizaron por Microscopía Electrónica de Barrido (SEM, por sus siglas en inglés) y Espectrómetro de Dispersión de Rayos X (EDX, por sus siglas en inglés). Como resultados se obtuvieron nanopartículas de 53,3 y 92,1 nm aproximadamente. Se verificó la remoción de los colorantes en agua por Espectrofotometría UV-Vis e Infrarrojos con Transformada de Fourier (FT-IR). Los parámetros óptimos para la remoción de tartrazina, se lograron empleando 200 mg/L de nanopartículas, 30 minutos de agitación y pH 3 con una eficiencia del 83,3 %. Se logró una adsorción de tartrazina de hasta 301 mmol/100g (1659 mg/g). Se concluye que el uso de nanopartículas de hierro cerovalentes, es adecuado para la remoción del colorante tartrazina en agua.
Descargas
La descarga de datos todavía no está disponible.
Detalles del artículo
Sección
Artículos Científicos
Esta obra está bajo licencia internacional Creative Commons Reconocimiento-NoComercial-CompartirIgual 4.0.
- Los autores se comprometen a respetar la información académica de otros autores, y a ceder los derechos de autor a la Revista infoANALÍTICA, para que el artículo pueda ser editado, publicado y distribuido.
- El contenido de los artículos científicos y de las publicaciones que aparecen en la revista es responsabilidad exclusiva de sus autores. La distribución de los artículos publicados en la Revista infoANALÍTICA se realiza bajo una licencia Creative Commons Reconocimiento-CompartirIgual 4.0 Internacional License.
Citas
Ahuja, N., Chopra, A. K., & Ansari, A. A. (2016). Removal of Colour from Aqueous Solutions by using ZeroValent Iron Nanoparticles. Journal of Environmental Science, Toxicology and Food Technology (IOSR-JESTFT), 10(1), 4–14.
Aksu, Z., Tatlı, A. ., & Tunç, Ö. (2008). A comparative adsorption/biosorption study of Acid Blue 161: Effect of temperature on equilibrium and kinetic parameters. Chemical Engineering Journal, 142(1), 23–39
Alamillo, V. (2013). Remoción de colorantes orgánicos azul índigo y tartrazina, en solución acuosa, empleando nanopartículas de hierro soportadas en piedra volcánica de óxido de hierro (tezontle)(Tesis de pregrado). Toluca de Lerdo, México
Bigg, T., & Judd, S. J. (2002). Reductive degradation of azo dyes in aqueous solution by zero-valent iron. IAHS PUBLICATION, 383–390
Borzelleca, J. F., & Hallagan, J. B. (1988). Chronic toxicity/carcinogenicity studies of FD & C Yellow No. 5 (tartrazine) in rats. Food and Chemical Toxicology, 26(3), 179– 187
Choulis, N. H. (2010). Miscellaneous drugs, materials, medical devices, and techniques. In Side Effects of Drugs Annual, 32, 891–902. Elsevier
Das, S., Dash, S. K., & Parida, K. M. (2018). Kinetics, Isotherm, and Thermodynamic Study for Ultrafast Adsorption of Azo Dye by an Efficient Sorbent: Ternary Mg/(Al + Fe) Layered Double Hydroxides. ACS Omega, 3(3), 2532–2545
Deepali, N. J. (2012). Study of ground water quality in and around SIDCUL industrial area, Haridwar, Uttarakhand, India. Journal of Applied Technology in Environmental Sanitation, 2(2), 129–134.
Fan, J., Guo, Y., Wang, J., & Fan, M. (2009). Rapid decolorization of azo dye methyl orange in aqueous solution by nanoscale zerovalent iron particles. Journal of Hazardous Materials, 166(2–3), 904–910
FDA, (2018) Listing of color additives subject to certification. 21 C.F.R. §74.705
Forgacs, E., Cserháti, T., & Oros, G. (2004). Removal of synthetic dyes from wastewaters: a review. Environment International, 30(7), 953–971.
Fu, Y., & Viraraghavan, T. (2001). Fungal decolorization of dye wastewaters: a review. Bioresource Technology, 79(3), 251–262.
Gonawala, K. H., & Mehta, M. J. (2014). Removal of Color from Different Dye Wastewater by Using Ferric Oxide as an Adsorbent. Int. Journal of Engineering Research and Applications, 4(5), 102–109.
Goscianska, J., & Pietrzak, R. (2015). Removal of tartrazine from aqueous solution by carbon nanotubes decorated with silver nanoparticles. Catalysis Today, 249, 259– 264
He, Y., Gao, J. F., Feng, F. Q., Liu, C., Peng, Y. Z., & Wang, S. Y. (2012). The comparative study on the rapid decolorization of azo, anthraquinone and triphenylmethane dyes by zero-valent iron. Chemical Engineering Journal, 179, 8–18.
Hu, D., Wan, X., Li, X., Liu, J., & Zhou, C. (2017). Synthesis of water-dispersible poly-Llysine-functionalized magnetic Fe3O4-(GO-MWCNTs) nanocomposite hybrid with a large surface area for high-efficiency removal of tartrazine and Pb(II). International Journal of Biological Macromolecules,105(2), 1611–1621.
König, J. (2015). Food colour additives of synthetic origin. In M. J. Scotter (Ed.), Colour Additives for Foods and Beverages, 36–60. Woodhead Publishing.
Leulescu, M., Rotaru, A., Plrie, I., Moan, A., Cioater, N., Popescu, M., … Rotaru, P. (2018). Tartrazine: physical, thermal and biophysical properties of the most widely employed synthetic yellow food-colouring azo dye. Journal of Thermal Analysis and Calorimetry, 134(1), 209–231
Lin, Y. H., Tseng, H. H., Wey, M. Y., & Lin, M. D. (2010). Characteristics of two types of stabilized nano zero-valent iron and transport in porous media. Science of the Total Environment, 408(10), 2260–2267
Maekawa, A., Matsuoka, C., Onodera, H., Tanigawa, H., Furuta, K., Kanno, J., … Ogiu, T. (1987). Lack of carcinogenicity of tartrazine (FD & C Yellow No. 5) in the F344 rat. Food and Chemical Toxicology, 25(12), 891–896.
Mao,Y., Xi, Z., Wang, W., Ma, C., &Yue, Q. (2015). Kinetics of solvent blue and reactive yellow removal using microwave radiation in combination with nanoscale zerovalent iron. Journal of Environmental Sciences, 30, 164–172.
Mateus, G. A. P., dos Santos, T. R. T., Sanches, I. S., Silva, M. F., de Andrade, M. B., Paludo, M. P., … Bergamasco, R. (2018). Evaluation of a magnetic coagulant based on Fe3O4 nanoparticles and Moringa oleifera extract on tartrazine removal: coagulation-adsorption and kinetics studies. Environmental Technology, 1, 1-16.
Merck KGaA. (2019). Tartrazine. Retrieved from https://www.sigmaaldrich.com/catalog/ product/sigma/t0388?lang=en®ion=EC
Moutinho, I., Bertges, L., & Assis, R. (2007). Prolonged use of the food dye tartrazine (FD&C yellow n° 5) and its effects on the gastric mucosa of Wistar rats. Brazilian Journal of Biology, 67(1), 141–145.
Nam, S., & Tratnyek, P. G. (2000). Reduction of azo dyes with zero-valent iron. Water Research, 34(6), 1837–1845.
Poul, M., Jarry, G., Elhkim, M. O., & Poul, J.-M. (2009). Lack of genotoxic effect of food dyes amaranth, sunset yellow and tartrazine and their metabolites in the gut micronucleus assay in mice. Food and Chemical Toxicology, 47(2), 443–448.
Raman, C. D., & Kanmani, S. (2016). Textile dye degradation using nano zero valent iron: A review. Journal of Environmental Management, 177, 341–355.
Sohrabi, M. R., Amiri, S., Masoumi, H. R. F., & Moghri, M. (2014). Optimization of Direct Yellow 12 dye removal by nanoscale zero-valent iron using response surface methodology. Journal of Industrial and Engineering Chemistry, 20(4), 2535–2542.
Spina, F., Anastasi, A. E., Prigione, V. P., Tigini, V., & Varese, G. (2012). Biological treatment of industrial wastewaters: a fungal approach.
Sun, Y. P., Li, X. Q., Cao, J., Zhang, W. X., & Wang, H. P. (2006). Characterization of zero-valent iron nanoparticles. Advances in Colloid and Interface Science, 120(1– 3), 47–56.
Tran, H. V, Tran, T. L., Le, T. D., Le, T. D., Nguyen, H. M. T., & Dang, L. T. (2018). Graphene oxide enhanced adsorption capacity of chitosan/magnetite nanocomposite for Cr(VI) removal from aqueous solution. Materials Research Express, 6(2), 025018.
Zhao, Z., Liu, J., Tai, C., Zhou, Q., Hu, J., & Jiang, G. (2008). Rapid decolorization of water soluble azo-dyes by nanosized zero-valent iron immobilized on the exchange resin. Science in China Series B: Chemistry, 51(2), 186–192.
Aksu, Z., Tatlı, A. ., & Tunç, Ö. (2008). A comparative adsorption/biosorption study of Acid Blue 161: Effect of temperature on equilibrium and kinetic parameters. Chemical Engineering Journal, 142(1), 23–39
Alamillo, V. (2013). Remoción de colorantes orgánicos azul índigo y tartrazina, en solución acuosa, empleando nanopartículas de hierro soportadas en piedra volcánica de óxido de hierro (tezontle)(Tesis de pregrado). Toluca de Lerdo, México
Bigg, T., & Judd, S. J. (2002). Reductive degradation of azo dyes in aqueous solution by zero-valent iron. IAHS PUBLICATION, 383–390
Borzelleca, J. F., & Hallagan, J. B. (1988). Chronic toxicity/carcinogenicity studies of FD & C Yellow No. 5 (tartrazine) in rats. Food and Chemical Toxicology, 26(3), 179– 187
Choulis, N. H. (2010). Miscellaneous drugs, materials, medical devices, and techniques. In Side Effects of Drugs Annual, 32, 891–902. Elsevier
Das, S., Dash, S. K., & Parida, K. M. (2018). Kinetics, Isotherm, and Thermodynamic Study for Ultrafast Adsorption of Azo Dye by an Efficient Sorbent: Ternary Mg/(Al + Fe) Layered Double Hydroxides. ACS Omega, 3(3), 2532–2545
Deepali, N. J. (2012). Study of ground water quality in and around SIDCUL industrial area, Haridwar, Uttarakhand, India. Journal of Applied Technology in Environmental Sanitation, 2(2), 129–134.
Fan, J., Guo, Y., Wang, J., & Fan, M. (2009). Rapid decolorization of azo dye methyl orange in aqueous solution by nanoscale zerovalent iron particles. Journal of Hazardous Materials, 166(2–3), 904–910
FDA, (2018) Listing of color additives subject to certification. 21 C.F.R. §74.705
Forgacs, E., Cserháti, T., & Oros, G. (2004). Removal of synthetic dyes from wastewaters: a review. Environment International, 30(7), 953–971.
Fu, Y., & Viraraghavan, T. (2001). Fungal decolorization of dye wastewaters: a review. Bioresource Technology, 79(3), 251–262.
Gonawala, K. H., & Mehta, M. J. (2014). Removal of Color from Different Dye Wastewater by Using Ferric Oxide as an Adsorbent. Int. Journal of Engineering Research and Applications, 4(5), 102–109.
Goscianska, J., & Pietrzak, R. (2015). Removal of tartrazine from aqueous solution by carbon nanotubes decorated with silver nanoparticles. Catalysis Today, 249, 259– 264
He, Y., Gao, J. F., Feng, F. Q., Liu, C., Peng, Y. Z., & Wang, S. Y. (2012). The comparative study on the rapid decolorization of azo, anthraquinone and triphenylmethane dyes by zero-valent iron. Chemical Engineering Journal, 179, 8–18.
Hu, D., Wan, X., Li, X., Liu, J., & Zhou, C. (2017). Synthesis of water-dispersible poly-Llysine-functionalized magnetic Fe3O4-(GO-MWCNTs) nanocomposite hybrid with a large surface area for high-efficiency removal of tartrazine and Pb(II). International Journal of Biological Macromolecules,105(2), 1611–1621.
König, J. (2015). Food colour additives of synthetic origin. In M. J. Scotter (Ed.), Colour Additives for Foods and Beverages, 36–60. Woodhead Publishing.
Leulescu, M., Rotaru, A., Plrie, I., Moan, A., Cioater, N., Popescu, M., … Rotaru, P. (2018). Tartrazine: physical, thermal and biophysical properties of the most widely employed synthetic yellow food-colouring azo dye. Journal of Thermal Analysis and Calorimetry, 134(1), 209–231
Lin, Y. H., Tseng, H. H., Wey, M. Y., & Lin, M. D. (2010). Characteristics of two types of stabilized nano zero-valent iron and transport in porous media. Science of the Total Environment, 408(10), 2260–2267
Maekawa, A., Matsuoka, C., Onodera, H., Tanigawa, H., Furuta, K., Kanno, J., … Ogiu, T. (1987). Lack of carcinogenicity of tartrazine (FD & C Yellow No. 5) in the F344 rat. Food and Chemical Toxicology, 25(12), 891–896.
Mao,Y., Xi, Z., Wang, W., Ma, C., &Yue, Q. (2015). Kinetics of solvent blue and reactive yellow removal using microwave radiation in combination with nanoscale zerovalent iron. Journal of Environmental Sciences, 30, 164–172.
Mateus, G. A. P., dos Santos, T. R. T., Sanches, I. S., Silva, M. F., de Andrade, M. B., Paludo, M. P., … Bergamasco, R. (2018). Evaluation of a magnetic coagulant based on Fe3O4 nanoparticles and Moringa oleifera extract on tartrazine removal: coagulation-adsorption and kinetics studies. Environmental Technology, 1, 1-16.
Merck KGaA. (2019). Tartrazine. Retrieved from https://www.sigmaaldrich.com/catalog/ product/sigma/t0388?lang=en®ion=EC
Moutinho, I., Bertges, L., & Assis, R. (2007). Prolonged use of the food dye tartrazine (FD&C yellow n° 5) and its effects on the gastric mucosa of Wistar rats. Brazilian Journal of Biology, 67(1), 141–145.
Nam, S., & Tratnyek, P. G. (2000). Reduction of azo dyes with zero-valent iron. Water Research, 34(6), 1837–1845.
Poul, M., Jarry, G., Elhkim, M. O., & Poul, J.-M. (2009). Lack of genotoxic effect of food dyes amaranth, sunset yellow and tartrazine and their metabolites in the gut micronucleus assay in mice. Food and Chemical Toxicology, 47(2), 443–448.
Raman, C. D., & Kanmani, S. (2016). Textile dye degradation using nano zero valent iron: A review. Journal of Environmental Management, 177, 341–355.
Sohrabi, M. R., Amiri, S., Masoumi, H. R. F., & Moghri, M. (2014). Optimization of Direct Yellow 12 dye removal by nanoscale zero-valent iron using response surface methodology. Journal of Industrial and Engineering Chemistry, 20(4), 2535–2542.
Spina, F., Anastasi, A. E., Prigione, V. P., Tigini, V., & Varese, G. (2012). Biological treatment of industrial wastewaters: a fungal approach.
Sun, Y. P., Li, X. Q., Cao, J., Zhang, W. X., & Wang, H. P. (2006). Characterization of zero-valent iron nanoparticles. Advances in Colloid and Interface Science, 120(1– 3), 47–56.
Tran, H. V, Tran, T. L., Le, T. D., Le, T. D., Nguyen, H. M. T., & Dang, L. T. (2018). Graphene oxide enhanced adsorption capacity of chitosan/magnetite nanocomposite for Cr(VI) removal from aqueous solution. Materials Research Express, 6(2), 025018.
Zhao, Z., Liu, J., Tai, C., Zhou, Q., Hu, J., & Jiang, G. (2008). Rapid decolorization of water soluble azo-dyes by nanosized zero-valent iron immobilized on the exchange resin. Science in China Series B: Chemistry, 51(2), 186–192.