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Licensed Unlicensed Requires Authentication Published by De Gruyter June 2, 2014

Tris(2-isocyanocarbonsäureester)-Halbsandwich-Komplexe [(Aren)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir) / Tris(2-isocyanocarboxylic Acid Ester) – Halfsandwich Complexes [(arene)M(CNCHR1CO2R2)3]2+ (M = Ru, Rh, Ir)

  • Markus A Lang , Peter Mayer and Wolfgang Beck EMAIL logo
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-2004-0211

By reaction of chloro bridged halfsandwich complexes with silver salts and subsequent addition of isocyanocarboxylic acid esters the isocyanide complexes [(arene)M(CNCHR1CO2R2)3]2+(X−)2 (arene = C6Me6, p-cymene, M = Ru; arene = C5Me5, M = Rh, Ir), (R1 = H, Me, CHMe2, CH2Ph, X = BF4, CF3 SO3) were prepared and characterized. The structure of [(C5Me5) Ir(CNCH2CO2Et)3]2+(CF3SO3−)2 was determined by X-ray structure analysis.

Keywords: 2-Isocyano Carboxylic Acid Ethyl Ester; Halfsandwich Complexes; Ruthenium; Rhodium; Iridium
Received: 2003-12-17
Published Online: 2014-6-2
Published in Print: 2004-2-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 59 Issue 2

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