Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌)
Online ISSN : 1882-1022
Print ISSN : 0914-5400
ISSN-L : 0914-5400
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Yb2O3-SiO2 系焼結助剤を用いたガス圧焼結 Si3N4 の高温特性の Yb2O3/SiO2 モル比依存性
山本 博一秋山 勝徳平田 武彦村上 勇一郎
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2005 年 113 巻 1316 号 p. 325-329

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High-temperature characteristics (especially high-temperature strength and oxidation resistance) of gas pressure sintered Si3N4 ceramics using Yb2O3-SiO2 additives were evaluated. The high temperature characteristic of Si3N4 depended on the Yb2O3/SiO2 molar ratio of additives. High 1500°C bending strength of 395 MPa was obtained for sintered bodies with 10.0 mass% addition of additives with Yb2O3/SiO2 molar ratio of 1.0. Also, small weight change (13.2 g/m2) during oxidation at 1300°C for 300 h was obtained in this sintered body. This is considered to be due to the precipitation of Yb4Si2N2O7 and Yb2Si2O7 phase in the grain boundary glass phase, as induced by a crystallization process.

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© 2005 The Ceramic Society of Japan
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