Deep-Blue Thermally Activated Delayed Fluorescence Emitters Containing Diphenyl Sulfone Group for Organic Light Emitting Diodes
Novel blue thermally activated delayed fluorescence (TADF) emitters, D1-DPS and D2-DPS, were designed and synthesized. Diphenyl sulfone (DPS) group functioned as a common acceptor, and it combined with each of two different spiro-acridine groups, D1 and D2. The calculated
energy differences (ΔE
ST) of the singlet and triplet excited states of D1-DPS (0.062 eV) and D2-DPS (0.128 eV) had sufficiently small ΔE
ST values, which is favorable in the thermally activated reverse intersystem crossing (RISC)
process from the T1 state to the S1 state. A device doped 10 wt% of D2-DPS with ADN host material, obtained 5.05% of external quantum efficiency with deep-blue emission having CIE
xy
coordinates of (0.152, 0.065). The results showed that these molecules
are promising host-free TADF deep-blue emitters by inhibiting concentration quenching.
Keywords: Deep-Blue Emitter; Diphenyl Sulfone Derivative; Organic Light Emitting Diodes; Thermally Activated Delayed Fluorescence
Document Type: Research Article
Affiliations: 1: Department of Chemical Engineering, Hongik University, Seoul 04066, Korea 2: Department of Information Display, Hongik University, Seoul 04066, Korea
Publication date: 01 August 2019
- Journal for Nanoscience and Nanotechnology (JNN) is an international and multidisciplinary peer-reviewed journal with a wide-ranging coverage, consolidating research activities in all areas of nanoscience and nanotechnology into a single and unique reference source. JNN is the first cross-disciplinary journal to publish original full research articles, rapid communications of important new scientific and technological findings, timely state-of-the-art reviews with author's photo and short biography, and current research news encompassing the fundamental and applied research in all disciplines of science, engineering and medicine.
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