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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Röntgenstrukturuntersuchungen an Trimethylsilylaluminiumverbindungen / X-Ray Crystal Study of Trimethylsilylaluminium Compounds

  • Lutz Rösch , Gerald Altnau , Carl Krüger and Y.-H. Tsay
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-1983-0109
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Abstract

Structure, Tris(trimethylsilyl)aluminium, Sodium-tetrakis(trimethylsilyl)aluminate The crystal and molecular structures of three trimethylsilylaluminium compounds -tris(trimethylsilyl)aluminium coordinated to a diethylether molecule (1), sodium-tetrakis-(trimethylsilyl)aluminate coordinated to two toluene molecules (2b) and unsolvated sodium-tetrakis(trimethylsilyl)aluminate (2a) -have been determined by X-ray structure analysis. In all three compounds the aluminium is tetrahedrally coordinated, the Al-Si-distances lying between 2.44 and 2.49 Å. (1) is monomeric and (2a) and (2b) form linear chains resulting from contact-ion pair interactions.

: Structure; Tris(trimethylsilyl)aluminium; Sodium-tetrakis(trimethylsilyl)aluminate
Received: 1982-9-14
Published Online: 2014-6-2
Published in Print: 1983-1-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 38 Issue 1

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Contents
Kristallstrukturell von Verbindungen A2X2 (A=S, Se; X=Cl, Br) / Crystal Structures of Compounds A2X2 (A=S, Se; X=Cl, Br)
Derivatives of NPCl2NSOCl)2 and (NPCl2)2NSOCl, Part XXI [1]. The Synthesis of a Spiro Phosphazene Derivative of NPCl2(NSOPh)2
Darstellung und Kristallstruktur von Di-gold(III)bis(selenit)oxid, Au2(SeO3)2O / Preparation and Crystal Structure of Di-gold(III) Bis(selenite) Oxide, Au2(SeO3)2O
Na6CoS4 - ein Thiocobaltat mit isolierten CoS4-Anionen / Na6CoS4 - A Thiocobaltate with Isolated CoS4 Anions
Characterisation of a Binary Transition Metal Complex of a Purine 3′ -Nucleotide, {[Cu3(3′ -GMP)2(3′ -GMPH)2(H2O)5]·7H2O}n. [1]. Phosphate-only Binding of Copper(II)
Monomere und dimere Oxotrihalogenoselenate(IV): Darstellung, Struktur und Eigenschaften von [As(C6H5)4]SeOCl3 und [N(C2H5)4]SeOCl3 / Monomerie and Dimeric Oxotrihalogenoselenates(IV): Preparation, Structure and Properties of [As(C6H5)4]SeOCl3 and [N(C2H5)4]SeOCl3
Darstellung und Eigenschaften von Fe[ClC(COOEt)2]3 / Synthesis and Properties of Fe[ClC(COOEt)2]3
Röntgenstrukturuntersuchungen an Trimethylsilylaluminiumverbindungen / X-Ray Crystal Study of Trimethylsilylaluminium Compounds
Anhydrous Chromium(III) Carboxylates: Reactions of CrO3 with Carboxylic Acid Anhydrides
Kernresonanzspektroskopische Untersuchungen (1H-, 13C-, 31P-, 195Pt-NMR) an Alkinyl-Komplexen von PtII, PdII und NiII / Nuclear Magnetic Resonance (1H-, 13C-, 31P-, 195Pt-NMR)-Studies of Alkynyl Derivatives of PtII, PdII and NiII
Synthese und Strukturuntersuchungen von Iodocupraten(I): II. Diiodocuprate(I) RCuI2 mit isoherten Ketten 1∞ [Cul4/2–]·R1 = N-Methylpyridinium, R2 = Dimethyl ( 3 - dimethylamino - 2 - aza - 2 -propenyliden ) ammonium [1] / Syntheses and Structure Analyses of Iodocuprates(I): II. Diiodocuprates(I) RCuI2 with Isolated Chains 1∞ [CuI4/2–]; R1 = N-Methylpyridinium, R2 = Dimethyl(3-dimethylamino-2-aza-2-propenyliden) Ammonium
Gold(I)-Bis(diphenylphosphino)amid und einige Gold(I)-Bis(diarylphosphino)methanide mit sterisch anspruchsvollen Arylsubstituenten / Gold(I)-bis(diphenylphosphino)amide and Some Gold(I)-bis(diarylphosphino)methanides with Bulkyl Aryl Substituents
Übergangsmetallketen-Verbindungen, XII [1] Darstellung und Struktur von η5-C5H5(CO)2 [P(CH3)3]W-C≡C-C3H5 / Compounds of Transition Metal Ketenes, XII [1] Synthesis and Structure of η5-C5H5(CO)2 [P(CH3)3]W-C≡C-C3H5
Umsetzungen von Metall- und Metalloidverbindungen mit mehrfunktionellen Molekülen, XXXVII [1]. Neue Synthesewege zu cyclischen N-Silylharnstoffen und thioharnstoffen / Reactions of Metal and Metalloid Compounds with Polyfunctional Molecules, XXXVII [1]. New Syntheses of Cyclic N-Silylureas and -thioureas
Metallkomplexe der Liganden 1.4.7-Triazacyclononan-N.N′.N″ -tris-2-ethansulfonat (TES) und 1.4.7-Triazacyclononan-N.N′.N″ -trisethylacetat (TEA). Die Kristallstrukturen von Na[Ni(TES)(H2O)]·5H2O und Na[Cu(TES)]·3H2O / Transition Metal Complexes Containing the Ligands 1,4,7-Triazacyclononane-N,N′,N″-tris-2-ethanesulfonate (TES) and 1,4,7-Triazacyclononane-N,N′,N″-tris-ethylacetate (TEA). The Crystal Structures of Na[Ni(TES) (H2O)]·5H2O and of Na[Cu(TES)]·3H2O
Oxamidoximkomplexe des Kupfers: Monomeres Chloro(oxamidoximato)(oxamidoxim)kupfer(II) und polymeres Dichloro(oxamidoxim)kupfer(II). Strukturen und EPR spektroskopische Eigenschaften / Oxamide Oxime Complexes of Copper(II): Monomeric Chloro(oxamidoximato)(oxamidoxim)copper(II) and Polymerie Dichloro(oxamidoxim)copper(II). Structures and EPR Spectroscopic Properties
Kernresonanzspektroskopische Untersuchungen an Organophosphorverbindungen - Thiophosphorylbromide RR′P(S)Br: R,R′=CH3, C2H5, i-C3H7, t-C4H9 / NMR Studies on Organophosphorous Compounds - Thiophosphorylbromides RR′P(S)Br (R, R′ = CH3, C2H5, i-C3H7, t-C4H9)
Reactions of Alkylamino- and Dialkylaminotriphenylphosphonium Halides with Halogens and Interhalogen Compounds; Formation of Alkylaminotriphenylphosphonium Polyhalides
Simple Syntheses of 3-Substituted Indoles and their Application for High Yield 14C-Labelling
Bis(trimethylsiloxy)zinn(II): Ein Heterosiloxan als weicher Ligand / Bis(trimethylsiloxy)tin(II): A Heterosiloxane as Soft Ligand
Styrene Forming Elimination Reaction from β-Phenylethylphosphonium Salts+
C-13 NMR of Hecubine and Voaphylline, and a Study of Mass Spectral Fragmentation of Hecubine by Linked Scan Measurements
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