Die Struktur von Ph-P[C5H5(CO)2MnFe2(CO)6]. Ein Komplex mit einem verbrückenden μ3-Ph-P-Liganden.: The Structure of Ph-P[C5H5(CO)2MnFe2(CO)6], a Complex Containing a Bridging μ3-Ph-P-Ligand

G. Huttner; A. Frank; G. Mohr

doi:10.1515/znb-1976-0901

Open Access Published by De Gruyter June 2, 2014

Die Struktur von Ph-P[C₅H₅(CO)₂MnFe₂(CO)₆]. Ein Komplex mit einem verbrückenden μ³-Ph-P-Liganden.

The Structure of Ph-P[C₅H₅(CO)₂MnFe₂(CO)₆], a Complex Containing a Bridging μ³-Ph-P-Ligand

G. Huttner , A. Frank and G. Mohr

From the journal Zeitschrift für Naturforschung B

https://doi.org/10.1515/znb-1976-0901

The title compound, which may be prepared from C₅H₅(CO)₂Mn—P(Ph)Cl₂ and Fe₂(CO)₉ crystallizes in the monoclinic space group C 2/c with a = 1579(2), b = 1592(2), c = 1790(3) pm, β = 97.2(1)°, Z = 8. The structure was solved by direct methods. Full matrix refinement led to R₁= 0.066. The compound contains a threemembered metallocycle with two iron and one manganes atoms. Each iron atom bears three terminal carbonyl groups; the two CO-ligands of the C₅H₅Mn(CO)₂ fragment form unsymmetrical bridges with the two iron atoms. The metal triangel is capped by a Ph—P group with a triply bridging phosphorus atom.

Received: 1976-6-28

Published Online: 2014-6-2

Published in Print: 1976-9-1

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Die Struktur von Ph-P[C₅H₅(CO)₂MnFe₂(CO)₆]. Ein Komplex mit einem verbrückenden μ³-Ph-P-Liganden.

The Structure of Ph-P[C₅H₅(CO)₂MnFe₂(CO)₆], a Complex Containing a Bridging μ³-Ph-P-Ligand

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