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Abstract
Two equivalents of N-lithio-N-trimethylsilyl-amino-9-borabicyclo[3.3.1]nonane (1) react with tin and lead dichloride by salt elimination to give the corresponding bis(amino)stannylene 2 and -plumbylene 3, respectively. The compounds 2 and 3 are monomers in solution and were characterized by 1H, 13C, 14N, 29Si, 119Sn and 207Pb NMR spectroscopy.
Received: 1997-5-22
Published Online: 2014-6-2
Published in Print: 1997-8-1
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