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Licensed Unlicensed Requires Authentication Published by De Gruyter February 17, 2016

Progress on sorption-enhanced reaction process for hydrogen production

  • Yi-Jiang Wu

    Yi-Jiang Wu received his BS in Applied Chemistry from Nanjing University in China and his PhD in Chemical Engineering from the University of Porto in Portugal under the supervision of Prof. A.E. Rodrigues. He is working at the East China University of Science and Technology (ECUST) as a postdoctoral fellow with Prof. Ping Li. His current research interest lies in the design and preparation of multifunctional material for process intensification and methane enrichment through PSA process.

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    , Ping Li

    Ping Li received her BS and MS in Chemical Engineering from Dalian University of Technology in China and her PhD in Chemical Engineering from the University of Porto in Portugal under the supervision of Prof. A.E. Rodrigues. She is a Professor in the School of Chemical Engineering at ECUST since 2007. Her research interests are focused on simulated moving-bed separation technology, expanded bed separation techniques, pressure swing/temperature swing, and hybrid separation technologies.

    , Jian-Guo Yu

    Jian-Guo Yu received his BS and MS in Chemical Engineering from the ECUST and his PhD in chemical engineering through a joint training from the ECUST and the University of Porto. He is a faculty member in the School of Resources and Environmental Engineering at the ECUST since 1988. Prof. Yu’s researches focus on integrated utilization of salt lake resources and industrial solid waste and gas separation technology. He has published more than 200 academic papers and issued more than 60 patents in resource integrated utilization.

    , Adelino F. Cunha

    Adelino F. Cunha finished high school at the Werner-Heisenberg-Gymnasium Rüsselsheim, Germany, with a special emphasis on economics, in 1995, and graduated with a Degree in Chemistry/Chemical Engineering from the Technische Universität Darmstadt (TUD), Germany. In 2009, he obtained his PhD in Chemical Engineering at the University of Porto with the thesis subject “Hydrogen production by catalytic decomposition of methane”. From 2009 to 2014, he was a postdoctorate working on “Hydrogen production by sorption-enhanced steam reforming of ethanol”. In 2014, he got a research position as a scientific investigator at FEUP, with emphasis on separation-enhanced reaction processes.

    and Alirio E. Rodrigues

    Alirio E. Rodrigues is an Emeritus Professor at the University of Porto where he graduated in Chemical Engineering in 1968. He obtained his PhD from the University of Nancy in 1973. He was a visiting Professor at the UT Compiègne, U. Oviedo, U. Virginia, ICT Mumbai, and UFCeará. He directed more than 60 PhD students and has published more than 560 papers, eight patents, and several books. His research focuses on cyclic adsorption/reaction processes, perfume engineering, and microencapsulation and lignin valorization.

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Abstract

Concerns about the environment and fossil fuel depletion led to the concept of “hydrogen economy”, where hydrogen is used as an energy carrier. Nowadays, hydrogen is mostly produced from fossil fuel resources by natural gas reforming, coal gasification, as well as the water-gas-shift (WGS) reaction involved in these processes. Alternatively, bioethanol, glucose, glycerol, bio-oil, and other renewable biomass-derived feedstocks can also be employed for hydrogen production via steam reforming process. The combination of steam reforming and/or WGS reaction with in situ CO2 adsorption is able to enhance the reaction above the thermodynamic equilibrium to produce more hydrogen, which is known as sorption-enhanced reaction process (SERP). In this review, research on thermodynamic studies, material developments, adsorptive reactor investigations, and cyclic operating process design for hydrogen production by SERP in recent decades has been surveyed and future research on these emerging areas has been discussed.


Corresponding authors: Yi-Jiang Wu, State Key Laboratory of Chemical Engineering, College of Chemical Engineering, East China University of Science and Technology (ECUST), Shanghai 20037, China, e-mail: . http://orcid.org/0000-0002-2595-6231; and Alirio E. Rodrigues, Laboratory of Separation and Reaction Engineering (LSRE), Associated Laboratory LSRE/LCM, Faculty of Engineering, Department of Chemical Engineering, University of Porto, Rua Dr. Roberto Frias s/n, 4200-465 Porto, Portugal, e-mail:

About the authors

Yi-Jiang Wu

Yi-Jiang Wu received his BS in Applied Chemistry from Nanjing University in China and his PhD in Chemical Engineering from the University of Porto in Portugal under the supervision of Prof. A.E. Rodrigues. He is working at the East China University of Science and Technology (ECUST) as a postdoctoral fellow with Prof. Ping Li. His current research interest lies in the design and preparation of multifunctional material for process intensification and methane enrichment through PSA process.

Ping Li

Ping Li received her BS and MS in Chemical Engineering from Dalian University of Technology in China and her PhD in Chemical Engineering from the University of Porto in Portugal under the supervision of Prof. A.E. Rodrigues. She is a Professor in the School of Chemical Engineering at ECUST since 2007. Her research interests are focused on simulated moving-bed separation technology, expanded bed separation techniques, pressure swing/temperature swing, and hybrid separation technologies.

Jian-Guo Yu

Jian-Guo Yu received his BS and MS in Chemical Engineering from the ECUST and his PhD in chemical engineering through a joint training from the ECUST and the University of Porto. He is a faculty member in the School of Resources and Environmental Engineering at the ECUST since 1988. Prof. Yu’s researches focus on integrated utilization of salt lake resources and industrial solid waste and gas separation technology. He has published more than 200 academic papers and issued more than 60 patents in resource integrated utilization.

Adelino F. Cunha

Adelino F. Cunha finished high school at the Werner-Heisenberg-Gymnasium Rüsselsheim, Germany, with a special emphasis on economics, in 1995, and graduated with a Degree in Chemistry/Chemical Engineering from the Technische Universität Darmstadt (TUD), Germany. In 2009, he obtained his PhD in Chemical Engineering at the University of Porto with the thesis subject “Hydrogen production by catalytic decomposition of methane”. From 2009 to 2014, he was a postdoctorate working on “Hydrogen production by sorption-enhanced steam reforming of ethanol”. In 2014, he got a research position as a scientific investigator at FEUP, with emphasis on separation-enhanced reaction processes.

Alirio E. Rodrigues

Alirio E. Rodrigues is an Emeritus Professor at the University of Porto where he graduated in Chemical Engineering in 1968. He obtained his PhD from the University of Nancy in 1973. He was a visiting Professor at the UT Compiègne, U. Oviedo, U. Virginia, ICT Mumbai, and UFCeará. He directed more than 60 PhD students and has published more than 560 papers, eight patents, and several books. His research focuses on cyclic adsorption/reaction processes, perfume engineering, and microencapsulation and lignin valorization.

Acknowledgments

This research has received funding from the Ministry of Science and Technology of the People’s Republic of China under the Program of International S&T Cooperation (2015DFG42220) and by Fundação para a Ciência e a Tecnologia of Portugal under the Cooperation Project FCT/CHINA 441.00, a China Postdoctoral Science Foundation-funded project (2015M570339), and the project is supported by the National Natural Science Foundation of China (no. 21506063) and Fundamental Research Funds for the Central Universities (222201514307). This work was cofinanced by QREN, ON2, and FEDER (Project NORTE-07-0124-FEDER-0000007).

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Received: 2015-7-13
Accepted: 2015-12-22
Published Online: 2016-2-17
Published in Print: 2016-6-1

©2016 by De Gruyter

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