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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Markierte Verbindungen, XXVI Das 1.2.3-Trichlorpropenylium-Ion als Intermediat bei der Fluorierung von 1.2.3.3-Tetrachlor-1-propen.

On Labelled Compounds, XXVI The 1,2,3-Trichloropropenylium Ion as Intermediate on the Fluorination of 1,2,3,3-Tetrachloro-1-propene

  • Friedrich Boberg and Rainer Voss

The sym. 1,2,3-trichloropropenylium ion is an intermediate on the reaction of 1,2,3,3-tetrachloro-l-propene with SbF3 to 1,2-dichloro-3,3-difluoro-1-propene. This is shown by the fluorination of 1,2,3,3-tetrachloro-(1,3-14C)-1-propene, with unsym. distribution of 14C, and studies with degradation products labelled with 14C.

Received: 1976-1-7
Published Online: 2014-6-2
Published in Print: 1976-5-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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