Abstract
Renders and plasters are usually employed for restoration, consolidation and decorative purposes. This paper looks at a rapid method based on conductivity measurements to evaluate the damage caused by sulphuric acid on cement renders. Exposure of the renders to 0.1% w/w sulphuric acid solutions resulted, as expected, in the formation of gypsum and no signs of ettringite were observed. The samples were also treated with siloxane coatings (polydimethylsiloxane) to investigate the waterproofing role on acid protection. A linear correlation was found between the time of immersion and change in conductivity. Finally, the results were supported by water absorption tests, scanning electron microscopy, X-ray diffraction and ion chromatography.
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References
Beddoe Robin E, Dorner Horst W (2005) Modeling acid attack on concrete: Part I. The essential mechanisms. Cem Concr Res 35:2333–2339. doi:10.1016/j.cemconres.2005.04.002
Brown PW, Clifton JR (1998) Mechanism of deterioration in cement-based materials and in lime mortar. Durab Build Mater 5:409–420
Camuffo D (1995) Physical weathering of stones. Sci Total Environ 167:1–14. doi:10.1016/0048-9697(95)04565-I
Doherty B, Pamplona M, Selvaggi R, Miliani C, Matteini M, Sgamellotti A, Brunetti B (2007) Efficiency and resistance of the artificial oxalate protection treatment on marble against chemical weathering. Appl Surf Sci 253:4477–4484. doi:10.1016/j.apsusc.2006.09.056
EN 998-1 (2003) Specification for mortar for masonry: Part 1. Rendering and plastering mortar. European Committee for Standardization
EN 196-1 (1994) Methods of testing cement: Part 1. European Committee for Standardization
Malaga-Starzec K, Panas I, Lindqvist JE, Lindqvist O (2003) Efflorescence on thin sections of calcareous stones. J Cult Herit 4:313–318. doi:10.1016/j.culher.2003.09.002
Maravelaki-Kalaitzaki P (2007) Hydraulic lime mortars with siloxane for waterproofing historic masonry. Cem Concr Res 37:283–290. doi:10.1016/j.cemconres.2006.11.007
Martínez-Ramírez S, Puertas F, Blanco-Varela MT, Thompson GE, Almendros P (1998) Behavior of repair lime mortars by wet deposition process. Cem Concr Res 28:221–229. doi:10.1016/S0008-8846(97)00262-7
Okochi H, Kameda H, Hasegawa S, Saito N, Kubota K, Igawa M (2000) Deterioration of concrete structures by acid deposition—an assessment of the role of rainwater on deterioration by laboratory and field exposure experiments using mortar specimens. Atmos Environ 34:2937–2945. doi:10.1016/S1352-2310(99)00523-3
Price CA (1996) Stone conservation: an overview of current research. The J. Paul Getty Trust, USA
Tittarelli F, Moriconi G, Bonazza A (2008) Atmospheric deterioration of cement plaster in a building exposed to an urban environment. J Cult Herit 9:203–206. doi:10.1016/j.culher.2007.09.005
Tsakalof A, Manoudis P, Karapanagiotis I, Chryssoulakis I, Panayiotou C (2007) Assessment of synthetic polymeric coatings for the protection and preservation of stone monuments. J Cult Herit 8:69–72. doi:10.1016/j.culher.2006.06.007
Xie S, Qi L, Zhou D (2004) Investigation of the effects of acid rain on the deterioration of cement concrete using accelerated tests established in laboratory. Atmos Environ 38:4457–4466. doi:10.1016/j.atmosenv.2004.05.017
Zivica V, Bajza A (2002) Acidic attack of cement-based materials—a review: Part 2. Factors of rate of acidic attack and protective measures. Constr Build Mater 16:215–222. doi:10.1016/S0950-0618(02)00011-9
Zivica V, Bajza A (2004) Acidic attack of cement based materials—a review: Part 3. Research and test methods. Constr Build Mater 18:683–688. doi:10.1016/j.conbuildmat.2004.04.030
Acknowledgments
The authors express their thanks to SAIT the technological service of the Technical University of Cartagena. The support and recommendations given by Alberto Alcolea from SAIT are much appreciated. We are grateful for the technical information and the samples provided by Saint Gobain Weber Cermaksa, Wacker-Chemie, Brenntag Ibérica and Cemex España.
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Lanzón, M., García-Ruiz, P.A. Deterioration and damage evaluation of rendering mortars exposed to sulphuric acid. Mater Struct 43, 417–427 (2010). https://doi.org/10.1617/s11527-009-9500-4
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DOI: https://doi.org/10.1617/s11527-009-9500-4