2016 年 32 巻 p. 25-26
The crystal structure of trans(Cl),cis(S)-dichlorobis(dimethyl sulfoxide-S)(N,N,N′,N′-tetramethylethylenediamine)ruthenium(II) was determined by X-ray crystallography. Single crystals were obtained from the reaction mixture after being left standing at 275 K. The complex crystallized in a monoclinic system, and was characterized as: P21/n, a = 8.616(5), b = 22.925(12), c = 8.991(5)Å, β = 94.415(6)°, Z = 4, V = 1770.7(16)Å3. The R1 and wR2 values were 0.0540 and 0.1359, respectively, for 4045 reflections.