TiNiSi-type YbIrMg with trivalent ytterbium

Maximilian Kai Reimann; Rainer Pöttgen

doi:10.1515/znb-2022-0149

Published by De Gruyter December 30, 2022

TiNiSi-type YbIrMg with trivalent ytterbium

Maximilian Kai Reimann and Rainer Pöttgen

From the journal Zeitschrift für Naturforschung B

https://doi.org/10.1515/znb-2022-0149

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Abstract

YbIrMg was obtained from a reaction of the elements in an equiatomic ratio in a sealed tantalum ampoule in a muffle furnace. The TiNiSi-type structure of YbIrMg was refined from single crystal X-ray diffractometer data: Pnma, a = 695.72(3), b = 405.84(6), c = 840.57(7) pm, wR = 0.0431, 511 F² values and 21 variables. A small degree of Mg/Ir mixing within the three-dimensional [IrMg] network leads to the refined composition YbIr_1.024(4)Mg_0.976(4). The course of the cell volume in the REIrMg series (Iandelli plot) points to trivalent ytterbium in YbIrMg.

Keywords: crystal structure; intermetallics; iridium; magnesium; ytterbium

Corresponding author: Rainer Pöttgen, Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, 48149 Münster, Germany, E-mail: pottgen@uni-muenster.de

Acknowledgments

We thank Dipl.-Ing. J. Kösters for the intensity data collection.

Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: None declared.
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2022-12-09

Accepted: 2022-12-20

Published Online: 2022-12-30

Published in Print: 2023-02-23

TiNiSi-type YbIrMg with trivalent ytterbium

Abstract

Acknowledgments

References

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