Abstract
Reactive N and H, created using rf plasma sources, were used to grow undoped GaN along with p-type GaN:Mg and p-type GaN:Mg:H thin films. By comparing the optical emission spectra from several rf sources with observed GaN grow rates, we deduce that nitrogen atoms and I stpositive series nitrogen molecules (3.95 eV binding energy) are the reactive species responsible for GaN film growth. A Mg ground state acceptor binding energy of about 224 meV was determined from low temperature photoluminescence (PL) experiments for both p-type GaN:Mg and p-type GaN:Mg:H films.
Similar content being viewed by others
References
R. W. B. Pearse and A. G. Gaydon, The Identification of Molecular Spectra, Wiley, New York, 1963, pp. 209–220.
A. N. Wright and C. A. Winkler, Active Nitrogen, Academic, New York, 1968, pp. 15–220.
A. R. Stringanow and N. S. Sventitskii, Tables of Spectral Lines of Neutral and Ionized Atoms, Plenum, New York, 1968, pp. 111–140b.
R.P. Vaudo, X. Yu, J.W. Cook Jr., and J.F. Schetzina, Optics Letters 18, p. 1843 (1993).
W. C. Hughes, J.W. Cook Jr, J. F. Schetzina, J. Ren and J. A. Edmond, J. Vac. Sci. Technol. B 13, p. 1571 (1995).
B.J. Skromme, J.W. Hutchins, H. Zhao, H.S. Kong, M.T. Leonard, G.E. Bulman, C.R. Abernathy, and S.J. Pearton, presented at the Electronic Materials Conference, Santa Barbara, Paper #W6, 1996.
R. Dingle, D.D. Sell, S.E. Stokowski, and M. Ilegems, Phys. Rev. B 4, p. 1211 (1971).
M. Ilegems and R. Dingle, J. Appl. Phys. 44, p. 4234 (1973).
P.J. Dean and A.M. White, Solid State Electron. 21, p. 1351 (1978).
E. Molva and N. Magnea, Phys. Stat. Sol. (b) 102, p. 475 (1980).
R. Dingle and M. Flegems, Solid State Commun. 9, p. 175 (1971).
P.W. Yu, J. Appl. Phys. 48, p. 5043 (1977).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Johnson, M.A.L., Yu, Z., Boney, C. et al. Reactive MBE Growth of GaN and GaN∶:H on GaN/SiC Substrates. MRS Online Proceedings Library 449, 215–220 (1996). https://doi.org/10.1557/PROC-449-215
Published:
Issue Date:
DOI: https://doi.org/10.1557/PROC-449-215