Abstract
Macro/meso/microporous carbon monoliths doped with sulfur have been prepared from sulfonated polydivinylbenzene networks followed by the activation with CO2 resulted in the activated carbon monoliths with high surface area of 2400 m2 g−1. The monolithic electrode of the activated carbon shows remarkably high specific capacitance (175 F g−1 at 5 mV s−1 and 206 F g−1 at 0.5 A g−1).
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References
Y.-S. Hu, P. Adelhelm, B. M. Smarsly, S. Hore, M. Antonietti, and J. Maier, Adv. Funct. Mater. 17, 1873 (2007).
K. M. Thomas, Catal. Today 120, 389 (2007).
P. Simon and Y. Gogotsi, Nature Mater. 7, 845 (2008).
L. L. Zhang and X. S. Zhao, Chem. Soc. Rev. 38, 2520 (2009).
G. Salitra, A. Soffer, L. Ehad, Y. Cohen, and D. Aurbach, J. Electrochem. Soc. 147, 2486 (2000).
O. Barbieri, M. Hahn, A. Herzog, and R. Kötz, Carbon 43, 1303 (2005).
S. Shiraishi, H. Kurihara, L. Shi, T. Nakayama, and A. Oya, J. Electrochem. Soc. 149, A855 (2002).
C. Largeot, C. Portet, J. Chmiola, P. L. Taberna, Y. Gogotsi, and P. Simon, J. Am. Chem. Soc. 130, 2730 (2008).
N. Brun, S. R. S. Prabaharan, M. Morcrette, C. Sanchez, G. Pécastaings, A. Derré, A. Soum, H. Deleuze, M. Birot, and R. Backov, Adv. Funct. Mater. 19, 3136 (2009).
V. Ruiz, C. Blanco, R. Santamaría, J. M. Ramos-Fernández, M. Martínez-Escandell, A. Sepúlveda-Escribano, and F. Rodrígez-Reinoso, Carbon 47, 195 (2009).
J. Lee, S. Yoon, T. Hyeon, S. M. Oh, and K. B. Kim, Chem. Commun. 21, 2177 (1999).
B. Liu, H. Shioyama, H. Jiang, X. Zhang, and Q. Xu, Carbon 48, 456 (2010).
D. W. Wang, F. Li, M. Liu, G. Q. Lu, and H. M. Cheng, Angew. Chem. Int. Ed. 47, 373 (2008).
S. W. Woo, K. Dokko, H. Nakano, and K. Kanamura, J. Mater. Chem. 18, 1674 (2008).
J. Hasegawa, K. Kanamori, K. Nakanishi, T. Hanada, and S. Yamago, Macromolecules 42, 1270 (2009).
J. Hasegawa, K. Kanamori, K. Nakanishi, and T. Hanada, C. R. Chimie 13, 207 (2010).
G. Hasegawa, K. Kanamori, K. Nakanishi, and T. Hanada, Carbon 48, 1757 (2010).
J. W. Neely, Carbon 19, 27 (1981).
M. Toyoda, U. Tani, and Y. Soneda, Carbon 42, 2833 (2004).
Y. T. Kim and T. Mitani, J. Power Sources 158, 1517 (2006).
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Hasegawa, G., Aoki, M., Kanamori, K. et al. Macroporous Carbon Monoliths with Large Surface Area for Electric Double-Layer Capacitor. MRS Online Proceedings Library 1304, 407 (2011). https://doi.org/10.1557/opl.2011.604
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DOI: https://doi.org/10.1557/opl.2011.604