Evaluation of Corrosion inhibition properties of pharmaceutically active compound Cefotaxime sodium on mild steel surface in sulfuric acid medium

Sudhish Kumar Shukla; Somya Tanwer

doi:10.18596/jotcsa.972325

Research Article

Year 2021, Volume: 8 Issue: 4, 1099 - 1110, 30.11.2021

Sudhish Kumar Shukla Somya Tanwer

https://doi.org/10.18596/jotcsa.972325

Cited By: 3

Abstract

References

1. Adejoro IA, Ojo FK, Obafemi SK. Corrosion inhibition potentials of ampicillin for mild steel in hydrochloric acid solution. Journal of Taibah University for Science. 2015 Apr;9(2):196–202.
2. Sastri V. Types of corrosion inhibitor for managing corrosion in underground pipelines. Woodhead Publishing Limited; 2014.
3. Kuznetsov Y. Organic Inhibitors of corrosion of Metals. Thomas J, editor. Springer Science+ Business Media, LLC; 1996.
4. Roberge P. Handbook of Corrosion Engineering. 2nd Edition. McGraw-Hill Companies; 2012.
5. Kruger J. Cost of Metallic Corrosion. In: Revie RW, editor. Uhlig’s Corrosion Handbook [Internet]. Hoboken, NJ, USA: John Wiley & Sons, Inc.; 2011 [cited 2021 Sep 25]. p. 15–20. ISBN: 978-0-470-08032-0.
6. Singh AK, Singh S, Ebenso EE. Cefacetrile as corrosion inhibitors for mild steel in acidic media. International Journal of Electrochemical Science. 2011;6:5689–700.
7. Anonymous. The Annual Cost of Corrosion to Ohio [Internet]. 2007. Available from: http://www.brown.senate.gov/imo/media/doc/OhioCorrosion.pdf
8. Bhaskaran, R, Palaniswamy, N, Rengaswamy, NS. COST OF CORROSION AND CORROSION AUDITING IN INDIAN INDUSTRIES. Corrosion Reviews. 2009 Dec;27(Supplement):1–35.
9. NACE International. NACE-international Cost of corrosion study unveiled. Mater Perform. 2002;(July):20.
10. Ebenso EE, Khaled K, Shukla SK, Singh AK, Eddy N, Saracoglu M, et al. Quantum chemical investigations on quinoline derivatives as effective corrosion inhibitors for mild steel in acidic medium. Int J Electrochem Sci. 2012.
11. Raja PB, Ismail M, Ghoreishiamiri S, Mirza J, Ismail MC, Kakooei S, et al. Reviews on Corrosion Inhibitors: A Short View. Chemical Engineering Communications. 2016 Sep 1;203(9):1145–56.
12. Dwivedi A, Bharti PK, Shukla SK. An overview of the polymeric material that can be used to prevent Metal corrosion: A Review. Journal of Turkish Chemical Society Section A: Chemistry, 2021; 8(3):863-72.
13. Palou R, Olivares-Xomelt O, Likhanova N. Environmentally Friendly Corrosion Inhibitors. In: Green Corrosion Inhibitors [Internet]. Hoboken, NJ, USA: John Wiley & Sons, Inc.; 2011 [cited 2021 Sep 25]. p. 257–303.
14. Abdullah Dar M. A review: plant extracts and oils as corrosion inhibitors in aggressive media. Ind Lubrication and Tribology. 2011 Jun 21;63(4):227–33.
15. Umoren SA. Polymers as Corrosion Inhibitors for Metals in Different Media - A Review. TOCORRJ. 2009 Jun 25;2(1):175–88.
16. Chigondo M, Chigondo F. Recent Natural Corrosion Inhibitors for Mild Steel: An Overview. Journal of Chemistry. 2016;2016:1–7.
17. Shukla SK. Corrosion inhibitive effect of N-(6-methoxyquinolin-8-yl)-pentane-1, 4-diamine on mild steel/sulphuric acid solution interface. J Mater Environ Sci. 2015;6:1779–86.
18. Ji G, Shukla SK, Dwivedi P, Sundaram S, Ebenso EE, Prakash R. Parthenium hysterophorus plant extract as an efficient green corrosion inhibitor for mild steel in acidic environment. International Journal of Electrochemical Science. 2012;7(10):9933–45.
19. Gece G. Drugs: A review of promising novel corrosion inhibitors. Corrosion Science. 2011 Dec;53(12):3873–98.
20. Singh AK, Shukla SK, Quraishi MA. Corrosion behavior of mild steel in sulphuric acid solutionin presence of ceftazidime. Int. J. Electrochem. Sci. 2011; 6(11): 5802-14.
21. Dwivedi A, Bharti P, Shukla S. Surface assimilation and corrosion inhibition characteristic of water soluble Polyvinyl Alcohol on mild steel surface in 0.5M HCl solution. Journal of the Turkish Chemical Society Section A: Chemistry. 2021 Jan 11;219–30.
22. Reza I, Saleemi A, Naveed S. Corrosion inhibition of mild steel in HCl solution by Tinidazole. Polish Journal of Chemical Technology. 2011 Jan 1;13(1):67–71.
23. Singh AK, Shukla SK, Singh M, Quraishi MA. Inhibitive effect of ceftazidime on corrosion of mild steel in hydrochloric acid solution. Materials Chemistry and Physics. 2011 Sep;129(1–2):68–76.
24. Shukla SK, Quraishi MA. Ceftriaxone: a novel corrosion inhibitor for mild steel in hydrochloric acid. J Appl Electrochem. 2009 Sep;39(9):1517–23.
25. Shukla SK, Quraishi MA. Cefalexin drug: A new and efficient corrosion inhibitor for mild steel in hydrochloric acid solution. Materials Chemistry and Physics. 2010 Mar;120(1):142–7.
26. Prasanna BM, Praveen BM, Hebbar N, Venkatesha TV, Tandon HC, Abd Hamid SB. Electrochemical study on inhibitory effect of Aspirin on mild steel in 1 M hydrochloric acid. Journal of the Association of Arab Universities for Basic and Applied Sciences. 2017 Feb;22(1):62–9.
27. Shukla SK, Quraishi MA. The effects of pharmaceutically active compound doxycycline on the corrosion of mild steel in hydrochloric acid solution. Corrosion Science. 2010 Feb;52(2):314–21.
28. Aronson JK, editor. Polystyrene sulfonates. In: Meyler’s side effects of drugs: the international encyclopedia of adverse drug reactions and interactions. 16. ed. Amsterdam Boston Heidelberg: Elsevier; 20. ISBN: 978-0-444-53717-1.
29. Shukla SK, Quraishi MA. Cefotaxime sodium: A new and efficient corrosion inhibitor for mild steel in hydrochloric acid solution. Corrosion Science. 2009 May;51(5):1007–11.
30. Salem H, Samir E. Determination of cefotaxime, cefoperazone, ceftazidime and cefadroxil using surface plasmon resonance band of silver nanoparticles. Braz J Pharm Sci [Internet]. 2018 Nov 29 [cited 2021 Sep 25];54(3).
31. SANKAR SA, Kumar AS, RAMESHKUMAR S. Corrosion Inhibition Of Mild Steel In 0.5 M H2SO4 By 1-(2-Methyl-4-(2-Methylphenyldiazenyl) Phenyl) Azonapthalen-2-Ol. Am. J. Eng. Res. 2013; 2(9):17-22.
32. Shukla SK, Quraishi MA. Effect of some substituted anilines-formaldehyde polymers on mild steel corrosion in hydrochloric acid medium. J Appl Polym Sci. 2011;5130-7.
33. Tang L. A study of the polarisation techniques for corrosion rate measurement in a steel-concrete system. 9DBMC. 2002;158:1–10.
34. Harabor I, Nechifor G, Branzoi V, Branzoi F. Investigation of some organic polymers as corrosion inhibitors on carbon steel in cooling water systems. Univ Politeh Buchar Sci Bull Series B-Chem Mater Sci. 2016;78(3):145–60.
35. Ji G, Shukla SK, Ebenso EE, Prakash R. Argimone maxicana leaf extract for inhibition of mild steel corrosion in sulfuric acid solution. Int. J. Electrochem. Sci. 2013;8(8):10878–89.
36. Shukla S, Ebenso E. Corrosion inhibition, adsorption behaviour and thermodynamic properties of streptomycin on mild steel in hydrochloric acid medium. International Journal of Electrochemical Science. 2011;6:3277–91.
37. Khedr MGA, Lashien AMS. The role of metal cations in the corrosion and corrosion inhibition of aluminium in aqueous solutions. Corrosion Science. 1992 Jan;33(1):137–51.
38. Schorr M, Yahalom J. The significance of the energy of activation for the dissolution reaction of metal in acids. Corros Sci. 1972;867–8.
39. Umoren SA, Solomon MM, Udosoro II, Udoh AP. Synergistic and antagonistic effects between halide ions and carboxymethyl cellulose for the corrosion inhibition of mild steel in sulphuric acid solution. Cellulose. 2010 Jun;17(3):635–48.
40. Solomon MM, Umoren SA, Udosoro II, Udoh AP. Inhibitive and adsorption behaviour of carboxymethyl cellulose on mild steel corrosion in sulphuric acid solution. Corrosion Science. 2010 Apr;52(4):1317–25.
41. Szauer T, Brandt A. On the role of fatty acid in adsorption and corrosion inhibition of iron by amine—fatty acid salts in acidic solution. Electrochimica Acta. 1981 Sep;26(9):1257–60.
42. Abd El Rehim SS, Hassan HH, Amin MA. Corrosion inhibition of aluminum by 1,1(lauryl amido)propyl ammonium chloride in HCl solution. Materials Chemistry and Physics. 2001 Apr;70(1):64–72.
43. Ebenso EE. Synergistic effect of halide ions on the corrosion inhibition of aluminium in H2SO4 using 2-acetylphenothiazine. Materials Chemistry and Physics. 2003 Mar;79(1):58–70.
44. Ebenso EE, Obot IB. Inhibitive properties, thermodynamic characterization and quantum chemical studies of secnidazole on mild steel corrosion in acidic medium. Int J Electrochem Sci. 2010;5(12):2012–35.
45. Hermas A-EA, Elnady AM, Ali RM. Corrosion inhibition of stainless steel in sulfuric acid solution containing sulfide ions. ACMM. 2019 May 7;66(3):360–8.
46. Madkour LH, Elshamy IH. Experimental and computational studies on the inhibition performances of benzimidazole and its derivatives for the corrosion of copper in nitric acid. Int J Ind Chem. 2016 Jun;7(2):195–221.
47. Murulana LC, Singh AK, Shukla SK, Kabanda MM, Ebenso EE. Experimental and Quantum Chemical Studies of Some Bis(trifluoromethyl-sulfonyl) Imide Imidazolium-Based Ionic Liquids as Corrosion Inhibitors for Mild Steel in Hydrochloric Acid Solution. Ind Eng Chem Res. 2012 Oct 10;51(40):13282–99.
48. Abd-El-Khalek DE, Hassan HHAM, Ramadan SR. Water-soluble sulfonated polyaniline as multifunctional scaling inhibitor for crystallization control in industrial applications. Chemical Engineering Research and Design. 2021 May;169:135–41.
49. Rahmani H, Meletis EI. Corrosion Inhibition of Brazing Cu-Ag Alloy with 1,2,3-Benzotriazole and 2,5-Dimercapto-1,3,4-Thiadiazole. Corrosion. 2021 Jan 1;77(1):29–39.
50. Tsoeunyane MG, Makhatha ME, Arotiba OA. Corrosion Inhibition of Mild Steel by Poly(butylene succinate)-L-histidine Extended with 1,6-diisocynatohexane Polymer Composite in 1 M HCl. International Journal of Corrosion. 2019 Mar 3;2019:1–12.

Evaluation of Corrosion inhibition properties of pharmaceutically active compound Cefotaxime sodium on mild steel surface in sulfuric acid medium

Year 2021, Volume: 8 Issue: 4, 1099 - 1110, 30.11.2021

Sudhish Kumar Shukla Somya Tanwer

https://doi.org/10.18596/jotcsa.972325

Cited By: 3

Abstract

Cefotaxime sodium is applied in various concentrations in 0.5M sulphuric acid towards the mild steel and analyzed through weight loss, potentiodynamic polarization and EIS studies at 298 to 338oK. It gives good inhibition activity at lower temperature. Activation parameters, Gibbs free energy, Enthalpy and entropy of the reaction has been calculated and found that the inhibition process follows physical adsorption on the surface. Adsorption process follows langmuir’s adsorption isotherm. The inhibition behavior on mild steel surface is supplemented by the surface study through atomic force microscopy and found that the inhibited surface have less roughness than the uninhibited surface.

Keywords

Eco-friendly inhibitors, weight loss, EIS, AFM

References

1. Adejoro IA, Ojo FK, Obafemi SK. Corrosion inhibition potentials of ampicillin for mild steel in hydrochloric acid solution. Journal of Taibah University for Science. 2015 Apr;9(2):196–202.
2. Sastri V. Types of corrosion inhibitor for managing corrosion in underground pipelines. Woodhead Publishing Limited; 2014.
3. Kuznetsov Y. Organic Inhibitors of corrosion of Metals. Thomas J, editor. Springer Science+ Business Media, LLC; 1996.
4. Roberge P. Handbook of Corrosion Engineering. 2nd Edition. McGraw-Hill Companies; 2012.
5. Kruger J. Cost of Metallic Corrosion. In: Revie RW, editor. Uhlig’s Corrosion Handbook [Internet]. Hoboken, NJ, USA: John Wiley & Sons, Inc.; 2011 [cited 2021 Sep 25]. p. 15–20. ISBN: 978-0-470-08032-0.
6. Singh AK, Singh S, Ebenso EE. Cefacetrile as corrosion inhibitors for mild steel in acidic media. International Journal of Electrochemical Science. 2011;6:5689–700.
7. Anonymous. The Annual Cost of Corrosion to Ohio [Internet]. 2007. Available from: http://www.brown.senate.gov/imo/media/doc/OhioCorrosion.pdf
8. Bhaskaran, R, Palaniswamy, N, Rengaswamy, NS. COST OF CORROSION AND CORROSION AUDITING IN INDIAN INDUSTRIES. Corrosion Reviews. 2009 Dec;27(Supplement):1–35.
9. NACE International. NACE-international Cost of corrosion study unveiled. Mater Perform. 2002;(July):20.
10. Ebenso EE, Khaled K, Shukla SK, Singh AK, Eddy N, Saracoglu M, et al. Quantum chemical investigations on quinoline derivatives as effective corrosion inhibitors for mild steel in acidic medium. Int J Electrochem Sci. 2012.
11. Raja PB, Ismail M, Ghoreishiamiri S, Mirza J, Ismail MC, Kakooei S, et al. Reviews on Corrosion Inhibitors: A Short View. Chemical Engineering Communications. 2016 Sep 1;203(9):1145–56.
12. Dwivedi A, Bharti PK, Shukla SK. An overview of the polymeric material that can be used to prevent Metal corrosion: A Review. Journal of Turkish Chemical Society Section A: Chemistry, 2021; 8(3):863-72.
13. Palou R, Olivares-Xomelt O, Likhanova N. Environmentally Friendly Corrosion Inhibitors. In: Green Corrosion Inhibitors [Internet]. Hoboken, NJ, USA: John Wiley & Sons, Inc.; 2011 [cited 2021 Sep 25]. p. 257–303.
14. Abdullah Dar M. A review: plant extracts and oils as corrosion inhibitors in aggressive media. Ind Lubrication and Tribology. 2011 Jun 21;63(4):227–33.
15. Umoren SA. Polymers as Corrosion Inhibitors for Metals in Different Media - A Review. TOCORRJ. 2009 Jun 25;2(1):175–88.
16. Chigondo M, Chigondo F. Recent Natural Corrosion Inhibitors for Mild Steel: An Overview. Journal of Chemistry. 2016;2016:1–7.
17. Shukla SK. Corrosion inhibitive effect of N-(6-methoxyquinolin-8-yl)-pentane-1, 4-diamine on mild steel/sulphuric acid solution interface. J Mater Environ Sci. 2015;6:1779–86.
18. Ji G, Shukla SK, Dwivedi P, Sundaram S, Ebenso EE, Prakash R. Parthenium hysterophorus plant extract as an efficient green corrosion inhibitor for mild steel in acidic environment. International Journal of Electrochemical Science. 2012;7(10):9933–45.
19. Gece G. Drugs: A review of promising novel corrosion inhibitors. Corrosion Science. 2011 Dec;53(12):3873–98.
20. Singh AK, Shukla SK, Quraishi MA. Corrosion behavior of mild steel in sulphuric acid solutionin presence of ceftazidime. Int. J. Electrochem. Sci. 2011; 6(11): 5802-14.
21. Dwivedi A, Bharti P, Shukla S. Surface assimilation and corrosion inhibition characteristic of water soluble Polyvinyl Alcohol on mild steel surface in 0.5M HCl solution. Journal of the Turkish Chemical Society Section A: Chemistry. 2021 Jan 11;219–30.
22. Reza I, Saleemi A, Naveed S. Corrosion inhibition of mild steel in HCl solution by Tinidazole. Polish Journal of Chemical Technology. 2011 Jan 1;13(1):67–71.
23. Singh AK, Shukla SK, Singh M, Quraishi MA. Inhibitive effect of ceftazidime on corrosion of mild steel in hydrochloric acid solution. Materials Chemistry and Physics. 2011 Sep;129(1–2):68–76.
24. Shukla SK, Quraishi MA. Ceftriaxone: a novel corrosion inhibitor for mild steel in hydrochloric acid. J Appl Electrochem. 2009 Sep;39(9):1517–23.
25. Shukla SK, Quraishi MA. Cefalexin drug: A new and efficient corrosion inhibitor for mild steel in hydrochloric acid solution. Materials Chemistry and Physics. 2010 Mar;120(1):142–7.
26. Prasanna BM, Praveen BM, Hebbar N, Venkatesha TV, Tandon HC, Abd Hamid SB. Electrochemical study on inhibitory effect of Aspirin on mild steel in 1 M hydrochloric acid. Journal of the Association of Arab Universities for Basic and Applied Sciences. 2017 Feb;22(1):62–9.
27. Shukla SK, Quraishi MA. The effects of pharmaceutically active compound doxycycline on the corrosion of mild steel in hydrochloric acid solution. Corrosion Science. 2010 Feb;52(2):314–21.
28. Aronson JK, editor. Polystyrene sulfonates. In: Meyler’s side effects of drugs: the international encyclopedia of adverse drug reactions and interactions. 16. ed. Amsterdam Boston Heidelberg: Elsevier; 20. ISBN: 978-0-444-53717-1.
29. Shukla SK, Quraishi MA. Cefotaxime sodium: A new and efficient corrosion inhibitor for mild steel in hydrochloric acid solution. Corrosion Science. 2009 May;51(5):1007–11.
30. Salem H, Samir E. Determination of cefotaxime, cefoperazone, ceftazidime and cefadroxil using surface plasmon resonance band of silver nanoparticles. Braz J Pharm Sci [Internet]. 2018 Nov 29 [cited 2021 Sep 25];54(3).
31. SANKAR SA, Kumar AS, RAMESHKUMAR S. Corrosion Inhibition Of Mild Steel In 0.5 M H2SO4 By 1-(2-Methyl-4-(2-Methylphenyldiazenyl) Phenyl) Azonapthalen-2-Ol. Am. J. Eng. Res. 2013; 2(9):17-22.
32. Shukla SK, Quraishi MA. Effect of some substituted anilines-formaldehyde polymers on mild steel corrosion in hydrochloric acid medium. J Appl Polym Sci. 2011;5130-7.
33. Tang L. A study of the polarisation techniques for corrosion rate measurement in a steel-concrete system. 9DBMC. 2002;158:1–10.
34. Harabor I, Nechifor G, Branzoi V, Branzoi F. Investigation of some organic polymers as corrosion inhibitors on carbon steel in cooling water systems. Univ Politeh Buchar Sci Bull Series B-Chem Mater Sci. 2016;78(3):145–60.
35. Ji G, Shukla SK, Ebenso EE, Prakash R. Argimone maxicana leaf extract for inhibition of mild steel corrosion in sulfuric acid solution. Int. J. Electrochem. Sci. 2013;8(8):10878–89.
36. Shukla S, Ebenso E. Corrosion inhibition, adsorption behaviour and thermodynamic properties of streptomycin on mild steel in hydrochloric acid medium. International Journal of Electrochemical Science. 2011;6:3277–91.
37. Khedr MGA, Lashien AMS. The role of metal cations in the corrosion and corrosion inhibition of aluminium in aqueous solutions. Corrosion Science. 1992 Jan;33(1):137–51.
38. Schorr M, Yahalom J. The significance of the energy of activation for the dissolution reaction of metal in acids. Corros Sci. 1972;867–8.
39. Umoren SA, Solomon MM, Udosoro II, Udoh AP. Synergistic and antagonistic effects between halide ions and carboxymethyl cellulose for the corrosion inhibition of mild steel in sulphuric acid solution. Cellulose. 2010 Jun;17(3):635–48.
40. Solomon MM, Umoren SA, Udosoro II, Udoh AP. Inhibitive and adsorption behaviour of carboxymethyl cellulose on mild steel corrosion in sulphuric acid solution. Corrosion Science. 2010 Apr;52(4):1317–25.
41. Szauer T, Brandt A. On the role of fatty acid in adsorption and corrosion inhibition of iron by amine—fatty acid salts in acidic solution. Electrochimica Acta. 1981 Sep;26(9):1257–60.
42. Abd El Rehim SS, Hassan HH, Amin MA. Corrosion inhibition of aluminum by 1,1(lauryl amido)propyl ammonium chloride in HCl solution. Materials Chemistry and Physics. 2001 Apr;70(1):64–72.
43. Ebenso EE. Synergistic effect of halide ions on the corrosion inhibition of aluminium in H2SO4 using 2-acetylphenothiazine. Materials Chemistry and Physics. 2003 Mar;79(1):58–70.
44. Ebenso EE, Obot IB. Inhibitive properties, thermodynamic characterization and quantum chemical studies of secnidazole on mild steel corrosion in acidic medium. Int J Electrochem Sci. 2010;5(12):2012–35.
45. Hermas A-EA, Elnady AM, Ali RM. Corrosion inhibition of stainless steel in sulfuric acid solution containing sulfide ions. ACMM. 2019 May 7;66(3):360–8.
46. Madkour LH, Elshamy IH. Experimental and computational studies on the inhibition performances of benzimidazole and its derivatives for the corrosion of copper in nitric acid. Int J Ind Chem. 2016 Jun;7(2):195–221.
47. Murulana LC, Singh AK, Shukla SK, Kabanda MM, Ebenso EE. Experimental and Quantum Chemical Studies of Some Bis(trifluoromethyl-sulfonyl) Imide Imidazolium-Based Ionic Liquids as Corrosion Inhibitors for Mild Steel in Hydrochloric Acid Solution. Ind Eng Chem Res. 2012 Oct 10;51(40):13282–99.
48. Abd-El-Khalek DE, Hassan HHAM, Ramadan SR. Water-soluble sulfonated polyaniline as multifunctional scaling inhibitor for crystallization control in industrial applications. Chemical Engineering Research and Design. 2021 May;169:135–41.
49. Rahmani H, Meletis EI. Corrosion Inhibition of Brazing Cu-Ag Alloy with 1,2,3-Benzotriazole and 2,5-Dimercapto-1,3,4-Thiadiazole. Corrosion. 2021 Jan 1;77(1):29–39.
50. Tsoeunyane MG, Makhatha ME, Arotiba OA. Corrosion Inhibition of Mild Steel by Poly(butylene succinate)-L-histidine Extended with 1,6-diisocynatohexane Polymer Composite in 1 M HCl. International Journal of Corrosion. 2019 Mar 3;2019:1–12.

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Details

Primary Language	English
Journal Section	Articles
Authors	Sudhish Kumar Shukla 0000-0003-1867-396X Somya Tanwer 0000-0002-8227-8668
Publication Date	November 30, 2021
Submission Date	July 16, 2021
Acceptance Date	September 22, 2021
Published in Issue	Year 2021 Volume: 8 Issue: 4

Cite

Vancouver	Kumar Shukla S, Tanwer S. Evaluation of Corrosion inhibition properties of pharmaceutically active compound Cefotaxime sodium on mild steel surface in sulfuric acid medium. JOTCSA. 2021;8(4):1099-110.

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