Journal of the Serbian Chemical Society 2005 Volume 70, Issue 12, Pages: 1419-1425
https://doi.org/10.2298/JSC0512419L
Full text (
107 KB)
Cited by
The effects of yttrium on the hydrogenation performance and surface properties of a ruthenium-supported catalyst
Luo Laitao (Institute of Applied Chemistry, Nanchang University, Nanchang, P.R.China)
Songjun Li (Chengdu Institute of Organic Chemistry, Chinese Academy of Science, Chengdu, P.R.China)
Zhu Yu (Institute of Applied Chemistry, Nanchang University, Nanchang P.R.China)
The effects of yttrium on the hydrogenation performance and surface properties of a Ru/sepiolite catalyst were studied. With CO2 methanation and CS2 poisoning as the testing reactons, TPR, TPD, XRD and CO chemisorption as the characterizations, the results showed that the presence of yttrium can increase the hydrogenation activity and anti-poisoning capacity of the Ru/sepiolite catalyst, which is due to a change of surface properties of the Ru/sepiolite. In the process of the catalytic reaction, the adjusting behavior of yttrium for the Ru/sepiolite catalyst aids in increasing the catalytic activity and anti-poisoning capacity of the catalyst.
Keywords: yttrium, ruthenium catalyst, sepiolite, hydrogenation