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Photoluminescence study of mesoporous MCM-41 and Ti-grafted MCM-41

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Abstract

Photoluminescence combined with diffuse reflectance UV—Vis spectroscopy was used to characterise both the pure siliceous MCM-41 and Ti-MCM-41 containing tetrahedral Ti(IV) species anchored onto the inner walls of the siliceous MCM-41. Both Ti-MCM-41 and MCM-41 showed complex photoemission signals and this study allows, for the first time, the distinction of the emission signals of tetrahedral Ti9IV) ions from those due to silica surface centres.

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Authors and Affiliations

  1. Dipartimento di Chimica IFM, Università de Torino, via P. Giuria, 7, I-10125, Torino, Italy

    E. Gianotti, V. Dellarocca, G. Martra & S. Coluccia

  2. Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, 464-8603, Nagoya, Japan

    H. Yoshida

  3. Dipartimento Scienze e Tecnologie Avanzate, Università del Piemonte Orientale “A. Avogadro”, c.so Borsalino 54, 15100, Alessandria, Italy

    L. Marchese

Authors
  1. E. Gianotti
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  2. H. Yoshida
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  3. V. Dellarocca
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  4. L. Marchese
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  5. G. Martra
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  6. S. Coluccia
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Correspondence to E. Gianotti.

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Gianotti, E., Yoshida, H., Dellarocca, V. et al. Photoluminescence study of mesoporous MCM-41 and Ti-grafted MCM-41. Res. Chem. Intermed. 29, 681–689 (2003). https://doi.org/10.1163/156856703322601708

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  • DOI: https://doi.org/10.1163/156856703322601708

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