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Licensed Unlicensed Requires Authentication Published by De Gruyter February 9, 2018

Corrosion inhibition of steel in phosphoric acid

  • Anees A. Khadom EMAIL logo and Salah N. Farhan
From the journal Corrosion Reviews

Abstract

Phosphoric acid has been used in many industrial applications and can be in contact with a lot chemical and petrochemical equipment. Most of this equipment is made of steel alloys that may be damaged because of contact with acid. Corrosion inhibitors can be used for to protect steel alloys against several forms and various environments of corrosion. In this paper, the efficiency and applications of organic and inorganic inhibitors in different environments of phosphoric acid are investigated. More than 40 papers were collected and reviewed. Surveys of the stated works in phosphoric acid environments are documented. It was concluded that organic inhibitors performed as good corrosion inhibitors and are used widely. The use of inorganic inhibitors was limited. Most of studied inhibitors follow Langmuir’s adsorption isotherm, and the mechanism of the inhibition can be ascribed to the mixed effect on cathodic and anodic reactions. The synergistic effect was also addressed in the present work.

Acknowledgments

Special thanks go to Prof. Dr. Aprael S. Yaro for his continuous support and encouragement.

References

Alaoui LM, Kertit S, Bellaouchou A, Guenbour A, Benbachir A, Hammouti B. Phosphate of aluminum as corrosion inhibitor for steel in H3PO4. Port Electrochim Acta 2008; 26: 339–347.10.4152/pea.200804339Search in Google Scholar

Arab T, Al-Turkustani AM. Corrosion inhibition of steel in phosphoric acid by phenacyldimethyl sulfonium bromide and some of its p-substituted derivatives. Port Electrochim Acta 2006; 24: 53–69.10.4152/pea.200601053Search in Google Scholar

Aramaki K. Synergistic inhibition of zinc corrosion in 0.5 m NaCl by combination of cerium(III) chloride and sodium silicate. Corros Sci 2002; 44: 871–886.10.1016/S0010-938X(01)00087-7Search in Google Scholar

Balanaga Karthik B. Inhibition of mild steel corrosion in phosphoric acid using allyl methyl sulfide. Asian J Chem 2011; 23: 4276–4278.Search in Google Scholar

Bartos M, Kapusta SD, Hackerman N. A study of polymerization of propargyl alcohol on steel. J Electrochem Soc 1993; 140: 2604–2605.10.1149/1.2220870Search in Google Scholar

Behpour M, Ghoreishi SM, Soltani N, Salavati-Niasari M. The inhibitive effect of some bis-N,S-bidentate Schiff bases on corrosion behaviour of 304 stainless steel in hydrochloric acid solution. Corros Sci 2009; 51: 1073–1082.10.1016/j.corsci.2009.02.011Search in Google Scholar

Belghiti M, Tighadouini S, Karzazi Y, Dafali A, Hammouti B, Radi S, Solmaz R. New hydrazine derivatives as corrosion inhibitors for mild steel protection in phosphoric acid medium. Part A: Experimental study. J Mater Environ Sci 2016a; 7: 337–346.Search in Google Scholar

Belghiti M, Karzazi Y, Tighadouini S, Dafali A, Jama C, Warad I, Hammouti B, Radi S. New hydrazine derivatives as corrosion for mild steel in phosphoric acid medium. Part B: Theoretical investigation. J Mater Environ Sci 2016b; 7: 956–967.Search in Google Scholar

Ben Hmamou D, Salghi R, Zarrouk A, Zarrok H, Assouag M, Hammouti B, Al-Deyab S, Hezzat M. Inhibition of carbon steel corrosion in phosphoric acid solution by Alizarin red. Pharm Lett 2013; 5: 135–142.Search in Google Scholar

Benabdellah M, Benkaddour M, Hammouti B, Bendahhou M, Aouniti A. Inhibition of steel corrosion in 2 m H3PO4 by artemisia oil. Appl Surf Sci 2006; 252: 6212–6217.10.1016/j.apsusc.2005.08.030Search in Google Scholar

Bockris JO’M, Yang B. The mechanism of corrosion inhibition of iron in acid solution by acetylenic alcohols. J Electrochem Soc 1991; 138: 2237–2252.10.1149/1.2085956Search in Google Scholar

Dadgarinezhad A, Baghaei F. The inhibition mild steel corrosion in phosphoric acid solutions by 2-phenyl-1-hydrazine carboxamide. J Chil Chem Soc 2009; 54: 208–211.10.4067/S0717-97072009000300002Search in Google Scholar

Dafali A, Hammouti B, Touzani R, Kertit S, Ramdani A, Elkacemi K. Corrosion inhibition of copper in 3 per cent NaCl solution by new bipyrazolic derivatives. Anti-Corros Methods Mater 2002; 49: 96–104.10.1108/00035590210419335Search in Google Scholar

Dafali A, Hammouti B, Mokhlisse R, Kertit S, Elkacemi K. Substituted uracils as corrosion inhibitors for copper in 3% NaCl solution. Corros Sci 2003; 45: 1619–1630.10.1016/S0010-938X(02)00255-XSearch in Google Scholar

Ebenso E, Ekpe U, Ita B, Offiong O, Ibok U. Effect of molecular structure on the efficiency of amides and thiosemicarbazones used for corrosion inhibition of mild steel in hydrochloric acid. Mater Chem Phys 1999; 60: 79–90.10.1016/S0254-0584(99)00074-7Search in Google Scholar

Feng Y, Siow KS, Teo WK, Hsieh AK. The synergistic effects of propargyl alcohol and potassium iodide on the inhibition of mild steel in 0.5 m sulfuric acid solution. Corros Sci 1999; 41: 829–852.10.1016/S0010-938X(98)00144-9Search in Google Scholar

George G. Corrosion inhibitors. Houston, TX: NACE, 1974.Search in Google Scholar

Guan N, Xueming Li, Fei Li. Synergistic inhibition between o-phenanthroline and chloride ion on cold rolled steel corrosion in phosphoric acid. Mater Chem Phys 2004; 86: 59–68.10.1016/j.matchemphys.2004.01.041Search in Google Scholar

Jabeera B, Shibli S, Anirudhan T. Synergistic inhibitive effect of tartarate and tungstate in preventing steel corrosion in aqueous media. Appl Surf Sci 2006; 252: 3520–3524.10.1016/j.apsusc.2005.05.029Search in Google Scholar

Jianguo Y, Lin W, Otieno-Alego V, Schweinsberg D. Polyvinylpyrrolidone and polyethylenimine as inhibitors for the corrosion of a low carbon steel in phosphoric acid. Corros Sci 1995; 37: 975–985.10.1016/0010-938X(95)00008-8Search in Google Scholar

Khadom A. The influence of temperature on corrosion inhibition of carbon steel in phosphoric acid. MSc thesis, University of Baghdad, 2000.Search in Google Scholar

Khadom A. Mathematical models for prediction of corrosion inhibition rates of steel in acidic media. The First National Conference for Engineering Sciences, November 7–8, Baghdad, Iraq. Baghdad, Iraq: IEEE, 2012.10.1109/NCES.2012.6740458Search in Google Scholar

Khadom A. Kinetics and synergistic effect of iodide ion and naphthylamine for the inhibition of corrosion reaction of mild steel in hydrochloric acid. React Kinet Mech Catal 2015; 115: 463–481.10.1007/s11144-015-0873-9Search in Google Scholar

Khadom A, Yaro A. Protection of low carbon steel in phosphoric acid by potassium iodide. Prot Met Phys Chem Surf 2011; 47: 662–669.10.1134/S2070205111050078Search in Google Scholar

Kuteja P, Vosta J, Pancir J, Hackerman N. Electrochemical and quantum chemical study of propargyl alcohol adsorption on iron. J Electrochem Soc 1995; 142: 1847–1850.10.1149/1.2044204Search in Google Scholar

Li XM, Tang LB, Liu HC, Mu GN, Liu GH. Influence of halide ions on inhibitive performance of cetyl trimethyl ammonium bromide in various concentrations of phosphoric acid for cold rolled steel. Mater Lett 2008; 62: 2321–2324.10.1016/j.matlet.2007.11.080Search in Google Scholar

Li XH, Deng SD, Fu H, Li T. Adsorption and inhibition of 6-benzylaminopurine on cold rolled steel in 1.0 m HCl. Electrochim Acta 2009a; 54: 4089–4098.10.1016/j.electacta.2009.02.084Search in Google Scholar

Li XH, Deng SD, Fu H. Synergistic inhibition effect of red tetrazolium and uracil on the corrosion of cold rolled steel in H3PO4 solution: weight loss, electrochemical, and AFM approaches. Mater Chem Phys 2009b; 115: 815–824.10.1016/j.matchemphys.2009.02.025Search in Google Scholar

Li XH, Deng SD, Fu H. Benzyltrimethylammonium iodide as a corrosion inhibitor for steel in phosphoric acid produced by dihydrate wet method process. Corros Sci 2011; 53: 664–670.10.1016/j.corsci.2010.10.013Search in Google Scholar

Li XH, Deng SD, Xie XG. Inhibition effect of tetradecylpyridinium bromide on the corrosion of cold rolled steel in 7.0 m H3PO4. Arabian J Chem 2017; 10: S3715–S3724.10.1016/j.arabjc.2014.05.004Search in Google Scholar

Mathur PB, Vasudevan T. Reaction rate studies for the corrosion of metals in acids. I. Iron in mineral acids. Corros 1982; 38: 171–178.10.5006/1.3579270Search in Google Scholar

Messali M, Lgaz H, Dassanayake R, Salghi R, Jodeh S, Abidi N, Hamed O. Guar gum as efficient non-toxic inhibitor of carbon steel corrosion in phosphoric acid medium: electrochemical, surface, DFT and MD simulations studies. J Mol Struct 2017; 1145: 43–54.10.1016/j.molstruc.2017.05.081Search in Google Scholar

Morad MS. Influence of propargyl alcohol on the corrosion behaviour of mild steel in H3PO4 solutions. Mater Chem Phys 1999; 60: 188–195.10.1016/S0254-0584(99)00090-5Search in Google Scholar

Mu GN, Li XM, Li F. Synergistic inhibition between o-phenanthroline and chloride ion on cold rolled steel corrosion in phosphoric acid. Mater Chem Phys 2004; 86: 59–68.10.1016/j.matchemphys.2004.01.041Search in Google Scholar

Noor A. The inhibition of mild steel corrosion in phosphoric acid solutions by some N-heterocyclic compounds in the salt form. Corros Sci 2005; 47: 33–55.10.1016/j.corsci.2004.05.026Search in Google Scholar

Noyel V, Rohith P, Manivannan R. Psidium guajava leaf extract as green corrosion inhibitor for mild steel in phosphoric acid. Int J Electrochem Sci 2015; 10: 2220–2238.Search in Google Scholar

Onuchukwu A, Lori J. The mechanism of the corrosion inhibition of carbon steel in neutral medium by chromate and nickel ions. Corros Sci 1984; 24: 833–841.10.1016/0010-938X(84)90122-7Search in Google Scholar

Poornima T, Jagannath N, Nityananda S. Effect of 4-(N,N-diethylamino)benzaldehyde thiosemicarbazone on the corrosion of aged 18 Ni 250 grade maraging steel in phosphoric acid solution. Corros Sci 2011; 53: 3688–3696.10.1016/j.corsci.2011.07.014Search in Google Scholar

Qu Q, Hao Z, Jiang S, Li L, Bai W. Synergistic inhibition between dodecylamine and potassium iodide on the corrosion of cold rolled steel in 0.1 m phosphoric acid. Mater Corros 2008; 59: 883–888.10.1002/maco.200804176Search in Google Scholar

Ramazan S, Ece A, Gülfeza K. Adsorption and corrosion inhibition effect of 2-((5-mercapto-1,3,4-thiadiazol-2-ylimino)methyl)phenol Schiff base on mild steel. Mater Chem Phys 2011; 125: 796–801.10.1016/j.matchemphys.2010.09.056Search in Google Scholar

Roberge R. Handbook of corrosion engineering, 1st ed., New York, NY: McGraw Hill, 1999.Search in Google Scholar

Saratha R, Meenakshi R. Dimethylaminobenzylidene acetone as corrosion inhibitor for mild steel in acid medium. Rasayan J Chem 2011; 4: 251–263.Search in Google Scholar

Sivaraju M, Kannan K. Inhibitive properties of plant extract (Acalypha indica L.) on mild steel corrosion in 1 N phosphoric acid. Int J ChemTech Research 2010; 2: 1243–1253.Search in Google Scholar

Subramanyam NC, Sheshardi BS, Mayanna SA. Thiourea and substituted thioureas as corrosion inhibitors for aluminium in sodium nitrite solution. Corros Sci 1993; 34: 563–571.10.1016/0010-938X(93)90272-ISearch in Google Scholar

Talbot D, Talbot J. Corrosion science and technology. Boca Raton, FL: CRC Press, 2000.Search in Google Scholar

Trethewey KR, Chamberlain J. Corrosion for science and engineering, 2nd ed., Harlow, UK: Longman, 1996.Search in Google Scholar

Uhlig HH. Corrosion and corrosion control, 2nd ed., London: John Wiley & Sons, Inc., 1971.Search in Google Scholar

Wang G, Yin J, Zhang Q, Pu X. Corrosion inhibition of low-carbon steel in phosphoric acid solution by 2-mercaptobenzoxazole. Corrosion 2000; 56: 1083–1085.10.5006/1.3294392Search in Google Scholar

Wang L, Zhu MJ, Yang FC, Gao CW. Study of a triazole derivative as corrosion inhibitor for mild steel in phosphoric acid solution. Int J Corros 2012; 2012: 1–6/573964.10.1155/2012/573964Search in Google Scholar

Yaro A, Khadom A. Polarisation resistance behaviour of corrosion inhibition of low carbon steel in H3PO4 acid. Int J Surf Sci Eng 2010; 4: 429–438.10.1504/IJSURFSE.2010.035145Search in Google Scholar

Yaro A, Khadom A, Wael R. Apricot juice as green corrosion inhibitor of mild steel in phosphoric acid. Alexandria Eng J 2013; 52: 129–135.10.1016/j.aej.2012.11.001Search in Google Scholar

Zarrok H, Zarrouk A, Salghi R, Hammouti B, Elbakri M, Touhami M, Bentiss F, Oudda H. Study of a cysteine derivative as a corrosion inhibitor for carbon steel in phosphoric acid solution. Res Chem Intermed 2014; 40: 801–815.10.1007/s11164-012-1004-0Search in Google Scholar

Zucchi F, Trabanelli G, Brunoro G. Iron corrosion inhibition in hot 4 m HCl solution by t-cinnamaldehyde and its structure-related compounds. Corros Sci 1994; 36: 1683–1690.10.1016/0010-938X(94)90123-6Search in Google Scholar

Received: 2017-6-29
Accepted: 2018-1-6
Published Online: 2018-2-9
Published in Print: 2018-6-27

©2018 Walter de Gruyter GmbH, Berlin/Boston

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