Abstract
The catalytic activity of MoVTeNbO catalyst and its constituent phases (M1, M2 and Mo5O14-like) in the oxidation of propane, as well as propylene and acrolein, which are intermediates of acrylic acid formation from propane, was studied. In all the reactions, the М1 phase shows higher activity and selectivity, compared to M2 and Mo5O14-like phases; its presence being sufficient for efficient proceeding the propane oxidation to acrylic acid.
References
T. Ushikubo, Catal. Today, 2003, 78, 79-84 10.1016/S0920-5861(02)00346-2Search in Google Scholar
T. Ushikubo, H. Nakamura, Y. Koyasu, S. Wajiki, US Pat. 1995, 5.380.933 Assigned to Mitsubishi Chemical Co. Search in Google Scholar
E.V. Ischenko, T.V. Andrushkevich, G.Ya. Popova, V.M. Bondareva, G.I. Aleshina, Y.A. Chesalov, T.Yu. Kardash, L.M. Plyasova, L.S. Dovlitova, A.V. Ischenko, Stud. Surf. Sci. Catal., 2010, 175, 479-482 10.1016/S0167-2991(10)75089-8Search in Google Scholar
H. Watanabe, Y. Koyasu, Appl. Catal A: Gen., 2000, 194- 195, 479-485 10.1016/S0926-860X(99)00394-4Search in Google Scholar
F. Ivars, B. Solsona, S. Hernandez, J.M. Lopez Nieto, Catal. Today, 2010, 149, 260–266 10.1016/j.cattod.2009.09.018Search in Google Scholar
G. Popova, T. Andrushkevich, G. Aleshina, L. Plyasova, M. Khramov, Appl. Catal. A: Gen., 2007, 328, 195-200 10.1016/j.apcata.2007.06.010Search in Google Scholar
P. DeSanto, D.J. Buttrey, R.K. Grasselli, C.G. Lugmair, A.F. Volpe, B.H. Toby, T. Vogt, Top. Catal., 2003, 23, 23 10.1023/A:1024812101856Search in Google Scholar
E.V. Ishchenko, Formation of MoVTeNb oxide catalysts for oxidative transformation of propane. The role of the phase and chemical composition, PhD thesis, Boreskov Institute of Catalysis SB RAS, Novosibirsk, RU, 2012 (In Russia) Search in Google Scholar
G.Ya. Popova, T.V. Andrushkevich, L.S. Dovlitova, G.A. Aleshina, Yu.A. Chesalov, A.V. Ishenko, E.V. Ischenko, L.M. Plyasova, V.V. Malakhov, M.I. Khramov, Appl. Catal., 2009, 353, 249-257 10.1016/j.apcata.2008.10.060Search in Google Scholar
T.Yu. Kardash, L.M. Plyasova, V.M. Bondareva, T.V. Andrushkevich, L.S. Dovlitova, A.I. Ischenko, A.I. Nizovskii, A.V. Kalinkin Appl. Catal. A: Gen., 2010, 375, 26–36 10.1016/j.apcata.2009.12.003Search in Google Scholar
G.Ya. Popova, T.V. Andrushkevich, Yu.A. Chesalov, L.M. Plyasova, L.S. Dovlitova, E.V. Ischenko, G.I. Aleshina, M.I. Khramov, Catal. Today, 2009, 144, 312-317 10.1016/j.cattod.2009.01.049Search in Google Scholar
J. M. Oliver, J. M. López-Nieto, P. Botella, A. Mifsud, Appl. Catal. A:Gen., 2004, 257, 67-76 Search in Google Scholar
R. Irmawati, P. Botella, F. Ivars, P.M. Woi, S.M.M. Zawawi, H.A. Ahangar, S. Hernandez, J.M.L. Nieto, J. Molecular Catalysis A: Chem., 2010, 342-343, 50-57 10.1016/j.molcata.2011.04.009Search in Google Scholar
L. Kihlborg, Arkiv Kemi, 1963, 21, 427 10.1111/j.1476-5381.1963.tb02010.xSearch in Google Scholar PubMed PubMed Central
L.M.Plyasova, L.P. Solov’eva, G.N. Kryukova, V.A. Zabolotnyi, I.P. Olen’kova, Zhurnal Strukturnoi Khimii, 1991, 32, 110 (In Russian) 10.1007/BF00744949Search in Google Scholar
B. Deniau, G. Bergeret, B. Jouguet, J.L. Dubois, J.M.M. Millet, Topics Catal., 2008, 50, 33-42 10.1007/s11244-008-9104-1Search in Google Scholar
P. Korovchenko, N.R. Shiju, A.K. Dozier, U.M. Graham, M.O. Guerrero-Perez, V.V. Guliants, Top. Catal., 2008, 50, 43-51 10.1007/s11244-008-9098-8Search in Google Scholar
J. Holmberg, R.K. Grasselli, A. Andersson, Topics Catal., 2003, 23, 55-63 10.1023/A:1024868219603Search in Google Scholar
M. Baca, M. Aouine, J.L. Dubois, J.M.M. Millet, J. Catal., 2005, 233, 234-241 10.1016/j.jcat.2004.12.002Search in Google Scholar
R.K. Grasselli, J.D. Burrington, D.J. Buttrey, P. DeSanto, C.G. Lugmair, A.F. Volpe, T. Weingand, Topics Catal., 2003, 23, 5-22 10.1023/A:1024859917786Search in Google Scholar
F. Cavani, G. Centi, Ph. Marion, Edited by S.D. Jackson, J.S.J. Hargreaves, Metal Oxide Catalysis, 2009, 782-786 Search in Google Scholar
Т.V. Andrushkevich, G.К.Boreskov, L.L.Kuznetsova, L.М. Plyasova, Yu.N.Tyurin, Yu.М.Schekochihin, Kinetics and Catalysis, 1974, 15, 424-429 Search in Google Scholar
T. Andrushkevich, Catal. Rev., 1993, 35, 213-25910.1080/01614949308014606Search in Google Scholar
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