doiSerbia

Efficiency of different additives in the improvement of the oxidation stability of fatty acid methyl esters with different properties

Rankov-Šicar Milica (University of Novi Sad, Faculty of Technology Novi Sad, Novi Sad, Serbia; SP Laboratorija a.d., Bečej, Serbia)
Mićić Radoslav (University of Novi Sad, Technical Faculty “Mihajlo Pupin”, Zrenjanin, Serbia)
Tomić Milan (University of Novi Sad, Faculty of Agriculture, Novi Sad, Serbia)
Đurišić-Mladenović Nataša (University of Novi Sad, Faculty of Technology Novi Sad, Novi Sad, Serbia), natasadjm@tf.uns.ac.rs, natasa.mladenovic@uns.ac.r

This study evaluates six formulations in improving the oxidation stability of different fatty acid methyl esters (MEs). Two MEs differed in the unsaturation levels as they were synthesized from different feedstock: a blend of soybean and sunflower oils, and waste cooking oil; they did not fulfill the requirements of the EN 14214 standard concerning their oxidation stability (≈0.6 h) and some impurities. The third MEs (SoSuME-EN) were fully compliant with the standard. Five formulations were phenolic-based, containing single or mixed antioxidant compounds of different molecular structures; one was amine-based. Different dosages of the formulations were added to the ME samples (corresponding to the addition range 50–48300 ppm). The MEs stability expressed as induction periods, IP, determined by the Rancimat method, were used for the calculation of stabilization factors, SF, indicating the efficiency of the applied formulation. The formulation containing 2-(1,1-dimethylethyl)- 1,4-benzenediol was the most efficient concerning the lowest consumption rate and the highest SF achieved for the low quality ME. 2,2′-Methylene- -bis-(4-methyl-6-tert-butylphenol) was linked with higher antioxidant potency than the amine-based formulation and the phenolic compounds with two bulky tert-butyl groups. Among the 4 selected phenolic additives, butylated hydroxytoluene and 2,2′-methylene-bis-(4-methyl-6-tert-butylphenol) had similar efficiency in SoSuME-EN (at ≈500 ppm they produced SF ≈ 2), while it took twice of this amount for mixed butylphenols to achieve the same effect.

Keywords: biodiesel, phenolic antioxidants, amine-based additive, oxidation stability, Rancimat induction period

Project of the Serbian Ministry of Education, Science and Technological Development, Grant no. 451-03-68/2020-14/200134, Grant no. 451-03-9/2021-14/200134 and Grant no. 451-03-68/2020-14/200117