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Determination of Molybdate in Environmental Water by Ion Chromatography Coupled with a Preconcentration Method Employing a Selective Chelating Resin

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Abstract

A simple and sensitive suppressed ion chromatography (IC) method with conductivity detection for the determination of molybdate in environmental water is proposed. Molybdate in highly saline water was extracted and precocentrated. Preconcentration was accomplished by using a chelating resin using a chelating resin immobilized with carboxymethylated polyethylenimine (Presep® PolyChelate). This resin is able to trap a variety of metal elements without any interference of alkali and alkaline-earth metals. A 30-mL volume of brackish water was adjusted for appropriate pH and then flushed through 100 mg of the chelating resin. Molybdate concentrated on the resin could be easily eluted with 6 mL of 0.1 M NaOH. A large volume injection method for IC was achieved with in-line neutralization of the effluent. The determination of 0.6 μg L–1 molybdate in highly saline water was made possible with a 500-μL injection. Samples of brackish water were taken at various distances from the river mouth. The determined concenctrations of molybdate correlated closely with concentrations of chloride.

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References

  1. J. L. Johnson, H. P. Jones, and K. V. Rajagopalan, J. Biol. Chem., 1977, 252, 4994.

    Article  CAS  PubMed  Google Scholar 

  2. H. D. Belitz, W. Grosch, and P. Schieberle, “Food Chemistry”, 3rd ed., 2004, Springer, Berline.

  3. M. Anke, M. Seifert, W. Arnhold, S. Anke, and U. Schäfer, Acta Alim., 2010, 39, 12.

    Article  CAS  Google Scholar 

  4. Y. Suzuki, T. Shirasaki, Y. Nakaguchi, Y. Koike, and K. Hiraki, Bunseki Kagaku, 1994, 43, 1127.

    Article  CAS  Google Scholar 

  5. C.-Y. Huang, N.-M. Lee, S.-Y. Lin, and C.-Y. Liu, Anal. Chim. Acta, 2002, 466, 161.

    Article  CAS  Google Scholar 

  6. Y. C. Sun, J. Y. Yang, and S. R. Tzeng, Analyst, 1999, 124, 421.

    Article  CAS  Google Scholar 

  7. M. Swartz, LCGC North Am., 2010, 28, 530.

    CAS  Google Scholar 

  8. P. R. Haddad, P. N. Nesterenko, and W. Buchberger, J. Chromatogr., A, 2008, 1184, 456

  9. A. Siriraks, H. M. Kingston, and J. M. Riviello, Anal. Chem., 1990, 62, 1185.

    Article  CAS  PubMed  Google Scholar 

  10. Marheni, P. R. Haddad, and A. R. McTaggart, J. Chromatogr., 1991, 546, 221.

    Article  Google Scholar 

  11. H. Sakamoto, K. Yamamoto, T. Shirasaki, and Y. Inoue, Bunseki Kagaku, 2006, 55, 133.

    Article  CAS  Google Scholar 

  12. Y. Sohrin, S. Urushihara, S. Nakatsuka, T. Kono, E. Higo, T. Minami, K. Norisuye, S. Umetani, Anal. Chem., 2008, 80, 6267.

    Article  CAS  PubMed  Google Scholar 

  13. K. Yamamoto, H. Sakamoto, A. Yonetani, and T. Shirasaki, Nippon Kaisui Gakkaishi, 2007, 61, 260.

    CAS  Google Scholar 

  14. S. Kagaya, E. Maeba, Y. Inoue, W. Kamichatani, T. Kajiwara, H. Yanai, M. Saito, and K. Tohda, Talanta, 2009, 79, 146.

    Article  CAS  PubMed  Google Scholar 

  15. Y.-H. Li, “Compendium of Geochemistry”, 2000, Princeton University Press, NJ, 304 – 307.

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Authors and Affiliations

  1. Metrohm Japan Ltd., 7-18 Ikenohata 2-chome, 110-0008, Taito, Tokyo, Japan

    Yasuo Nakashima

  2. Nippon Filcon Co., Ltd., 2220 Ohmaru, 206-8577, Inagi, Tokyo, Japan

    Yoshinori Inoue & Waka Kamichatani

  3. College of Bioscience and Biotechnology, Chubu University, 1200 Matsumoto-cho, 487-8501, Kasugai, Aichi, Japan

    Yasuo Nakashima, Takahisa Yamamoto, Waka Kamichatani & Atsushi Yamamoto

  4. Graduate School of Science and Engineering for Research, University of Toyama, 3190 Gofuku, 930-8555, Toyama, Japan

    Sigehiro Kagaya

Authors
  1. Yasuo Nakashima
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  2. Yoshinori Inoue
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  3. Takahisa Yamamoto
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  4. Waka Kamichatani
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  5. Sigehiro Kagaya
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  6. Atsushi Yamamoto
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Correspondence to Yasuo Nakashima.

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Nakashima, Y., Inoue, Y., Yamamoto, T. et al. Determination of Molybdate in Environmental Water by Ion Chromatography Coupled with a Preconcentration Method Employing a Selective Chelating Resin. ANAL. SCI. 28, 1113–1116 (2012). https://doi.org/10.2116/analsci.28.1113

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  • DOI: https://doi.org/10.2116/analsci.28.1113

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