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BY-NC-ND 3.0 license Open Access Published by De Gruyter May 1, 2012

Supramolecular organotin tris-carboxylates: crystal and molecular structure of [Cy2NH2]2[1-Me3(H2O)SnOCO-3,5-(OOC)2C6H3]·EtOH

  • Daouda Ndoye , Libasse Diop EMAIL logo , Kieran C. Molloy and Gabriele Kociok-Köhn

Abstract

The crystal and molecular structure of [Cy2NH2]2[C6H3(CO2)3SnMe3·H2O]·CH3CH2OH (1) has been determined by single crystal X-ray diffraction analysis. In this compound, the tin atom is pentacoordinated by three methyl groups, one oxygen atom of a water molecule and one oxygen atom deriving from the tris-carboxylato ligand, in a trans-coordinated O2SnC3 environment. The dicyclohexylammonium cations are involved in intermolecular hydrogen bonds with the non-coordinated oxygen atoms of the carboxylate, while, along with hydrogen bonds involving water and ethanol, gives rise to a complex 3D lattice structure.


Corresponding author

Received: 2011-10-26
Accepted: 2012-2-22
Published Online: 2012-05-01
Published in Print: 2012-05-01

©2012 by Walter de Gruyter Berlin Boston

This article is distributed under the terms of the Creative Commons Attribution Non-Commercial License, which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

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