Thin Films of Silver Nanowires for Flexible, Transparent, and Conductive (FTC) Electrodes

- Junaidi (1), Kemal Maulidiasani (2), Kuwat Triyana (3), - Khairurrijal (4)
(1) Departement of Physics, Lampung University, Lampung, 35145 Indonesia
(2) Departement of Physics, Gadjah Mada University, Yogyakarta, 55281 Indonesia
(3) Departement of Physics, Gadjah Mada University, Yogyakarta, 55281 Indonesia
(4) Departement of Physics, Bandung Institute of Technology, Bandung, 40132 Indonesia
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How to cite (IJASEIT) :
Junaidi, -, et al. “Thin Films of Silver Nanowires for Flexible, Transparent, and Conductive (FTC) Electrodes”. International Journal on Advanced Science, Engineering and Information Technology, vol. 10, no. 1, Feb. 2020, pp. 137-44, doi:10.18517/ijaseit.10.1.5889.
In this research, we have succeeded in making thin-films for flexible, transparent, and conductive (FTC) electrodes based on silver nanowires. The synthesis of silver nanowires is carried out at low temperatures, namely at 60 to 130 oC. The materials used in the synthesis of AgNWs are polyvinyl pyrrolidone (PVP) as a capping agent and Iron (III) chloride hexahydrate (FeCl3”¢6H2O) as a precursor to controlling the size of silver nanowires. Furthermore, the silver nanowires colloid then created a thin layer over the polycarbonate (PC) substrate by the roll to roll process.  The Result shows that the formation of silver nanowires occurred at low temperatures of about 90 °C. The optimum condition of silver nanowires has obtained synthesis at the temperature of 110 °C with the average diameter of (100 ± 20) nm and length (30 ± 15) μm. The silver nanowires will increase in length and diameter at low-temperature and decrease at high temperatures .The transmittance of FTC film silver nanowires about 76-95% at a wavelength of 550 nm. The absorbance coefficient of FTC film silver nanowires has increased from 2.7 to 29.2 cm-1 at wavelength range 400 to 700 nm. The sheet resistance of the FTC film by varying the number of layers obtained of 905.2, 340.7, 21.9, and 3.4 Ω.sq-1 with the transmittance obtained at 76.7 to 95.8%. The number of layers of silver nanowires will increase the sheet resistance and decrease the optical transmittance of the FTC film.

B. Wang, L. Zhang, and X. Zhou, “Synthesis of silver nanocubes as a SERS substrate for the determination of pesticide paraoxon and thiram,” Spectrochim. Acta - Part A Mol. Biomol. Spectrosc., vol. 121, pp. 63-69, 2014.

B. Sun, X. Jiang, S. Dai, and Z. Du, “Single-crystal silver nanowires: Preparation and Surface-enhanced Raman Scattering (SERS) property,” Mater. Lett., vol. 63, no. 29, pp. 2570-2573, 2009.

G. Y. Margulis et al., “Spray deposition of silver nanowire electrodes for semitransparent solid-state dye-sensitized solar cells,” Adv. Energy Mater., vol. 3, no. 12, pp. 1657-1663, 2013.

M. Song, J.-K. Kim, S.-Y. Yang, and J.-W. Kang, “Solution-processed silver nanowires as a transparent conducting electrode for air-stable inverted organic solar cells,” Thin Solid Films, vol. 573, pp. 14-17, 2014.

T. Cheng, Y. Zhang, W. Lai, Y. Chen, and W. Huang, “A Rapid Synthesis of High Aspect Ratio Silver Nanowires for High-Performance Transparent Electrodes,” Chinese J. Chem., vol. 33, no. 1, pp. 147-151, 2015.

H. Hosseinzadeh Khaligh, K. Liew, Y. Han, N. M. Abukhdeir, and I. A. Goldthorpe, “Silver nanowire transparent electrodes for liquid crystal-based smart windows,” Sol. Energy Mater. Sol. Cells, vol. 132, pp. 337-341, 2015.

X. Yu, X. Yu, J. Zhiang, D. Zhang, J. Ni, H. Cai, D. Zhang, and Y. Zhao, “Investigation of light transmission and scattering properties in silver nanowire mesh transparent electrodes,” Mater. Lett., vol. 145, pp. 219-233, 2015.

M. Cann, M.J. Large, S.J. Hanley, D. Milne, T. Sato, H. Chan, I. Jurewicz, and A.B. Dalton, “High Performance Transparent Multi-Touch Sensors Based on Silver Nanowires,” Mater. Today Commun., vol. 7, pp. 42-50, 2016.

A. T. Fried, S. W. Tanamachi, J. T. Abrahamson, and R. J. Monson, “Qualification of silver nanowire transparent conductive films for touch panel applications,” 14th IEEE Int. Conf. Nanotechnol., pp. 24-26, 2014.

M. Chalh, S. Vedraine, B. Lucas, and B. Ratier, “Plasmonic Ag nanowire network embedded in zinc oxide nanoparticles for inverted organic solar cells electrode,” Sol. Energy Mater. Sol. Cells, vol. 152, pp. 34-41, 2016.

Junaidi, K. Triyana, H. Hui, L. Y. L. Wu, E. Suharyadi, and Harsojo, “The silver nanowires synthesized using different molecule weight of polyvinyl pyrrolidone for controlling diameter and length by one-pot polyol method,” AIP Conference Proceedings, vol. 1746, no. 020014, 2016.

Junaidi, M. Yunus, Harsojo, E. Suharyadi, and K. Triyana, “Effect of Stirring Rate on The Synthesis Silver Nanowires using Polyvinyl Alcohol as A Capping Agent by Polyol Process,” Int. J. Adv. Sci. Eng. Inf. Technol., vol. 6, no. 3, pp. 365-369, 2016.

J.-Y. Lin, Y.-L. Hsueh, J.-J. Huang, and J.-R. Wu, “Effect of silver nitrate concentration of silver nanowires synthesized using a polyol method and their application as transparent conductive films,” Thin Solid Films, vol. 584, pp. 243-247, 2015.

Y. Sun, Y. Yin, B. T. Mayers, T. Herricks, and Y. Xia, “Uniform silver nanowires synthesis by reducing AgNO3 with ethylene glycol in the presence of seeds and poly (vinyl pyrrolidone),” Chem. Mater., vol. 14, no. 11, pp. 4736-4745, 2002.

Y. Sun, B. Mayers, T. Herricks, and Y. Xia, “Polyol synthesis of uniform silver nanowires: A plausible growth mechanism and the supporting evidence,” Nano Lett., vol. 3, no. 7, pp. 955-960, 2003.

Junaidi, K. Triyana, H. Sosiati, E. Suharyadi, and Harsojo, “Effect of Temperature on Silver Nanorods Synthesized by Polyol Method,” Adv. Mater. Res., vol. 1123, pp. 256-259, 2015.

S. H. Kim, B. S. Choi, K. Kang, Y.-S. Choi, and S. I. Yang, “Low temperature synthesis and growth mechanism of Ag nanowires,” J. Alloys Compd., vol. 433, no. 1-2, pp. 261-264, 2007.

K. S. Teppei Araki, Jinting Jiu, Masaya Nogi, Hirotaka Koga, Shijo Nagao, Tohru Sugahara, “Low Haze Transparent Electrodes and Highly Conducting Air-Dried Films with Ultra-Long Silver Nanowires Synthesized by One-Step Polyol Method,” Nano Res., vol. 7, pp. 236-245, 2014.

S. De, T. M. Higgins, P. E. Lyons, E. M. Doherty, P. N. Nirmalraj, W. J. Blau, J. J. Boland, and J. N. Coleman, “Silver Nanowire Networks as Flexible, Transparent, Conducting Films: Extremely High DC to Optical Conductivity Ratios,” ACS Nano, vol. 3, no. 7, pp. 1767-1774, 2009.

Y.-H. Duan, Y. Duan, X. Wang, D. Yang, Y.-Q. Yang, P. Chen, F.-B. Sun, K.-W. Xue, and Y. Zhao, “Highly flexible peeled-off silver nanowire transparent anode using in organic light-emitting devices,” Appl. Surf. Sci., vol. 351, pp. 445-450, 2015.

Juniadi, K. Triyana, Harsojo, and E. Suharyadi, “High-Performance Silver Nanowire Film on Flexible Substrate Prepared by Meyer-rod Coating,” Mater. Sci. Eng., vol. 202, pp. 1-7, 2017.

H. Mao, J. Feng, X. Ma, C. Wu, and X. Zhao, “One-dimensional silver nanowires synthesized by self-seeding polyol process,” J. Nanoparticle Res., vol. 14, no. 6, pp. 1-15, 2012.

K. Triyana, E. Suharyadi, and L. Y. Wu, “The Roles of Polyvinyl Alcohol (PVA) as the Capping Agent on the Polyol Method for Synthesizing Silver Nanowires,” J. nano Res., vol. 49, pp. 174-180, 2017.

D. Preetha, R. Arun, P. Kumari, and C. Aarti, “Synthesis and Characterization of Silver Nanoparticles Using Cannonball Leaves and Its Cytotoxic Activity Against Mcf-7 Cell Line,” J. Nanotechnol., vol. 6, no. 8, 2014.

Junaidi, K. Triyana, Harsojo, and E. Suharyadi, “Chloride ion addition for controlling shapes and properties of silver nanorods capped by polyvinyl alcohol synthesized by polyol method,” AIP Conference Proceedings,vol. 1725, no. 020092, 2016.

B. Wiley, Y. Sun, and Y. Xia, “Synthesis of silver nanostructures with controlled shapes and properties,” Acc. Chem. Res., vol. 40, no. 10, pp. 1067-1076, 2007.

Y. Mao, C. Wang, and H. Yang, “Rapid and uniform synthesis of silver nanowires via rice-shaped silver nucleant,” Mater. Lett., vol. 142, pp. 102-105, 2015.

Y. Zhang, J. Wang, and P. Yang, “Convenient synthesis of Ag nanowires with tunable length and morphology,” Mater. Res. Bull., vol. 48, no. 2, pp. 461-468, 2013.

Y. Xia, Y. Xiong, B. Lim, and S. E. Skrabalak, “Shape-Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics?” Angew. Chemie Int. Ed., vol. 48, no. 1, pp. 60-103, 2009.

O. G. Abdullah, B. K. Aziz, and S. A. Hussen, “Optical Characterization of Polyvinyl alcohol - Ammonium Nitrate Polymer Electrolytes Films,” Chem. Mater. Res., vol. 3, no. 9, pp. 84-91, 2013.

G. Attia and M. F. H. A. El-kader, “Structural, Optical and Thermal Characterization of PVA/2HEC Polyblend Films,” Int. J. Electrochem. Sci., vol. 8, pp. 5672-5687, 2013.

H. A. Wahab, A. A. Salama, A. A. El-saeid, O. Nur, M. Willander, and I. K. Battisha, “Results in Physics Optical , structural and morphological studies of ( ZnO ) nano-rod thin films for biosensor applications using sol gel technique,” RESULTS Phys., vol. 3, pp. 46-51, 2013.

S. S. Gasaymeh, S. Radiman, L. Y. Heng, E. Saion, and G. H. M. Saeed, “Synthesis and Characterization of Silver / Polyvinilpirrolidone (Ag/PVP) Nanoparticles Using Gamma Irradiation Techniques,” Am. J. Appl. Sc., vol. 7, no. 10, pp. 31-41, 2010.

N. Budhiraja, A. Sharma, S. Dahiya, and R. Parmar, “Synthesis and optical characteristics of silver nanoparticles on different substrates,” ILCPA, vol. 19, pp. 80-88, 2013.

T. Arumanayagam and P. Murugakoothan, “Optical Conductivity and Dielectric Response of an Organic Aminopyridine NLO Single Crystal,” J. Miner. Mater. Char. Eng., vol. 10, no. 13, pp. 1225-1231, 2011.

N. A. Bakr, A.M. Funde, V. S. Waman, M. M. Kamble, R. R. Hawaldar, D. P. Amalnerkar, S. W. Gosavi, and S. R. Jadkar, “Determination of the optical parameters of a-Si:H thin films deposited by hot wire-chemical vapour deposition technique using transmission spectrum only,” Pramana - J. Phys., vol. 76, no. 3, pp. 519-531, 2011.

F. Xu and Y. Zhu, “Highly conductive and stretchable silver nanowire conductors,” Adv. Mater., vol. 24, no. 37, pp. 5117-5122, 2012.

S. De et al., “Silver Nanowire Networks as Flexible, Transparent, Conducting Films: Extremely High DC to Optical Conductivity Ratios,” ACS Nano, vol. 3, no. 7, pp. 1767-1774, 2009.

M. J. Kim, Y. S. Cho, and Y. D. Huh, “Synthesis of silver nanowires by reduction of silver-pyridine complexes,” Bull. Korean Chem. Soc., vol. 33, no. 5, pp. 1762-1764, 2012.

H. Y. Mi, Z. Li, L. S. Turng, Y. Sun, and S. Gong, “Silver nanowire/thermoplastic polyurethane elastomer nanocomposites: Thermal, mechanical, and dielectric properties,” Mater. Des., vol. 56, pp. 398-404, 2014.

G. Khanarian, J. Joo, X.-Q. Liu, P. Eastman, D. Werner, K. O'Connell, and P. Trefonas, “The optical and electrical properties of silver nanowire mesh films the optical and electrical properties of silver nanowire mesh films,” J. Appl. Phys, 114, 024302, 2013.

D. A. Dinh, K. N. Hui, K. S. Hui, P. Kumar, and J. Singh, “Silver Nanowires: A Promising Transparent Conducting Electrode Material for Optoelectronic and Electronic Applications,” Rev. Adv. Sci. Eng., vol. 2, no. 4, pp. 1-22, 2013.

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