Skip to content
BY-NC-ND 3.0 license Open Access Published by De Gruyter Open Access October 6, 2009

Cloud point extraction-preconcentration and flame atomic absorption spectrometric determination of low levels of zinc in water and blood serum samples

  • Ardeshir Shokrollahi EMAIL logo , Mojtaba Shamsipur , Fahimeh Jalali and Hamid Nomani
From the journal Open Chemistry

Abstract

A simple, sensitive and selective flotation method is described for the preconcentration and atomic absorption spectrometric determination of zinc ion in water and blood samples. At a solution pH of 5.2, 4-(2-pyridylazo-resorcinol) and Triton X-114 were used as hydrophobic ligand and non-ionic surfactant, respectively. The chemical variables affecting the preconcentration process were optimized. Under the optimized experimental conditions, the selective preconcentration and determination of as low zinc concentration as 6.5 µg L−1 can be made. The proposed method was successfully applied to the preconcentration and low-level determination of zinc in different water and blood serum samples.

[1] K.M. Hambridge, C.E. Casey, N.F. Krebs, In: W. Mertz (Ed.), Trace elements in human and animal nutrition, 5th edition (Academic Press, Orlando, 1987) vol. 2, 1 Search in Google Scholar

[2] P. Sybil (Ed.), Concise Encyclopedia of Science and Technology (McGraw-Hill, New York, 1984) Search in Google Scholar

[3] A.H. Shankar, A.S. Prasad, Am. J. Clin. Nutrit. 68(Suppl.), S447 (1998) 10.1093/ajcn/68.2.447SSearch in Google Scholar

[4] D. Nonova, K. Stoyanov, Mikrochim. Acta 74, 171 (1980) 10.1007/BF01196442Search in Google Scholar

[5] B.A. Diantouba, I. Guiguemde, A. Tayeb, G.J. Goetzgrandmont, J.P. Brunette, Solvent Extr. Ion Exch. 12, 325 (1994) http://dx.doi.org/10.1080/0736629940891821310.1080/07366299408918213Search in Google Scholar

[6] T. Sekine, I. Kobelova, J. Noro, T.K.D. Nguyen, Anal. Sci. 10, 743 (1994) http://dx.doi.org/10.2116/analsci.10.74310.2116/analsci.10.743Search in Google Scholar

[7] P.C. Reddy, B. Rangamannar, J. Radianal. Nucl. Chem. Lett. 200, 181 (1995) http://dx.doi.org/10.1007/BF0216408010.1007/BF02164080Search in Google Scholar

[8] E. Abd-Elhafeez, Egypt. J. Anal. Chem. 5, 23 (1996) Search in Google Scholar

[9] D.J. Johnson, Y.Y. Djuh, J. Bruton, H.L. Williams, Clin. Chem. 23, 1321 (1977) 10.1093/clinchem/23.7.1321Search in Google Scholar

[10] R. Homsher, B. Zak, Clin. Chem. 31, 1310 (1985) 10.1093/clinchem/31.8.1310Search in Google Scholar

[11] T. Makino, Clin. Chim. Acta 197, 209 (1991) http://dx.doi.org/10.1016/0009-8981(91)90141-X10.1016/0009-8981(91)90141-XSearch in Google Scholar

[12] A. Kaplan, R. Jack, K.E. Opheim, B. Toivola, A.W. Lyon, Clinical chemistry interpretation and techniques, 4th edition (Williams & Wilkins, Malvern, 1995) 348 Search in Google Scholar

[13] W.L. Hinze, E. Pramauro, Crit. Rev. Anal. Chem. 24, 133 (1993) http://dx.doi.org/10.1080/1040834930804882110.1080/10408349308048821Search in Google Scholar

[14] I. Casero, D. Sicilia, S. Rubio, D. Perez-Bendito, Anal. Chem. 71, 4519 (1999) http://dx.doi.org/10.1021/ac990106g10.1021/ac990106gSearch in Google Scholar

[15] D. Sicilia, S. Rubio, D. Perez-Bendito, N. Maniasso, E.A.G. Zagatto, Anal. Chim. Acta 392, 29 (1999) http://dx.doi.org/10.1016/S0003-2670(99)00054-910.1016/S0003-2670(99)00054-9Search in Google Scholar

[16] C.G. Pinto, J.L. Perez-Pavon, B. Moreno-Cordero, Anal. Chem. 66, 874 (1994) http://dx.doi.org/10.1021/ac00078a01910.1021/ac00078a019Search in Google Scholar

[17] M. Du, W. Wu, N. Ercal, Y. Ma, J. Chromatogr. B 803, 321 (2004) http://dx.doi.org/10.1016/j.jchromb.2004.01.02710.1016/j.jchromb.2004.01.027Search in Google Scholar PubMed

[18] M. Ghaedi, A. Shokrollahi, R. Mehrnoosh, O. Hossaini, M. Soylak, Cent. Eur. J. Chem. 6, 488 (2008) http://dx.doi.org/10.2478/s11532-008-0049-910.2478/s11532-008-0049-9Search in Google Scholar

[19] M. Ghaedi, F. Ahmadi, A. Shokrollahi, J. Hazard. Mat. 142, 272 (2007) http://dx.doi.org/10.1016/j.jhazmat.2006.08.01210.1016/j.jhazmat.2006.08.012Search in Google Scholar PubMed

[20] M. Ghaedi, A. Shokrollahi, Fresenius. Environ. Bull. 15, 79 (2006) Search in Google Scholar

[21] A. Shokrollahi, M. Ghaedi, H.R. Rajabi, Annali di Chimica 97, 823 (2007) http://dx.doi.org/10.1002/adic.20079006710.1002/adic.200790067Search in Google Scholar PubMed

[22] M. Ghaedi, A. Shokrollahi, K. Niknam, E. Niknam, A. Najibi, M. Soylak, J. Hazard. Mater. 168, 1022 (2009) http://dx.doi.org/10.1016/j.jhazmat.2009.02.13010.1016/j.jhazmat.2009.02.130Search in Google Scholar PubMed

[23] M. Ghaedi, A. Daneshfar, A. Shokrollahi, H. Ghaedi, F. Arvin Pili, Annali di Chimica 97, 971 (2007) http://dx.doi.org/10.1002/adic.20079008110.1002/adic.200790081Search in Google Scholar PubMed

[24] A. Shokrollahi, M. Ghaedi, M.S. Niband, H.R. Rajabi, J. Hazard. Mater. 151, 642 (2008) http://dx.doi.org/10.1016/j.jhazmat.2007.06.03710.1016/j.jhazmat.2007.06.037Search in Google Scholar PubMed

[25] A. Shokrollahi, M. Ghaedi, O. Hossaini, N. Khanjari, M. Soylak, J. Hazard. Mater. 160, 435 (2008) http://dx.doi.org/10.1016/j.jhazmat.2008.03.01610.1016/j.jhazmat.2008.03.016Search in Google Scholar PubMed

[26] A. Shokrollahi, M. Ghaedi, S. Gharaghani, M.R. Fathi, M. Soylak, Quim. Nova, 31, 70 (2007) 10.1590/S0100-40422008000100015Search in Google Scholar

[27] M. Ghaedi, A. Shokrollahi, A.H. Kianfar, A.S. Mirsadeghi, A. Pourfarokhi, M. Soylak, J. Hazard. Mater. 154, 128 (2008) http://dx.doi.org/10.1016/j.jhazmat.2007.10.00310.1016/j.jhazmat.2007.10.003Search in Google Scholar

[28] M. Ghaedi, A. Shokrollahi, F. Ahmadi, H.R. Rajabi, M. Soylak, J. Hazard. Mater. 150, 533 (2008) http://dx.doi.org/10.1016/j.jhazmat.2007.05.02910.1016/j.jhazmat.2007.05.029Search in Google Scholar

[29] J.L. Manzoori, A. Bavili-Tabrizi, Michrochem. J. 72, 1 (2002) http://dx.doi.org/10.1016/S0026-265X(01)00113-810.1016/S0026-265X(01)00113-8Search in Google Scholar

[30] A.M. Abdallah, M.A. Kabil, M.A. Akl, D.S. Ismael, J. Iran. Chem. Soc. 1, 79 (2004) 10.1007/BF03245774Search in Google Scholar

[31] S.E. Ghazy, R.M. El-Shazly, M.S. El-Shahawi, G.A.A. El-Hazmi, A.A. El-Asmy, J. Iran. Chem. Soc. 3, 140 (2006) 10.1007/BF03245941Search in Google Scholar

[32] M. Ghaedi, A. Shokrollahi, K. Niknam, E. Niknam, M. Soylak, Cent. Eur. J. Chem. 7, 148 (2009) http://dx.doi.org/10.2478/s11532-008-0102-810.2478/s11532-008-0102-8Search in Google Scholar

[33] M. Ghaedi, A. Shokrollahi, K. Niknam, M. Soylak, Sep. Sci. Technol. 44, 773 (2009) http://dx.doi.org/10.1080/0149639080243716410.1080/01496390802437164Search in Google Scholar

[34] J. Chen, K.C. Teo, Anal. Chim. Acta 450, 215 (2003) http://dx.doi.org/10.1016/S0003-2670(01)01367-810.1016/S0003-2670(01)01367-8Search in Google Scholar

[35] S.A. Kulichenko, V.A.J. Doroshchuk, Anal. Chem. 58, 586 (2003) 10.1023/A:1024103916725Search in Google Scholar

[36] S. Shibata, In: H.A. Flaschka, A.J. Barnard (Eds.), Chelates in Analytical Chemistry (Marcell-Dekker, New York, 1972) Search in Google Scholar

Published Online: 2009-10-6
Published in Print: 2009-12-1

© 2009 Versita Warsaw

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Downloaded on 8.5.2024 from https://www.degruyter.com/document/doi/10.2478/s11532-009-0077-0/html
Scroll to top button