1986 Volume 27 Issue 2 Pages 102-107
The microstructure of the Al2O3–ZrO2 eutectic with addition of a small amount of Y2O3 has been studied. The eutectic composition was determined as 59 mol%Al2O3–36.8 mol%ZrO2–4.2 mol%Y2O3. The added Y2O3 (2.1–5.3 mol%) dissolved only in the ZrO2 phase and the crystal structure of this phase changed from monoclinic to tetragonal+cubic and cubic depending on the amount of Y2O3. Several orientation relationships were found between the ZrO2 and Al2O3 phases. The Al2O3–ZrO2 eutectic contained twins in the ZrO2 phase. Cracks were observed in the Al2O3 matrix and at the Al2O3/ZrO2 interface. The orientation relationship between monoclinic ZrO2 and Al2O3 can be interpreted to be affected by the difference in the thermal expansion coefficient between ZrO2 and Al2O3.