Abstract
The current investigation deals with the removal of Pb (II), Cd (II), and Cr (VI) ions by using chemically modified Quercus dilatata leaves (CMQDL) treated with nitric acid (HNO3), and calcium chloride (CaCl2). Batch biosorption experiments were performed to determine the optimal conditions of pH, biomass dose, temperature, contact time, and initial metal concentration for the utmost removal of heavy metals from water. The structural morphology and functionalities were explained by SEM and FTIR analysis. The maximum biosorption capacities for remediation of Pb (II), Cd (II), and Cr (VI) ions via CMQDL were 17.54, 20.408, 20.83 mg g−1, respectively at the optimal conditions. The Langmuir and Freundlich isotherm were applied to explore the equilibrium data however Freundlich isotherm model best evaluate the equilibrium data with high regression correlation coefficient (R2) values of 0.985, 0.826, and 0.919 for the elimination of Pb (II) Cd (II), and Cr (VI) ions, respectively. The kinetic study proposed that the remediation operation best obeyed the kinetic pseudo 2nd order model. The calculated thermodynamics functions like change in entropy (ΔS°), change in enthalpy (ΔH°) and Gibbs free energy (ΔG°) revealed that the removal of Pb (II) ions via the CMQDL was viable, exothermic and spontaneous, Cd (II) was endothermic and spontaneous and Cr (VI) was endothermic and non-spontaneous. The current study explored that CMQDL can be used for the remediation of Pb (II), Cd (II), and Cr (VI) ions, respectively.
Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: None declared.
Conflict of interest statement: The authors declare no conflict of interest regarding this article.
Data availability statement: All the data associated with this research has been presented in this paper.
References
1. Indhumathi, P., Sathiyaraj, S., Koelmel, J. P., Shoba, S. U., Jayabalakrishnan, C., Saravanabhavan, M., Zeitschrift Fur Physikalische Chemie 2018, 232, 527.10.1515/zpch-2016-0900Search in Google Scholar
2. Naseem, K., Huma, R., Shahbaz, A., Jamal, J., Ur Rehman, M. Z., Sharif, A., Ahmed, E., Begum, R., Irfan, A, Al-Sehemi, A. G., Farooqi, Z. H. Zeitschrift fur Physikalische Chemie 2019, 233, 201; https://doi.org/10.1515/zpch-2018-1182.Search in Google Scholar
3. Ata, S., Tabassum, A., Bibi, I., Ghafoor, S., Ahad, A., Bhatti, M. A., Islam, A., Rizvi, H., Iqbal, M. Zeitschrift fur Physikalische Chemie 2019, 233, 995; https://doi.org/10.1515/zpch-2018-1203.Search in Google Scholar
4. Vinod, V. T. P., Sashidhar, R. B., Sreedhar, B. J. Hazard. Mater. 2010, 178, 851; https://doi.org/10.1016/j.jhazmat.2010.02.016.Search in Google Scholar
5. Reddy, D. H. K., Harinath, Y., Seshaiah, K., Reddy, A. V. R. Chem. Eng. J. 2010, 162, 626; https://doi.org/10.1016/j.cej.2010.06.010.Search in Google Scholar
6. Jang, Y., Shapiro, A., Horani, F., Kauffmann, Y., Lifshitz, E. Zeitschrift fur Physikalische Chemie 2018, 232, 1443; https://doi.org/10.1515/zpch-2018-1148.Search in Google Scholar
7. Kumar, U., Bandyopadhyay, M. Bioresour. Technol. 2006, 97, 104; https://doi.org/10.1016/j.biortech.2005.02.027.Search in Google Scholar
8. Wang, Y. H., Lin, S. H., Juang, R. S. J. Hazard. Mater. 2003, 102, 291; https://doi.org/10.1016/s0304-3894(03)00218-8.10.1016/S0304-3894(03)00218-8Search in Google Scholar
9. Yang, J., Volesky, B. Water Res. 1999, 33, 3357; https://doi.org/10.1016/s0043-1354(99)00043-3.10.1016/S0043-1354(99)00043-3Search in Google Scholar
10. Khokhar, A., Siddique, Z. J. Chem. Environ. Eng. 2015, 3, 944; https://doi.org/10.1016/j.jece.2015.03.009.Search in Google Scholar
11. Edokpayi, J., Odiyo, J., Msagati, T., Popoola, E. Sustainability 2015, 7, 14026; https://doi.org/10.3390/su71014026.Search in Google Scholar
12. Wang, G., Zhang, S., Yao, P., Chen, Y., Xu, X., Li, T., Gong, G. Arabian J. Chem. 2018, 11, 99; https://doi.org/10.1016/j.arabjc.2015.06.011.Search in Google Scholar
13. Cimá-Mukul, C., Abdellaoui, Y., Abatal, M., Vargas, J., Santiago, A. A., Barrón-Zambrano, J. A., Bioinorg. Chem. Appl. 2019, 1. https://doi.org/10.1155/2019/2814047.10.1155/2019/2814047Search in Google Scholar PubMed PubMed Central
14. Salman, S. M., Ali, A., Khan, B., Iqbal, M., Alamzeb, M., Environ. Sci. Pollut. Res. 2019, 1. https://doi.org/10.1007/s11356-019-04611-6.Search in Google Scholar PubMed
15. Adelaja, O. A., Bankole, A. C., Oladipo, M. E., Lene, D. B. Int. J. Energy Water Resour. 2019 3, 1; https://doi.org/10.1007/s42108-019-00012-0.Search in Google Scholar
16. Priyantha, N., Kotabewatta, P. J. Appl. Water Sci. 2019, 9, 37; https://doi.org/10.1007/s13201-019-0911-2.Search in Google Scholar
17. Gupta, S., Sharma, S., Kumar, A. J. W. S., Water Sci. Eng. 2019, 27. https://doi.org/10.1016/j.wse.2019.04.003.Search in Google Scholar
18. Ahmed, M., Fatima, H., Qasim, M., Gul, B., Ihsan-ul-Haq. BMC Complement. Altern. Med. 2017, 17, 386; https://doi.org/10.1186/s12906-017-1894-x.Search in Google Scholar PubMed PubMed Central
19. Jamil, M., ul Haq, I., Mirza, B., Qayyum, M. Ann. Clin. Microbiol. Antimicrobials 2012, 11, 11; https://doi.org/10.1186/1476-0711-11-11.Search in Google Scholar PubMed PubMed Central
20. Ngah, W. S. W., Hanafiah, M. A. K. M., Bioresour. Technol. 2008, 99, 3935. https://doi.org/10.1016/j.biortech.2007.06.011.Search in Google Scholar PubMed
21. Xu, G. F., Shen, Z. X., Guo, R. X. The kinetics studies for the adsorption of furadan from aqueous solution by orange peel, Advanced Materials Research. Trans Tech Publ, Switzerland. 2014, 87, p. 187.10.4028/www.scientific.net/AMR.842.187Search in Google Scholar
22. Salman, S. M., Ali, A., Khan, B., Iqbal, M., Alamzeb, M. Environ. Sci. Pollut. Res. 2019, https://doi.org/10.1007/s11356-019-04611-6.Search in Google Scholar PubMed
23. Anayurt, R. A., Sari, A., Tuzen, M. Chem. Eng. J. 2009, 151, 255; https://doi.org/10.1016/j.cej.2009.03.002.Search in Google Scholar
24. Yu, J., Tong, M., Sun, X., Li, B. J. Hazard. Mater. 2007, 143, 277; https://doi.org/10.1016/j.jhazmat.2006.09.021.Search in Google Scholar PubMed
25. Peng, J., He, Y., Ye, L., Shen, T., Liu, F., Kong, W., Liu, X., Zhao, Y. Anal. Chem. 2017, 89, 7593; https://doi.org/10.1021/acs.analchem.7b01441.Search in Google Scholar PubMed
26. Choi, K., Lee, S., Park, J. O., Park, J.-A., Cho, S.-H., Lee, S. Y., Lee, J. H., Choi, J.-W. Sci. Rep. 2018, 8, 1438; https://doi.org/10.1038/s41598-018-20017-9.Search in Google Scholar PubMed PubMed Central
27. Janik, P., Zawisza, B., Talik, E., Sitko, R. Microchim. Acta 2018, 185, 117; https://doi.org/10.1007/s00604-017-2640-2.Search in Google Scholar PubMed PubMed Central
28. Amegrissi, F., Maghri, I., Elkouali, M., Kenz, A., Salouhi, M., Ta, M., Glob. J. Sci. Front. Res. Environ. Earth Sci. 2013, 1.Search in Google Scholar
29. Enniya, I., Rghioui, L., Jourani, A. Sustain. Chem. Pharm. 2018, 7, 9; https://doi.org/10.1016/j.scp.2017.11.003.Search in Google Scholar
30. Hanafiah, M. A. K. M., Zakaria, H., Ngah, W. S. W. Water Air Soil Pollut. 2009, 201, 43; https://doi.org/10.1007/s11270-008-9926-2.Search in Google Scholar
31. Shi, Y., Zhang, T., Ren, H., Kruse, A., Cui, R. Bioresour. Technol. 2018, 247, 370; https://doi.org/10.1016/j.biortech.2017.09.107.Search in Google Scholar PubMed
32. Rao, K. S., Anand, S., Venkateswarlu, P. Acta Hydroch. Hydrob. 2011, 39, 384; https://doi.org/10.1002/clen.201000098.Search in Google Scholar
33. Huang, J., Li, Y., Cao, Y., Peng, F., Cao, Y., Shao, Q., Liu, H., Guo, Z. J. Mater. Chem. A 2018, 6, 13062; https://doi.org/10.1039/c8ta02861c.Search in Google Scholar
34. Sarı, A., Tuzen, M., J. Hazard. Mater. 2009, 164, 1004.10.1016/j.jhazmat.2008.09.002Search in Google Scholar PubMed
35. Bharagava, R. N., Mishra, S. Ecotoxicol. Environ. Saf. 2018, 147, 102; https://doi.org/10.1016/j.ecoenv.2017.08.040.Search in Google Scholar PubMed
36. Moussout, H., Aazza, M., El Akili, C. Int. J. Biol. Macromol. 2018, 108, 1063; https://doi.org/10.1016/j.ijbiomac.2017.11.018.Search in Google Scholar PubMed
37. Ho, Y. S. J. Hazard. Mater. 2009, 162, 539; https://doi.org/10.1016/j.jhazmat.2008.05.065.Search in Google Scholar PubMed
38. Çelekli, A., Bozkurt, H., Geyik, F. Bioresour. Technol. 2013, 129, 396.10.1016/j.biortech.2012.11.085Search in Google Scholar PubMed
39. Anwar, J., Shafique, U., Salman, M., Dar, A., Anwar, S. Bioresour. Technol. 2010, 101, 1752; https://doi.org/10.1016/j.biortech.2009.10.Search in Google Scholar
40. Singh, K., Singh, A., Hasan, S. Bioresour. Technol. 2006, 97, 994; https://doi.org/10.1016/j.biortech.2005.04.043.Search in Google Scholar PubMed
41. Guo, H., Bi, C., Zeng, C., Ma, W., Yan, L., Li, K., Wei, K. J. Mol. Liquids 2018, 249, 629; https://doi.org/10.1016/j.molliq.2017.11.096.Search in Google Scholar
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