Abstract
The λ6Si-silicate [Cs(18-crown-6)]2[Si(OSO2CH3)6] (1) was synthesized by treatment of Si2Cl6 with Cs[OSO2CH3] in the presence of 18-crown-6. Compound 1 is the first example of a λ6Si-silicate with a methanesulfonate ligand. It was characterized by NMR spectroscopy and by single-crystal X-ray diffraction. The solid-state structure of 1 consists of discrete [Si(OSO2CH3)6]2– anions and two [Cs(18-crown-6)]+ cations (triclinic space group,
Funding source: Evonik Stiftung
Acknowledgments
The authors are grateful to the Evonik Operations GmbH, Rheinfelden (Germany), for the generous donation of Si2Cl6. I.G. wishes to thank the Evonik Foundation for a Ph.D. grant.
Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: None declared.
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
References
1. Kaczmarczyk, A., Urry, G. J. Am. Chem. Soc. 1960, 82, 751–752. https://doi.org/10.1021/ja01488a069.Search in Google Scholar
2. Kaczmarczyk, A., Millard, M., Urry, G. J. Inorg. Nucl. Chem. 1961, 17, 186–188. https://doi.org/10.1016/0022-1902(61)80212-1.Search in Google Scholar
3. Nuss, J. W., Urry, G. J. Inorg. Nucl. Chem. 1964, 26, 435–444. https://doi.org/10.1016/0022-1902(64)90008-9.Search in Google Scholar
4. Kaczmarczyk, A., Millard, M., Nuss, J. W., Urry, G. J. Inorg. Nucl. Chem. 1964, 26, 421–425. https://doi.org/10.1016/0022-1902(64)90006-5.Search in Google Scholar
5. Urry, G. Acc. Chem. Res. 1970, 3, 306–312. https://doi.org/10.1021/ar50033a004.Search in Google Scholar
6. Meyer-Wegner, F., Nadj, A., Bolte, M., Auner, N., Wagner, M., Holthausen, M. C., Lerner, H.-W. Chem. Eur J. 2011, 17, 4715–4719. https://doi.org/10.1002/chem.201003654.Search in Google Scholar
7. Schweizer, J. I., Scheibel, M. G., Diefenbach, M., Neumeyer, F., Würtele, C., Kulminskaya, N., Linser, R., Auner, N., Schneider, S., Holthausen, M. C. Angew. Chem. Int. Ed. 2016, 55, 1782–1786. https://doi.org/10.1002/anie.201510477.Search in Google Scholar
8. Tillmann, J., Meyer-Wegner, F., Nadj, A., Becker-Baldus, J., Sinke, T., Bolte, M., Holthausen, M. C., Wagner, M., Lerner, H.-W. Inorg. Chem. 2012, 51, 8599–8606. https://doi.org/10.1021/ic301283m.Search in Google Scholar
9. Tillmann, J., Lerner, H,-W., Bolte, M. Acta Crystallogr. 2015, C71, 883–888. https://doi.org/10.1107/s2053229615016484.Search in Google Scholar
10. Georg, I., Bursch, M., Stückrath, J. B., Alig, E., Bolte, M., Lerner, H.-W., Grimme, S., Wagner, M. Angew. Chem. Int. Ed. 2020, 59, 16181–16187.10.1002/anie.202006463Search in Google Scholar PubMed PubMed Central
11. Teichmann, J., Kunkel, C., Georg, I., Moxter, M., Santowski, T., Bolte, M., Lerner, H.-W., Bade, S., Wagner, M. Chem. Eur J. 2019, 25, 2740–2744. https://doi.org/10.1002/chem.201806298.Search in Google Scholar
12. Georg, I., Teichmann, J., Bursch, M., Tillmann, J., Endeward, B., Bolte, M., Lerner, H.-W., Grimme, S., Wagner, M. J. Am. Chem. Soc. 2018, 140, 9696–9708. https://doi.org/10.1021/jacs.8b05950.Search in Google Scholar
13. Teichmann, J., Wagner, M. Chem. Commun. 2018, 54, 1397–1412. https://doi.org/10.1039/c7cc09063c.Search in Google Scholar
14. Heininger, W., Stucka, R., Nagorsen, G. Z. Naturforsch. 1986, 41b, 702–707. https://doi.org/10.1515/znb-1986-0607.Search in Google Scholar
15. Seiler, O., Burschka, C., Götz, K., Kaupp, M., Metz, S., Tacke, R. Z. Anorg. Allg. Chem. 2007, 633, 2667–2670. https://doi.org/10.1002/zaac.200700189.Search in Google Scholar
16. Logemann, C., Klüner, T., Wickleder, M. S. Chem. Eur J. 2011, 17, 758–760. https://doi.org/10.1002/chem.201002619.Search in Google Scholar
17. Portius, P., Peerless, B., Davis, M., Campbell, R. Inorg. Chem. 2016, 55, 8976–8984. https://doi.org/10.1021/acs.inorgchem.6b01455.Search in Google Scholar
18. Harloff, J., Laatz, K. C., Lerch, S., Schulz, A., Stoer, P., Strassner, T., Villinger, A. Eur. J. Inorg. Chem. 2020, 2457–2464. https://doi.org/10.1002/ejic.202000281.Search in Google Scholar
19. Kowalke, J., Wagler, J., Viehweger, C., Brendler, E., Kroke, E. Chem. Eur J. 2020, 26, 8003–8006. https://doi.org/10.1002/chem.202000435.Search in Google Scholar
20. He, W., Zheng, X., Xiong, Y., Zhang, Z., Dong, J. Microvast Power Systems Co., Ltd. Silyl Ester Compound, its Preparation Method and Application in Electrolyte of Secondary Battery, 2020. CN 111217850.Search in Google Scholar
21. Schmidt, M., Schmidbaur, H., Sechser, L. J. Organomet. Chem. 1968, 15, 77–87.10.1016/S0022-328X(00)86326-3Search in Google Scholar
22. Schmidbaur, H., Sechser, L., Schmidt, M. Chem. Ber. 1969, 102, 376–377. https://doi.org/10.1002/cber.19691020143.Search in Google Scholar
23. Sonnek, G., Müller, G., Baumgarten, K.-G. J. Organomet. Chem. 1980, 194, 9–14. https://doi.org/10.1016/s0022-328x(00)90331-0.Search in Google Scholar
24. X-Area. Diffractometer Control Program System; STOE & Cie GmbH: Darmstadt (Germany), 2002.Search in Google Scholar
25. Sheldrick, G. M. Acta Crystallogr. 2008, A64, 112–122. https://doi.org/10.1107/s0108767307043930.Search in Google Scholar
26. Sheldrick, G. M. Acta Crystallogr. 2015, C71, 3–8.Search in Google Scholar
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