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A Wireless Magnetoelastic Sensor for Urinary 2-Naphthol Detection Based on the Precipitation of 2-Naphthol with Diazonium Salts

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Abstract

A wireless magnetoelastic sensor has been developed for the determination of 2-naphthol (2-NAP) in human urine. This method is based on the precipitation of 2-NAP with diazonium salts produced by the diazo-reaction of sulfamethoxazole (SMZ) with nitrite under a weak alkaline condition, resulting in a descending of the resonance frequency of a wireless magnetoelastic sensor. The frequence shift values (ΔF) of the sensor were directly proportional to the concentration in the range of 1.13 – 139 µmol L−1 for 2-NAP with a correlation coefficient of 0.997 and a detection limit of 0.340 µmol L−1. The relative standard deviations were 2.38, 2.40 and 2.44%, and the average recovery was 107% (n = 6). The proposed method has additional advantages of being less time-consuming, low cost and remote query, and can be applied for realtime and in situ monitoring of 2-NAP in human urine. It would be a benefit to extend the scope of applications of magnetoelastic sensing techniques.

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References

  1. T. T. Dong and B. K. Lee, Chemosphere, 2009, 74, 1245.

    Article  CAS  PubMed  Google Scholar 

  2. C. Achten and T. Hofmann, Sci. Total Environ., 2009, 407, 2461.

    Article  CAS  PubMed  Google Scholar 

  3. Y. Zhang and S. Tao, Atmos. Environ., 2009, 43, 812.

    Article  CAS  Google Scholar 

  4. C. L. Sisinno, A. D. Pereira Netto, E. C. Rego, and S. Lima Gdos, Cad. Saude. Publica, 2003, 19, 671.

    Article  PubMed  Google Scholar 

  5. Z. Fiala, A. Vyskocil, V. Krajak, V. Masin, S. Emminger, V. Srb, and J. Tejral, Acta Medica (Hradec Kralove), 1999, 42(Suppl.), 77.

    CAS  PubMed  Google Scholar 

  6. W. Yan, J. Chi, Z. Wang, W. Huang, and G. Zhang, Environ. Pollut., 2009, 157, 1823.

    Article  CAS  PubMed  Google Scholar 

  7. R. Preuss and J. Angerer, J. Chromatogr, B, 2004, 801, 307.

    Article  CAS  Google Scholar 

  8. M. Wilhelm, J. Hardt, C. Schulz, and J. Angerer, Int. J. Hyg. Environ. Health, 2008, 211, 447.

    Article  CAS  PubMed  Google Scholar 

  9. R. Preuss, H. M. Koch, M. Wilhelm, M. Pischetsrieder, and J. Angerer, Int. J. Hyg. Environ. Health, 2004, 207, 441.

    Article  CAS  PubMed  Google Scholar 

  10. K. Ohyama, N. Kishikawa, K. Matayoshi, L. A. Adutwum, M. Wada, K. Nakashima, and N. Kuroda, J. Sep. Sci., 2009, 32, 2218.

    Article  CAS  PubMed  Google Scholar 

  11. F. Onyemauwa, S. M. Rappaport, J. R. Sobus, D. Gajdosova, R. Wu, and S. Waidyanatha, J. Chromatogr, B, 2009, 877, 1117.

    Article  CAS  Google Scholar 

  12. C. J. Smith, C. J. Walcott, W. Huang, V. Maggio, J. Grainger, and D. G. Patterson, Jr., J. Chromatogr, B, 2002, 778, 157.

    Article  CAS  Google Scholar 

  13. L. C. Romanoff, Z. Li, K. J. Young, N. C. Blakely, 3rd, D. G. Patterson, Jr., and C. D. Sandau, J. Chromatogr, B, 2006, 835, 47.

    Article  CAS  Google Scholar 

  14. H. M. Yang, Y S. Wang, J. H. Li, G. R. Li, Y Wang, X. Tan, J. H. Xue, X. L. Xiao, and R. H. Kang, Anal. Chim. Acta, 2009, 636, 51.

    Article  CAS  PubMed  Google Scholar 

  15. R. H. Kang, Y S. Wang, H. M. Yang, G. R. Li, X. Tan, J. H. Xue, J. Q. Zhang, Y K. Yuan, L. F. Shi, and X. L. Xiao, Anal. Chim. Acta, 2010, 658, 180.

    Article  CAS  PubMed  Google Scholar 

  16. S. Li, Y Li, H. Chen, S. Horikawa, W. Shen, A. Simonian, and B. A. Chin, Biosens. Bioelectron., 2010, 26, 1313.

    Article  CAS  PubMed  Google Scholar 

  17. B. He, L. Liao, X. Xiao, S. Gao, and Y Wu, Anal. Biochem., 2011, 408, 1.

    Article  CAS  PubMed  Google Scholar 

  18. Q. Lu, H. Lin, S. Ge, S. Luo, Q. Cai, and C. A. Grimes, Anal. Chem., 2009, 81, 5846.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  19. C. A. Grimes and D. Kouzoudis, Sens. Actuators, A, 2000, 84, 205.

    Article  CAS  Google Scholar 

  20. Q. Y Cai and C. A. Grimes, Sens. Actuators, B, 2000, 71, 112.

    Article  CAS  Google Scholar 

  21. P. Pang, X. Gao, X. Xiao, W. Yang, Q. Cai, and S. Yao, Anal. Sci., 2007, 23, 463.

  22. Q. Cai, K. Zeng, C. Ruan, T. A. Desai, and C. A. Grimes, Anal. Chem., 2004, 76, 4038.

    Article  CAS  PubMed  Google Scholar 

  23. C. Ruan, K. Zeng, O. K. Varghese, and C. A. Grimes, Anal. Chem., 2003, 75, 6494.

    Article  CAS  PubMed  Google Scholar 

  24. P. Pang, S. Huang, Q. Cai, S. Yao, K. Zeng, and C. A. Grimes, Biosens. Bioelectron., 2007, 23, 295.

    Article  CAS  PubMed  Google Scholar 

  25. S. Huang, H. Yang, R. S. Lakshmanan, M. L. Johnson, I. Chen, J. Wan, H. C. Wikle, V. A. Petrenko, J. M. Barbaree, Z. Y Cheng, and B. A. Chin, Biotechnol. Bioeng., 2008, 101, 1014.

    Article  CAS  PubMed  Google Scholar 

  26. S. Huang, H. Yang, R. S. Lakshmanan, M. L. Johnson, J. Wan, I. H. Chen, H. C. Wikle, 3rd, V. A. Petrenko, J. M. Barbaree, and B. A. Chin, Biosens. Bioelectron., 2009, 24, 1730.

    Article  CAS  PubMed  Google Scholar 

  27. C. Ruan, K. Zeng, O. K. Varghese, and C. A. Grimes, Biosens. Bioelectron., 2004, 19, 1695.

    Article  CAS  PubMed  Google Scholar 

  28. L. G. Puckett, G. Barrett, D. Kouzoudis, C. Grimes, and L. G. Bachas, Biosens. Bioelectron., 2003, 18, 675.

    Article  CAS  PubMed  Google Scholar 

  29. R. Guntupalli, J. Hu, R. S. Lakshmanan, T. S. Huang, J. M. Barbaree, and B. A. Chin, Biosens. Bioelectron., 2007, 22, 1474.

    Article  CAS  PubMed  Google Scholar 

  30. X. Xiao, M. Guo, Q. Li, Q. Cai, S. Yao, and C. A. Grimes, Biosens. Bioelectron., 2008, 24, 247.

    Article  CAS  PubMed  Google Scholar 

  31. Y F Ou-Yang, Y S. Wang, X. W. Mi, J. H. Xue, and Y Wang, Anal. Sci., 2007, 23, 533.

    Article  CAS  PubMed  Google Scholar 

  32. T. I. Younis and W. A. Bashir, Talanta, 1995, 42, 1121.

    Article  CAS  PubMed  Google Scholar 

  33. S. Schmidt and C. A. Grimes, Sens. Actuators, A, 2001, 94, 189.

    Article  CAS  Google Scholar 

  34. N. Bouropoulos, D. Kouzoudis, and C. Grimes, Sens. Actuators, B, 2005, 109, 227.

    Article  CAS  Google Scholar 

  35. Y. Q. Zhai, S. Z. Zhang, J. W Xie, and C. S. Liu, Anal. Chim. Acta, 2003, 494, 71.

    Article  CAS  Google Scholar 

  36. B. Tang, X. Wang, G. Wang, C. Yu, and Z. Chen, Talanta, 2006, 69, 113.

    Article  CAS  PubMed  Google Scholar 

  37. IUPAC, “Compendium of Analytical Nomenclature-Definitive Rules”, ed. J. Inczédy, T. Lengyel, A. M. Ure, A. Gelencsér, and A. Hulanicki, 3rd ed., 1998, Blackwell, Oxford.

  38. X. P. Yang, B. F. Shi, Y. H. Zhang, J. Tang, and D. C. Cai, Spectrochim. Acta, A, 2008, 69, 400.

    Article  Google Scholar 

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Authors and Affiliations

  1. College of Public Health, University of South China, 421001, Hengyang, P. R. China

    Yu-Kun Yuan, Yong-Sheng Wang, Jin-Hua Xue, Gui-Rong Li, Rong-Hui Kang, Jin-Quan Zhang & Lin-Fei Shi

  2. The Clinical Laboratory of Chenzhou Fourth People’s Hospital, 423000, Chenzhou, P. R. China

    Yu-Kun Yuan

  3. College of Chemistry and Chemical Engineering, University of South China, 421001, Hengyang, P. R. China

    Xi-Lin Xiao

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  1. Yu-Kun Yuan
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  2. Yong-Sheng Wang
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  3. Xi-Lin Xiao
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  4. Jin-Hua Xue
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  5. Gui-Rong Li
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  7. Jin-Quan Zhang
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  8. Lin-Fei Shi
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Correspondence to Yong-Sheng Wang.

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Yuan, YK., Wang, YS., Xiao, XL. et al. A Wireless Magnetoelastic Sensor for Urinary 2-Naphthol Detection Based on the Precipitation of 2-Naphthol with Diazonium Salts. ANAL. SCI. 27, 517–521 (2011). https://doi.org/10.2116/analsci.27.517

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  • DOI: https://doi.org/10.2116/analsci.27.517

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