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Publicly Available Published by De Gruyter January 1, 2009

Cycloruthenated compounds as efficient catalyst for asymmetric hydride transfer reaction

  • Jean-Baptiste Sortais , Laurent Barloy , Claude Sirlin , André H. M. de Vries , Johannes G. de Vries and Michel Pfeffer
From the journal Pure and Applied Chemistry
https://doi.org/10.1351/pac200678020457
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Abstract

Cycloruthenated complexes obtained by direct C-H activation of enantiopure aromatic primary and secondary amines are efficient catalysts in asymmetric hydride transfer reaction. Reduction of acetophenone has been achieved rapidly with enantiomeric excesses (ee's) ranging from 38 to 89 %. The importance of Ru-C bond in the catalytic efficiency is highlighted.

Keywords: amines; catalysis; chirality; cyclometallation; enantioselectivity; high-throughput experiments; ketones; reduction; ruthenium

Conference

IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS-13), International Symposium on Organometallic Chemistry Directed Toward Organic Synthesis, OMCOS, Organometallic Chemistry Directed Toward Organic Synthesis, 13th, Geneva, Switzerland, 2005-07-17–2005-07-21

Published Online: 2009-01-01
Published in Print: 2006-01-01

© 2013 Walter de Gruyter GmbH, Berlin/Boston

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From the journal
Pure and Applied Chemistry
Pure and Applied Chemistry
Volume 78 Issue 2
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Journal and Issue

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Preface
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