Phosphorus-Fluorine Chemistry, XXXI: Synthesis and Nuclear Magnetic Resonance Investigation of Methyl-substituted Piperidyl-fluorophosphoranes

M. J. C. Hewson; R. Schmutzler

doi:10.1515/znb-1972-0802

Open Access Published by De Gruyter June 2, 2014

Phosphorus-Fluorine Chemistry, XXXI

Synthesis and Nuclear Magnetic Resonance Investigation of Methyl-substituted Piperidyl-fluorophosphoranes

M. J. C. Hewson and R. Schmutzler

From the journal Zeitschrift für Naturforschung B

https://doi.org/10.1515/znb-1972-0802

The preparation of a series of methyl-substituted piperidyl-fluorophosphoranes is described, of general formula RR′NPF_4-nPh_n (where RR′N = 2-Me-piperidyl-, 3-Me-piperidyl-, or 4-Me-piperi-dyl; n = 0, 1, or 2), from the cleavage of silicon-nitrogen bonds in methyl-substituted piperidyl silanes by fluorophosphoranes. The structures of the new compounds are deduced from ¹⁹F and ³¹P n.m.r. data.

Received: 1972-5-26

Published Online: 2014-6-2

Published in Print: 1972-8-1

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Phosphorus-Fluorine Chemistry, XXXI

Synthesis and Nuclear Magnetic Resonance Investigation of Methyl-substituted Piperidyl-fluorophosphoranes

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