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Biyodizel Atıksularında MeOH ve KOİ Gideriminin Elektrokoagülasyon Yöntemi İle Arıtımı

Yıl 2018, Cilt: 22 Sayı: 2, 600 - 606, 01.04.2018

Pınar Tanatti Ayhan Şengil Halil Aksu Meryem Mehmetbaşoğlu Büşra Erden

https://doi.org/10.16984/saufenbilder.330946

Öz

 Biyodizel atıksuları çok miktarda yağ, metanol, sabun ve
gliserin içermektedir. Bu atıksuların KOİ değeri 250 000- 450 000 mg/L, TOK 54
000- 110 000 mg/L, gliserin 800-1500 mg/L ve metanol 6 000- 15 000 mg/L
arasında değişmektedir. Atıksudaki yağ içeriği ise 15 000 mg/L kadar yüksek
olabilmektedir. Bu nedenle biyodizel atıksuları, yağ-
drenaj sistemlerin tıkanmasına, biyolojik arıtma sistemlerinde biyolojik
aktivitenin azalmasına sebep olmaktadır. Bu çalışmanın ana amacı, laboratuvar
ölçeğinde çalışmalar yaparak esterifikasyon yöntemiyle üretilen biyodizel
yıkama sularının arıtılabilirliğinin incelenmesidir. Bu çalışmada, biyodizel
atıksuyunun elektrokoagülasyon yöntemi ile arıtımı kesikli bir reaktörde
incelenmiştir. EC prosesinde, başlangıç atıksu pH değeri 6, tuz miktarı 0,5
g/L, akım yoğunluğu 0,7 mA/cm2 ve elektroliz süresi 2 dakika
belirlenmiştir. 2 dakikalık elektrokogülasyon prosesi sonucunda %64,2 MeOH
ve %95,8 KOİ
giderme verimleri elde edilmiştir. Bu sonuçlara göre MeOH ve KOİ gideriminde
işletme boyunca elektrokoagülasyon yöntemi daha yüksek miktarda MeOH ve KOİ
giderimi sağlanmaktadır.

Anahtar Kelimeler

Elektrokoagülasyon Biyodizel atıksuyu metanol

Kaynakça

  • [1] Ham petrol ve Doğal Gaz Sektör Raporu, 2016 Available: http://www.enerji.gov.tr/File/?path=ROOT%2F1%2FDocuments%2FSekt%C3%B6r%20Raporu%2FTP_HAM_PETROLDOGAL_GAZ_SEKTOR_RAPORU__2016.pdf [Accessed: 1-June-2017].
  • [2] S. K. Karmee, D. Linardi, J. Lee, and C.S.K. Lin, “Conversion of lipid from food waste to biodiesel,” Waste Management, vol. 41, pp. 169–173, 2015.
  • [3] T.C. Enerji ve Tabii Kaynaklar Bakanlığı, Yenilenebilir Enerji Müdürlüğü, Available: http://www.eie.gov.tr/yenilenebilir/biyodizel.aspx [Accessed: 1-June-2017].
  • [4] J.M Marchetti, “A summary of the available Technologies for biodiesel production based on a comparison of different feedstock's properties,” Process Saf Environ Prot, vol. 90, pp. 157–63, 2012.
  • [5] M.G. Gomes, D.Q. Santos, L.C. De Morais, and D. Pasquini, “Purification of biodiesel by dry washing, employing starch and cellulose as natural adsorbents,” Fuel, vol. 155, pp. 1–6, 2015.
  • [6] Introduction To Biodiesel And Glossary Of Terms National Biodiesel Board, Usa Available: https://doi.org/10.1016/B978-0-12-407909-0.00002-X [Accessed: 2-June-2017].
  • [7] Biodiesel emissions And healty Effects Testing, Bioenergy, vol. 35, pp. 557-559, 2015.
  • [8] G. Isenberg, “Assessment of Automotive Fuels,” Journal of Power Sources, vol. 84, pp. 214-217, 1999.
  • [9] G. Antolin, F.V. Tinaut, Y. Briceno, V. Castano, C. Perez, and A.I. Ramirez, “Optimisation of biodiesel production by sunflower oil transesterification,” Bioresource Technology, vol. 83, pp. 111-114, 2002.
  • [10] P. Hoffmann, “Tomorrow’s Energy: Hydrogen, Fuel Cells and the Prospects for a Cleaner Planet,” The MIT Pres, Cambridge, Massachusetts and London, England, Third Printing, 2002.
  • [11] G. Vicente, M. Martínez, and J. Aracil, “Optimisation of integrated biodiesel production, Part I. A study of the biodiesel purity and yield,” Bioresource Technol., vol. 98, pp. 1724–1733, 2007.
  • [12] Q. Fu, C. Song, Y. Kansha, Y. Liu, M. Ishizuka, and A. Tsutsumi, “Energy saving in a biodiesel production process based on self-heat recuperation technology,” Chemical Engineering Journal, vol. 278, pp. 556–562, 2015.
  • [13] V.B. Veljković, I.B. Banković-Ilić, and O.S. Stamenković, “Purification of crude biodiesel obtained by heterogeneously-catalyzed transesterification,” Renewable and Sustainable Energy Reviews, vol. 49, pp. 500–516, 2015.
  • [14] Biodiesel İndustry and Technical Overview, 2017. Available: http://biodiesel.org/docs/default-source/ffs-basics/biodiesel-industry-and-technical-overview.pdf?sfvrsn=20 [Accessed: 4-June-2017].
  • [15] Biofuels Annual, 2016. Available: https://gain.fas.usda.gov/Recent%20GAIN%20Publications/Biofuels%20Annual_The%20Hague_EU-28_6-29-2016.pdf [Accessed: 4-June-2017].
  • [16] E.T. Karagöl, and İ. Kavaz, “Dünyada ve Türkiye’de Yenilenebilir Enerji”, Analiz, vol. 197, 2017. Available: https://setav.org/assets/uploads/2017/04/YenilenebilirEnerji.pdf [Accessed: 7-June-2017].
  • [17] N.P. Tanattı, “Biyodizel Atıksularının Elektrokoagülasyon ve İleri Oksidasyon Yöntemleri İle Arıtılabilirliği,” (Doktora Tezi), Sakarya Ünv. Fen Bilimleri Enstitüsü, 2015.
  • [18] D.L. Woytowıch, C.W. Dalrymple, F.W. Gılmore, and M.G. Brıtton, “Electrocoagulation (Cure) Treatment Of Ship Bilgewater For The U.S. Coast Guard in Alaska,” Mts. Journal., vol. 27 (1), pp. 62-67,1993.
  • [19] İ. Taymaz, and M. Coban, “Performance and emissions of an engine fuelled with a biodiesel fuel produced from anımal fats,” Thermal Scıence, vol. 17, pp. 233-240, 2013.
  • [20] Y.Y. Zhan, Y. Zhang Q.M. Lia, Xin-Zhen, and X.Z. Du, “A Novel Visible Spectrophotometric Method for the Determination of Methanol Using Sodium Nitroprusside as Spectroscopic Probe,” Journal of the Chinese Chemical Society, vol.57, pp. 230-235, 2010.
  • [21] S. Song, Z. He, J. Qıu, L. Xu, and J. Chen, “Ozone assisted electrocoagulation for decolorization of C. I. Reaktive Black 5 in aqueoud solution: An investigation of the effect of operational parameters,” Sep. Purif. Technol., vol. 55, pp. 238-245, 2007.
  • [22] E.A.Vik, D.A. Carlson, A.S. Eikum, and E.T. Gjessing, “Electrocoagulation of potable water,” Water Res., vol. 18, pp. 1355–1360, 1984.
  • [23] G. Chen, “Electrochemical Technologies in wastewater treatment,” Sep. Purif. Technol., vol. 38, pp. 11-41, 2004.
  • [24] M. Tir, N. Moulai-Mostefa, “Optimization of oil removal from oily wastewater by electrocoagulation using response surface method,” Journal of Hazard. Materi., vol. 158, pp. 107–115, 2008.
  • [25] N.P. Tanattı, “Kanatlı hayvan kesimhane atıksularının elektrokoagülasyon yöntemi ile arıtılabilirliği,” (Yüksek Lisans Tezi), Sakarya Ünv. Fen Bilimleri Enstitüsü, 2009.
  • [26] M.Y.A. Mollah, P. Morkovsky, J.A.G. Gomes, M. Kesmez, J. Parga, and D.L. Cocke, “Fundamentals, present and future perspectives of electrocoagulation,” J. Hazard. Mater. B, vol. 114, pp. 199-210, 2004.

Treatment of MeOH and COD removal in biodiesel wastewaters by electrocoagulation

Yıl 2018, Cilt: 22 Sayı: 2, 600 - 606, 01.04.2018

Pınar Tanatti Ayhan Şengil Halil Aksu Meryem Mehmetbaşoğlu Büşra Erden

https://doi.org/10.16984/saufenbilder.330946

Öz

The
main components of the wastewater are the residual remaining oil, methanol,
glycerol, soap. In general, wastewater from the biodiesel processing industry
contains high concentrations of COD, TOC, Glycerol, methanol and oil and/or
grease such as 250 000- 450 000 mg L-1, 54 000- 110 000 mg L-1
, 800-1500 mg L-1  , 6 000- 15
000 mg L-1  and 15 000 mg L-1,
respectively. In this respect, biodiesel wastewater should not be discharged
into public drainage because the oil causes clogging of the drainage and
decreases biological activity in sewage treatment. The
initial aim of this study is, investigation of, treatability of the biodiesel
washing water, maintained by the esterification process with fulfillmentlaboratory
scale studies. In
this study, the treatment of biodiesel wastewater by electrocoagulation was
investigated carried out in a batch reactor. Removal efficiencies for 64.2% of
MeOH and 95.8% KOİ were obtained at wastewater inital pH 6, NaCl dose 0.5 g/L,
current density of 0.7 mA/cm2 and 2 min of operating time. According
to these results, MeOH and COD removal are provided by the electrocoagulation
method during operation at a higher amount of MeOH and COD removal.

Anahtar Kelimeler

Electrocoagulation Biodiesel wastewater Methanol

Kaynakça

  • [1] Ham petrol ve Doğal Gaz Sektör Raporu, 2016 Available: http://www.enerji.gov.tr/File/?path=ROOT%2F1%2FDocuments%2FSekt%C3%B6r%20Raporu%2FTP_HAM_PETROLDOGAL_GAZ_SEKTOR_RAPORU__2016.pdf [Accessed: 1-June-2017].
  • [2] S. K. Karmee, D. Linardi, J. Lee, and C.S.K. Lin, “Conversion of lipid from food waste to biodiesel,” Waste Management, vol. 41, pp. 169–173, 2015.
  • [3] T.C. Enerji ve Tabii Kaynaklar Bakanlığı, Yenilenebilir Enerji Müdürlüğü, Available: http://www.eie.gov.tr/yenilenebilir/biyodizel.aspx [Accessed: 1-June-2017].
  • [4] J.M Marchetti, “A summary of the available Technologies for biodiesel production based on a comparison of different feedstock's properties,” Process Saf Environ Prot, vol. 90, pp. 157–63, 2012.
  • [5] M.G. Gomes, D.Q. Santos, L.C. De Morais, and D. Pasquini, “Purification of biodiesel by dry washing, employing starch and cellulose as natural adsorbents,” Fuel, vol. 155, pp. 1–6, 2015.
  • [6] Introduction To Biodiesel And Glossary Of Terms National Biodiesel Board, Usa Available: https://doi.org/10.1016/B978-0-12-407909-0.00002-X [Accessed: 2-June-2017].
  • [7] Biodiesel emissions And healty Effects Testing, Bioenergy, vol. 35, pp. 557-559, 2015.
  • [8] G. Isenberg, “Assessment of Automotive Fuels,” Journal of Power Sources, vol. 84, pp. 214-217, 1999.
  • [9] G. Antolin, F.V. Tinaut, Y. Briceno, V. Castano, C. Perez, and A.I. Ramirez, “Optimisation of biodiesel production by sunflower oil transesterification,” Bioresource Technology, vol. 83, pp. 111-114, 2002.
  • [10] P. Hoffmann, “Tomorrow’s Energy: Hydrogen, Fuel Cells and the Prospects for a Cleaner Planet,” The MIT Pres, Cambridge, Massachusetts and London, England, Third Printing, 2002.
  • [11] G. Vicente, M. Martínez, and J. Aracil, “Optimisation of integrated biodiesel production, Part I. A study of the biodiesel purity and yield,” Bioresource Technol., vol. 98, pp. 1724–1733, 2007.
  • [12] Q. Fu, C. Song, Y. Kansha, Y. Liu, M. Ishizuka, and A. Tsutsumi, “Energy saving in a biodiesel production process based on self-heat recuperation technology,” Chemical Engineering Journal, vol. 278, pp. 556–562, 2015.
  • [13] V.B. Veljković, I.B. Banković-Ilić, and O.S. Stamenković, “Purification of crude biodiesel obtained by heterogeneously-catalyzed transesterification,” Renewable and Sustainable Energy Reviews, vol. 49, pp. 500–516, 2015.
  • [14] Biodiesel İndustry and Technical Overview, 2017. Available: http://biodiesel.org/docs/default-source/ffs-basics/biodiesel-industry-and-technical-overview.pdf?sfvrsn=20 [Accessed: 4-June-2017].
  • [15] Biofuels Annual, 2016. Available: https://gain.fas.usda.gov/Recent%20GAIN%20Publications/Biofuels%20Annual_The%20Hague_EU-28_6-29-2016.pdf [Accessed: 4-June-2017].
  • [16] E.T. Karagöl, and İ. Kavaz, “Dünyada ve Türkiye’de Yenilenebilir Enerji”, Analiz, vol. 197, 2017. Available: https://setav.org/assets/uploads/2017/04/YenilenebilirEnerji.pdf [Accessed: 7-June-2017].
  • [17] N.P. Tanattı, “Biyodizel Atıksularının Elektrokoagülasyon ve İleri Oksidasyon Yöntemleri İle Arıtılabilirliği,” (Doktora Tezi), Sakarya Ünv. Fen Bilimleri Enstitüsü, 2015.
  • [18] D.L. Woytowıch, C.W. Dalrymple, F.W. Gılmore, and M.G. Brıtton, “Electrocoagulation (Cure) Treatment Of Ship Bilgewater For The U.S. Coast Guard in Alaska,” Mts. Journal., vol. 27 (1), pp. 62-67,1993.
  • [19] İ. Taymaz, and M. Coban, “Performance and emissions of an engine fuelled with a biodiesel fuel produced from anımal fats,” Thermal Scıence, vol. 17, pp. 233-240, 2013.
  • [20] Y.Y. Zhan, Y. Zhang Q.M. Lia, Xin-Zhen, and X.Z. Du, “A Novel Visible Spectrophotometric Method for the Determination of Methanol Using Sodium Nitroprusside as Spectroscopic Probe,” Journal of the Chinese Chemical Society, vol.57, pp. 230-235, 2010.
  • [21] S. Song, Z. He, J. Qıu, L. Xu, and J. Chen, “Ozone assisted electrocoagulation for decolorization of C. I. Reaktive Black 5 in aqueoud solution: An investigation of the effect of operational parameters,” Sep. Purif. Technol., vol. 55, pp. 238-245, 2007.
  • [22] E.A.Vik, D.A. Carlson, A.S. Eikum, and E.T. Gjessing, “Electrocoagulation of potable water,” Water Res., vol. 18, pp. 1355–1360, 1984.
  • [23] G. Chen, “Electrochemical Technologies in wastewater treatment,” Sep. Purif. Technol., vol. 38, pp. 11-41, 2004.
  • [24] M. Tir, N. Moulai-Mostefa, “Optimization of oil removal from oily wastewater by electrocoagulation using response surface method,” Journal of Hazard. Materi., vol. 158, pp. 107–115, 2008.
  • [25] N.P. Tanattı, “Kanatlı hayvan kesimhane atıksularının elektrokoagülasyon yöntemi ile arıtılabilirliği,” (Yüksek Lisans Tezi), Sakarya Ünv. Fen Bilimleri Enstitüsü, 2009.
  • [26] M.Y.A. Mollah, P. Morkovsky, J.A.G. Gomes, M. Kesmez, J. Parga, and D.L. Cocke, “Fundamentals, present and future perspectives of electrocoagulation,” J. Hazard. Mater. B, vol. 114, pp. 199-210, 2004.
Toplam 26 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Çevre Mühendisliği
Bölüm Araştırma Makalesi
Yazarlar

Pınar Tanatti

Ayhan Şengil

Halil Aksu Bu kişi benim

Meryem Mehmetbaşoğlu Bu kişi benim

Büşra Erden Bu kişi benim

Yayımlanma Tarihi 1 Nisan 2018
Gönderilme Tarihi 26 Temmuz 2017
Kabul Tarihi 9 Mart 2018
Yayımlandığı Sayı Yıl 2018 Cilt: 22 Sayı: 2

Kaynak Göster

APA Tanatti, P., Şengil, A., Aksu, H., Mehmetbaşoğlu, M., vd. (2018). Biyodizel Atıksularında MeOH ve KOİ Gideriminin Elektrokoagülasyon Yöntemi İle Arıtımı. Sakarya University Journal of Science, 22(2), 600-606. https://doi.org/10.16984/saufenbilder.330946
AMA Tanatti P, Şengil A, Aksu H, Mehmetbaşoğlu M, Erden B. Biyodizel Atıksularında MeOH ve KOİ Gideriminin Elektrokoagülasyon Yöntemi İle Arıtımı. SAUJS. Nisan 2018;22(2):600-606. doi:10.16984/saufenbilder.330946
Chicago Tanatti, Pınar, Ayhan Şengil, Halil Aksu, Meryem Mehmetbaşoğlu, ve Büşra Erden. “Biyodizel Atıksularında MeOH Ve KOİ Gideriminin Elektrokoagülasyon Yöntemi İle Arıtımı”. Sakarya University Journal of Science 22, sy. 2 (Nisan 2018): 600-606. https://doi.org/10.16984/saufenbilder.330946.
EndNote Tanatti P, Şengil A, Aksu H, Mehmetbaşoğlu M, Erden B (01 Nisan 2018) Biyodizel Atıksularında MeOH ve KOİ Gideriminin Elektrokoagülasyon Yöntemi İle Arıtımı. Sakarya University Journal of Science 22 2 600–606.
IEEE P. Tanatti, A. Şengil, H. Aksu, M. Mehmetbaşoğlu, ve B. Erden, “Biyodizel Atıksularında MeOH ve KOİ Gideriminin Elektrokoagülasyon Yöntemi İle Arıtımı”, SAUJS, c. 22, sy. 2, ss. 600–606, 2018, doi: 10.16984/saufenbilder.330946.
ISNAD Tanatti, Pınar vd. “Biyodizel Atıksularında MeOH Ve KOİ Gideriminin Elektrokoagülasyon Yöntemi İle Arıtımı”. Sakarya University Journal of Science 22/2 (Nisan 2018), 600-606. https://doi.org/10.16984/saufenbilder.330946.
JAMA Tanatti P, Şengil A, Aksu H, Mehmetbaşoğlu M, Erden B. Biyodizel Atıksularında MeOH ve KOİ Gideriminin Elektrokoagülasyon Yöntemi İle Arıtımı. SAUJS. 2018;22:600–606.
MLA Tanatti, Pınar vd. “Biyodizel Atıksularında MeOH Ve KOİ Gideriminin Elektrokoagülasyon Yöntemi İle Arıtımı”. Sakarya University Journal of Science, c. 22, sy. 2, 2018, ss. 600-6, doi:10.16984/saufenbilder.330946.
Vancouver Tanatti P, Şengil A, Aksu H, Mehmetbaşoğlu M, Erden B. Biyodizel Atıksularında MeOH ve KOİ Gideriminin Elektrokoagülasyon Yöntemi İle Arıtımı. SAUJS. 2018;22(2):600-6.
 Kapak Resmi İndir

Sakarya University Journal of Science (SAUJS)