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Licensed Unlicensed Requires Authentication Published by De Gruyter May 26, 2022

Cyclohexane oxidation using advanced oxidation processes with metals and metal oxides as catalysts: a review

  • Siphumelele Thandokwazi Mkhondwane and Viswanadha Srirama Rajasekhar Pullabhotla ORCID logo EMAIL logo
From the journal Physical Sciences Reviews

Abstract

Selective oxidation of cyclohexane has gained substantial interest in the field of research due to the prominence of its products in industrial processes. Particularly, advanced oxidation processes (AOPs) constitute a positive technology for the oxidation of cyclohexane owing to their high oxidation potentials and environmental benign properties. This review entails to address the progress made in advanced oxidation of cyclohexane over nanostructured metals and metal oxides catalysts. The main focus is directed toward the photocatalysis, Fenton oxidation and ozonation as advanced oxidation processes. Mainly, the fundamental principles, prime factors of the AOPs in conjunction with metal and metal oxide catalysts and the mechanistic insight toward the oxidation of cyclohexane are highlighted. The affirmative effects of the metals and metal oxide catalysts mainly focusing on particle size, structure and elemental composition is stressed. Lastly, the advantages and disadvantages of the AOPs and the strategic approaches to counter the disadvantages are also clearly elucidated.


Corresponding author: Viswanadha Srirama Rajasekhar Pullabhotla, Department of Chemistry, University of Zululand, Private Bag X1001, Kwa-Dlangezwa, 3886, South Africa, E-mail:

Award Identifier / Grant number: Incentive Fund Grant (Grant No: 103691)

Award Identifier / Grant number: Research Developmental Grant for Rated Researchers

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was supported by the National Research Foundation under Incentive Fund Grant (Grant No: 103691) and Research Developmental Grant for Rated Researchers.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Published Online: 2022-05-26

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