热压温度对一种Ni-Co-Al粉末高温合金摩擦学行为的影响<sup>*</sup>

doi:10.11901/1005.3093.2013.602

材料研究学报

2014, Vol. 28

Issue (3): 173-179 DOI: 10.11901/1005.3093.2013.602

本期目录 | 过刊浏览

热压温度对一种Ni-Co-Al粉末高温合金摩擦学行为的影响^*

辛成来^1,²,马勤¹,王文珍²(

),贾均红²

1. 兰州理工大学材料科学与工程学院兰州 730050
2. 中国科学院兰州化学物理研究所固体润滑国家重点实验室兰州 730000

Effect of Hot-press Sintering Temperature on Tribological Performance of Ni-Co-Al Superalloy

Chenglai XIN^1,²,Qin MA¹,Wenzhen WANG^2,^**(

),Junhong JIA²

1. School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou, 730050
2. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000

引用本文:

辛成来,马勤,王文珍,贾均红. 热压温度对一种Ni-Co-Al粉末高温合金摩擦学行为的影响^*[J]. 材料研究学报, 2014, 28(3): 173-179.
Chenglai XIN, Qin MA, Wenzhen WANG, Junhong JIA. Effect of Hot-press Sintering Temperature on Tribological Performance of Ni-Co-Al Superalloy[J]. Chinese Journal of Materials Research, 2014, 28(3): 173-179.

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摘要:

采用粉末冶金工艺制备一种Ni-Co-Al系高温合金, 研究了该合金的室温力学性能和高温(800℃)摩擦学性能与热压温度的关系。结果表明：合金的密度、硬度、抗压强度随着热压温度的提高而提高, 但是热压温度高于1200℃后提高不大; 随着热压温度的提高合金的高温摩擦学性能有所改善, 磨痕表面形成了保护性的氧化物“釉质层”, “釉质层”与基体的结合强度影响了合金的高温摩擦性能, 而结合强度又可能与热压烧结试样的致密度有关。磨痕表面犁沟的深浅与热压温度有很大关系。

关键词 ：金属材料, 粉末高温合金, 热压温度, 摩擦学行为

Abstract：

A Ni-Co-Al superalloy was prepared by powder metallurgy(mechanical alloying + hot-press sintering). Then the effect of hot-press sintering temperature on the mechanical property of the alloy at ambient temperatures and the tribological performance at 800℃ were investigated. Results show that the density, hardness and compressive strength of the alloy increase with the increase of sintering temperature, while these properties change little when the sintering temperature above 1200℃. As the sintering temperature increases, the tribological performance of the alloy at 800℃gets better. The examination of the worn surface morphology by SEM and XPS found that a glaze-like oxide scale formed on the worn surface, which seemed to be beneficial to the tribological performance. The adhesive strength between the oxide scale and the substrate affects the tribological performance of the alloy, which may relate to higher density induced by higher sintering temperature. The examination of the worn surface with 3D non-contact surface mapping profiler exhibits that the depth of abrasion grooves is dependent on the hot-pressing temperature.

Key words： metal material P/M superalloy hot-press sintering temperature tribological performance

收稿日期: 2013-08-20

基金资助:* 国家自然科学青年基金51101166 资助项目。

作者简介:

本文联系人: 王文珍

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表1 真空热压烧结工艺参数

图1 球磨30 h, 40 h和50 h粉末的SEM照片

图2 球磨30 h,40 h和50 h粉末的XRD图谱

图3 Ni-10Co-5Al合金的XRD图谱

图4 在1260℃烧结的Ni-10Co-5Al合金的SEM照片

图5 Ni-10Co-5Al合金硬度、抗压强度随热压温度的变化曲线

图6 Ni-10Co-5Al 合金在800℃摩擦测试的摩擦系数随热压温度的变化关系

图7 Ni-10Co-5Al合金在800℃摩擦测试的磨损率随热压温度的变化关系

图8 热压温度分别为1100℃、1200℃和1260℃的Ni-10Co-5Al合金的磨损表面SEM照片

图9 热压温度分别为1100℃、1200℃和1260℃的Ni-10Co-5Al合金磨损表面的三维轮廓图

图10 1260℃烧结Ni-10Co-5Al 合金磨损表面XPS图谱

表2 XPS结合能对照表

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