Abstract
Application of paints by spraying, extensively used in the automotive industry, generates a solid waste, known as paint sludge, which, if improperly managed, may lead to significant environmental and economic burdens. In the research work described in this paper, use of paint sludge for the production of modified bituminous binders for paving applications was investigated. In particular, expected field performance of paint sludge modified binders (PSMBs) was assessed and compared to that of neat bitumen and polymer-modified binders. PSMBs considered in the study were prepared in the laboratory by employing variable dosages of sludge coming from different painting plants and derived either from basecoat or clearcoat application. PSMB characteristics were evaluated by means of rheological tests which led to construction of master curves, determination of performance grade (PG) according to the SUPERPAVE scheme, detailed evaluation of resistance to permanent deformation by means of multiple stress creep recovery tests, and analysis of resistance to fatigue damage by making use of time sweep and linear amplitude sweep tests. Obtained results showed that use of automotive paint sludge for the production of PSMBs is a feasible, cost-effective and environmentally compatible alternative to currently adopted management solutions which consist either in incineration or in energy production in cement kilns. Although fluxing and stiffening effects were observed in the case of basecoat and clearcoat sludge, respectively, only minor variations were recorded in terms of PG, elastic response, stress sensitivity, fatigue resistance and fatigue ductility of neat bitumen.
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References
Streitberger HJ, Dössel KF (2008) Automotive paints and coatings. Wiley-VCH Verlag GmbH & Co KgaA, Weinheim
Toda K, Salazar A, Saito K (2013) Automotive painting technology. Springer, Dordrecht
FCA S.p.A. (2014a) FCA Annual Report at 31 December 2014. Fiat Chrysler Automobiles, Turin
FCA S.p.A. (2014b) Sustainability Report 2014. Economic, environmental and social responsibility. Fiat Chrysler Automobiles, Turin
Chen CP (1995) Automotive painting: achieving a technological, economic and environmental balance. Degree of Master of Science in Technology and Policy, Massachusetts Institute of Technology, Cambridge
Papasavva S, Kia S, Claya J, Gunther R (2002) Life cycle environmental assessment of paint processes. J Coat Technol 74:65–76
Gerace MJ, Gerace JM (1992) Method of making a filler from automotive paint sludge, filler and sealant containing a filler. US Patent 5,160,628
Gerace MJ, Gamboa SC, Landaburu YS (1993) Method of making sludge powder and sealant from paint sludge and sludge powder and sealant composition produced thereby. US Patent 5,254,263
Gerace MJ, Landaburu YS, Gamboa SC (1999) Compounded polymeric compositions utilizing processed paint sludge as a replacement for polymeric components. US Patent 5,880,218
Mathenson RR, Dixon DM, Moore JR, Fisher DA (2006) Process for producing building materials from raw paint sludge. US Patent 7,128,780
Soroushian P, Okwuegbu AC (1996) Shrinkage compensating concrete with expansive additive. US Patent 5,489,333
St. Louis DM (1996) Process for producing building materials from paint sludge. US Patent 5,573,587
Bhatia RK, Bhatia VK, Vishnoi AS (2007) Composition and process for conversion of paint sludge into reusable paint. Patent WO/2007/072502
Du Pont De Nemours & Co. (2005) Process for producing building materials from raw paint sludge. Patent EP 1 432 663 B1
Haden Inc. (1998) Method for processing paint sludge. Patent EP 0 882 678
Haden Schweitzer Corporation (1993) Method and apparatus for treating waste paint sludge. Patent EP 0 344 946 B1
Maharani Paints Private (2004) Composition for conversion of paint sludge into bitumen blendable mixture, process for preparation thereof. Patent IN 264 332 B
Martínez-González GM, Castro-Agũero A, Quintana-Hernández PA, González-Alatorre G, Castro-Montoya AJ (1998) Use of automotive paint sludge as filler in asphaltic mixtures. J Solid Waste Technol Manag 25:1–4
Ruffino B, Dalmazzo D, Riviera PP, Santagata E, Zanetti MC (2012) Preliminary performance assessment of asphalt concrete with paint sludge from automotive industries. In: Proceedings of 3rd international conference on industrial and hazardous waste management, Crete, 12–14 Sept 2012
Ruffino B, Dalmazzo D, Santagata E, Zanetti MC (2011) Preliminary evaluation of the potential use of paint sludge in bituminous binders. In: Proceedings, Sardinia 2011, 13th international waste management and landfill symposium, 3–7 Oct 2011
Vercelli A, Ruffino B, Dalmazzo D, Zanetti MC, Santagata E (2016) Reuse of paint sludge for the production of modified bituminous binders for road pavements. Resour Conserv Recycl (Submitted)
Chailleux E, Ramond G, Such C, De La Roche C (2006) A mathematical-based master curve construction method applied to complex modulus of bituminous materials. Road Mater Pavement Des 7(Special issue EATA 2006), 75-92
Ferry JD (1980) Viscoelastic properties of polymers, 3rd edn. Wiley, New York
Christensen DC, Anderson DA (1992) Interpretation of dynamic mechanical test data for paving grade asphalt cements. J Assoc Asph Paving Technol 61:67–116
AASHTO M 332-14 (2014) Performance-graded asphalt binder using multiple stress creep recovery (MSCR) test
AASHTO T 240-13 (2013) Effect of heat and air on a moving film of asphalt binder (Rolling Thin Film Oven test)
AASHTO R 28-12 (2012) Accelerated aging of asphalt binder using a pressurized aging vessel (PAV)
AASHTO T 350-14 (2014) Multiple stress creep recovery (MSCR) test of asphalt binder using a dynamic shear rheometer (DSR)
FHWA (2011) The multiple stress creep recovery (MSCR) procedure. Techbrief, Office of Pavement Technology FHWA
Bahia H, Hanson DI, Zeng M, Zhai H, Khatri MA, Anderson RM (2001) Characterization of modified asphalt binders in superpave mix design. NCHRP Report 459, project 9-10, Transportation Research Board, Washington DC
Pronk AC, Hopman PC (1990) Energy dissipation: the leading factor to fatigue. In: Proceedings of the Strategic Highway Research Program: sharing the benefits, London
Santagata E, Baglieri O, Dalmazzo D (2008) Experimental investigation on the fatigue behaviour of modified bituminous binders and mastics. J Assoc Asph Paving Technol 77:851–884
Botella R, Perez-Jimenez FE, Mirò R (2012) Application of a strain sweep test to assess fatigue behavior of asphalt binders. Constr Build Mater 36:906–912
Hintz C, Bahia H (2013) Simplification of the linear amplitude sweep (LAS) test and specification parameter. J Transp Res Board 2370:10–16
Hintz C, Velasquez R, Johnson C, Bahia H (2011) Modification and validation of the linear amplitude sweep test for binder fatigue specification. J Transp Res Board 2207:99–106
Kim Y, Lee HJ, Little DN, Kim YR (2006) A simple testing method to evaluate fatigue fracture and damage performance of asphalt mixtures. J Assoc Asph Paving Technol 75:755–788
Peebles GR, Mehta Y (2013) Characterization of fatigue properties of binders and mastics at intermediate temperatures using dynamic shear rheometer. University Transportation Research Center—Region 2. Final Report, New York
Santagata E, Baglieri O, Tsantilis L, Dalmazzo D (2013) Evaluation of self-healing properties of bituminous binders taking into account steric hardening effects. Constr Build Mater 41:60–67
Lee HJ, Daniel JS, Kim YR (2000) Continuum damage mechanics-based fatigue model of asphalt concrete. J Mater Civ Eng 12:105–112
Lee HJ, Kim YR (1998) Viscoelastic continuum damage model of asphalt concrete with healing. J Eng Mech 124:1224–1232
Park SW, Kim YR, Schapery RA (1996) A viscoelastic continuum damage model and its application to uniaxial behavior of asphalt concrete. Mech Mater 24:241–255
Wen H, Bahia H (2009) Characterizing fatigue of asphalt binders using viscoelastic continuum damage mechanics. J Transp Res Board 2126:55–62
AASHTO TP 101-14 (2014) Estimating damage tolerance of asphalt binders using the linear amplitude sweep
Anderson DA, Christensen DW, Bahia HU, Dongre R, Sharma MG, Antle CE, Button J (1994) Binder characterization and evaluation. Physical characterization, vol 3. SHRP-A-369. Strategic Highway Research Program, National Research Council, Washington DC
AASHTO M 320-10 (2010) Standard specification for performance-graded asphalt binder
Domingos MDI, Faxina AL (2015) Rheological behavior of bitumens modified with PE and PPA at different MSCR creep-recovery times. Int J Pavement Eng 16:771–783
Anderson RM (2013) Northeast Asphalt User-Producer Group Second Interlaboratory Study to determine the precision of AASHTO TP70—the Multiple-Stress Creep-Recovery (MSCR) test, prepared for the Northeast Asphalt User-Producer Group (NEAUPG), Asphalt Institute and FHWA, DTFH61-11-H-00033
Acknowledgments
The study reported in this paper is part of the research project entitled “Reuse of Paint Sludge in Road Pavements (RP2)” funded by FCA Italy S.p.A. The constant support of Simone Cencetti and Germano Gaido is gratefully acknowledged.
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Dalmazzo, D., Vercelli, A., Santagata, E. et al. Rheological characterization and performance-related evaluation of paint sludge modified binders. Mater Struct 50, 74 (2017). https://doi.org/10.1617/s11527-016-0945-y
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DOI: https://doi.org/10.1617/s11527-016-0945-y