Journal of Molecular Catalysis(China). 2021, (05) Core

Preparation of Acylhydrazines via Carbonylation and Their Applications as Intelligent MaterialsChinese Full Text

YANG Shu-qing;LIU Ye;Shanghai Key Laboratory of Green Chemistry and Chemical Process, School of Chemistry and Molecular Engineering, East China Normal University;

Abstract: The development of synthesis protocols of acylhydrazines has attracted attention because of the wide uses of such compounds in pesticides, medicines, intelligentmaterials etc. The catalytic carbonylations of halohydrocarbons, organichydrazines（or N-acylhydrazines） and CO is undoubtedly one of the most ideal methods to afford acylhydrazines. In addition to CO, CO₂, DMC（dimethyl carbonate）, and solid metal carbonyl also could be used as an CO-surrogate in the synthesis of acylhydrazines via carbonylations. This review summaries the recent research status on the carbonylations of halohydrocarbons and organic hydrazines with the different CO-sources for the synthesis of acylhydrazines, and then introduces the latest applications of such carbonyl compounds as the intelligentmaterials. Finally, the future research trends of the synthesis methods of acylhydrazines and the application of these compounds are prospected.

Keywords：

acylhydrazines; carbonylation; carbonyl source; halohydrocarbons; hydrazines; intelligent material;

DOI：
10.16084/j.issn1001-3555.2021.05.007
Series：
(B) Chemistry/ Metallurgy/ Environment/ Mine Industry
Subject：
Organic Chemical Industry; Material Science
Classification Code：
TQ225.266;TB381

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Preparation of Acylhydrazines via Carbonylation and Their Applications as Intelligent MaterialsChinese Full Text

YANG Shu-qing;LIU Ye;Shanghai Key Laboratory of Green Chemistry and Chemical Process, School of Chemistry and Molecular Engineering, East China Normal University;

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