Skip to content
BY-NC-ND 3.0 license Open Access Published by De Gruyter Open Access November 17, 2014

Hydrogen production from ethanol in nitrogen microwave plasma at atmospheric pressure

  • Bartosz Hrycak EMAIL logo , Dariusz Czylkowski , Robert Miotk , Miroslaw Dors , Mariusz Jasinski and Jerzy Mizeraczyk
From the journal Open Chemistry

Abstract

Hydrogen seems to be one of the most promising alternative energy sources. It is a renewable fuel as it could be produced from e.g. waste or bio-ethanol. Furthermore hydrogen is compatible with fuel cells and is environmentally clean. In contrast to conventional methods of hydrogen production such as water electrolysis or coal gasification we propose a method based on atmospheric pressure microwave plasma. In this paper we present results of the experimental investigations of hydrogen production from ethanol in the atmospheric pressure plasma generated in waveguide-supplied cylindrical type nozzleless microwave (2.45 GHz) plasma source (MPS). Nitrogen was used as a working gas. All experimental tests were performed with the nitrogen flow rate Q ranged from 1500 to 3900 NL h-1 and absorbed microwave power PA up to 5 kW. Ethanol was introduced into the plasma using the induction heating vaporizer. The process resulted in an ethanol conversion rate greater than 99%. The hydrogen production rate was up to 728 NL[H2] h-1 and the energy efficiency was 178 NL[H2] per kWh of absorbed microwave energy.

Graphical Abstract

References

[1] Holladay J.D., Hu J., King D.L., Wang Y., Catalysis Today, 2009, 139, 244 10.1016/j.cattod.2008.08.039Search in Google Scholar

[2] Abbas H.F., Wan Daud W.M.A., Int. J. Hydrogen Energy, 2010, 35, 1160 10.1016/j.ijhydene.2009.11.036Search in Google Scholar

[3] Shin D.H., Hong Y.C., Lee S.J., Kim Y.J., Cho C.H., Ma S.H., et al., Surf. & Coat. Technol., 2013, 228, S520 10.1016/j.surfcoat.2012.04.071Search in Google Scholar

[4] Boudesocque N., Vandensteendam C., Lafon C., Girold C., Baronnet J.M., 16th World Hydrogen Energy Conference, 13-16 June 2006, Lyon, France (Curran Associates, Red Hook, NY, 2006) 1616 Search in Google Scholar

[5] Liu X.Z., Liu Ch.J., Eliasson B., Chinese Chemical Letters, 2003, 14, 631 Search in Google Scholar

[6] Pineda M., Santiago I., Calzada M.D., Feugeas J., 32nd EPS Conference on Plasma Physics, 27 June – 1 July, Tarragona, 2005, Spain, http://epsppd.epfl.ch/Tarragona/pdf/P4_135.pdf, p-4.135 Search in Google Scholar

[7] Sekine Y., Urasaki K., Asai S., Matsukata M., Kikuchia E., Kadob S., Chem. Commun., 2005, 78 10.1039/b412552eSearch in Google Scholar PubMed

[8] Aubry O., Met C., Khacef A., Cormier J.M., Chem. Engineering J., 2005, 106, 241 10.1016/j.cej.2004.12.003Search in Google Scholar

[9] Wang Y.-F., You Y.-S., Tsai C.-H., Wang L.-C., Int. J. Hydrogen Energy, 2010, 35, 9637 10.1016/j.ijhydene.2010.06.104Search in Google Scholar

[10] Rincon R., Jimenez M., Munoz J., Saez M., Calzada M.D., Plasma Chem. Plasma Process, 2014, 34, 145 10.1007/s11090-013-9502-4Search in Google Scholar

[11] Tang L., Huang H., Fuel, 2005, 84, 2055 10.1016/j.fuel.2005.04.015Search in Google Scholar

[12] Hrabovsky M., Konrad M., Kopecky V., Hlina M., Kavka T., van Oost G., et al., Czechoslovak J. Phys., 2006, 56, B1199 10.1007/s10582-006-0350-9Search in Google Scholar

[13] Kim Y., Abbate S., Ziock H., Anderson G.K., Rosocha L.A., IEEE Transaction on Plasma Science, 2007, 35, 1677 10.1109/TPS.2007.910139Search in Google Scholar

[14] Yoon S.J., Lee J.G., Energy Fuels, 2012, 26, 524 10.1021/ef2013584Search in Google Scholar

[15] Moustakas K., Fatta D., Malamis S., Haralambous K., Loizidou M., J. Hazardous Materials B, 2005, 123, 120 10.1016/j.jhazmat.2005.03.038Search in Google Scholar PubMed

[16] Gomez E., Amutha Rani D., Cheeseman C.R., Deegan D., Wise M., Boccaccini A.R., J. Hazardous Materials, 2009, 161, 614 10.1016/j.jhazmat.2008.04.017Search in Google Scholar PubMed

[17] Du Ch., Li H., Zhang L., Wang J., Huang D., Xiao M., et al., Int. J. Hydrogen Energy, 2012, 37, 8318 10.1016/j.ijhydene.2012.02.166Search in Google Scholar

[18] Hydrogen Energy and Fuel Cells - A vision of our future, European Commission, Luxembourg: Office for Official Publications of the European Communities, 2003, EUR 20719 EN, ISBN 92-894-5589-6 Search in Google Scholar

[19] Randolph K., U.S. DOE. Hydrogen Production. Annual Merit Review and Peer Evaluation Meeting. May 16, 2013 http://www.hydrogen.energy.gov/pdfs/review13/pd000_randolph_2013_o.pdf Search in Google Scholar

[20] Burlica R., Shih K.-Y., Hnatiuc B., Locke B.R., Ind. Eng. Chem. Res., 2011, 50, 9466 10.1021/ie101920nSearch in Google Scholar

[21] Sarmiento B., Brey J.J., Viera I.G., Gonzalez-Elipe A.R., Cotrino J., Rico V.J., J. Power Sources, 2007, 169, 140 10.1016/j.jpowsour.2007.01.059Search in Google Scholar

[22] Dors M., Izdebski T., Berendt A., Mizeraczyk J., Int. J. Plasma Envir. Sci. Technol., 2012, 6, 93 Search in Google Scholar

[23] Mishra L.N., Shibata K., Ito H., Yugami N., Nishida Y., J. Natural Gas Chem., 2004, 13, 82 Search in Google Scholar

[24] Wang Y.-F., Tsai C.-H., Chang W.-Y., Kuo Y.-M., Int. J. Hydrogen Energy, 2010, 35, 135 10.1016/j.ijhydene.2009.10.088Search in Google Scholar

[25] Tatarova E., Bundaleska N., Dias F.M., Tsyganov D., Saavedra R., Ferreira C.M., Plasma Sources Sci. Technol., 2013, 22, 065001 10.1088/0963-0252/22/6/065001Search in Google Scholar

[26] Petitpas G., Rollier J.-D., Darmon A., Gonzalez-Aguilar J., Metkemeijer R., Fulcheri L., Int. J. Hydrogen Energy, 2007, 32, 2848 10.1016/j.ijhydene.2007.03.026Search in Google Scholar

[27] Sun S.,. Yan W, Sun P., J. Chen, Energy, 2012, 44, 911 10.1016/j.energy.2012.04.059Search in Google Scholar

[28] Jasinski M.,. Dors M, Mizeraczyk J., Plasma Chemistry and Plasma Processing, 2009, 29, 363 10.1007/s11090-009-9183-1Search in Google Scholar

[29] Jasinski M., Dors M., Mizeraczyk J., Eur. Phys. J. D, 2009, 54, 179 10.1140/epjd/e2008-00221-1Search in Google Scholar

[30] Hrycak B., Czylkowski D., Jasinski M., Mizeraczyk J., Przegląd Elektrotechniczny, 2012, 88, 98 Search in Google Scholar

[31] Laux, C.O., Radiation and Nonequilibrium Collisional-Radiative Models, In: Fletcher D., Charbonnier J.-M., Sarma G.S.R., Magin T., (Eds.), von Karman Institute Lecture Series 2002-07, Physico-Chemical Modeling of High Enthalpy and Plasma Flows, Rhode-Saint-Genese, Belgium, 2002 Search in Google Scholar

[32] Luque J., Crosley D.R., LIFBASE: database and spectral simulation program (version 1.5). SRI international report 1999, MP: 99-009 Search in Google Scholar

[33] Machala Z., Janda M., Hensel K., Jedlovsky I., Lestinska L., Foltin V., Martisovits V., Morvova M., J. Mol. Spectros., 2007, 243, 194 10.1016/j.jms.2007.03.001Search in Google Scholar

[34] Raud J., Laan M., Jogi I., J. Phys. D: Appl. Phys., 2011, 44, 345201 10.1088/1751-8113/44/34/345201Search in Google Scholar

[35] Okada A., Kijima K., J. Phys. D Appl. Phys., 2002, 35, 2126 10.1088/0022-3727/35/17/308Search in Google Scholar

[36] Laux C.O., Spence T.G., Kruger C.H., Zare R.N., Plasma Sources Sci. Technol., 2003, 12, 125 10.1088/0963-0252/12/2/301Search in Google Scholar

[37] Hrycak B., Jasiński M., Mizeraczyk J., Naumov V., Chernyak V., Proc. Int. Conf. on Research and Applications of Plasmas, 12-16 Sep. 2011, Warsaw, Poland, 2011 Search in Google Scholar

[38] Marinov N.M., Int. J. Chem. Kinetics, 1999, 31, 183 10.1002/(SICI)1097-4601(1999)31:3<183::AID-KIN3>3.0.CO;2-XSearch in Google Scholar

[39] Hrycak B., Czylkowski D., Miotk R., Dors M., Jasinski M., Mizeraczyk J., Int. J. Hydrogen Energy (in press) http://dx.doi.org/10.1016/j.ijhydene.2014.02.160 10.1016/j.ijhydene.2014.02.160Search in Google Scholar

[40] Tsyganov D., Bundaleska N., Tatarova E., Ferreira C., Int. J. Hydrogen Energy, 2013, 38, 14512 10.1016/j.ijhydene.2013.08.127Search in Google Scholar

[41] Dors M., Nowakowska H., Jasiński M., J. Mizeraczyk, Plasma Chem. Plasma Process, 2013, 34, 313 10.1007/s11090-013-9510-4Search in Google Scholar

[42] Bundaleska N., Tsyganov D., Tatarova E., Dias F.M., Int. J. Hydrogen Energy, 2014, 39, 5663 10.1016/j.ijhydene.2014.01.194Search in Google Scholar

[43] Henriques J., Bundaleska N., Tatarova E., Dias F.M., Ferreira C.M., Int. J. Hydrogen Energy, 2011, 36, 345 10.1016/j.ijhydene.2010.09.101Search in Google Scholar

[44] Bundaleska N., Tsyganov D., Saavedra R., Tatarova E., Dias F.M., Int. J. Hydrogen Energy, 2013, 38, 9145 10.1016/j.ijhydene.2013.05.016Search in Google Scholar

Received: 2014-1-31
Accepted: 2014-5-14
Published Online: 2014-11-17

© 2015 Bartosz Hrycak et al.

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Downloaded on 16.4.2024 from https://www.degruyter.com/document/doi/10.1515/chem-2015-0039/html
Scroll to top button