Abstract
Fine whiskers of a C60 derivative, i.e., C60 monosubstituted by ethyl ester of malonic acid, C60[C(COOC2H5)2], were fabricated for the first time using a system of toluene with concentrated C60[C(COOC2H5)2] and isopropyl alcohol. The center-to-center distance of C60[C(COOC2H5)2] molecules along the close-packed direction of the C60[C(COOC2H5)2] whiskers was in the same range as that of the C60 nanowhiskers prepared by the same method. The C60[C(COOC2H5)2] whiskers were assumed to take body-centered tetragonal or hexagonal close-packed crystal structures. The C60[C(COOC2H5)2] whiskers showed a high density of stacking faults. The C60[C(COOC2H5)2] whiskers with the growth direction different from the C60 whiskers were observed.
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Miyazawa, K., Mashino, T. & Suga, T. Structural characterization of the C60[C(COOC2H5)2] whiskers prepared by the liquid–liquid interfacial precipitation method. Journal of Materials Research 18, 2730–2735 (2003). https://doi.org/10.1557/JMR.2003.0380
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DOI: https://doi.org/10.1557/JMR.2003.0380