Calculation of the Minimum Pressure, p‐T Diagrams, and Solidus of ZnTe

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© 1969 ECS - The Electrochemical Society
, , Citation A. S. Jordan and R. R. Zupp 1969 J. Electrochem. Soc. 116 1264 DOI 10.1149/1.2412294

1945-7111/116/9/1264

Abstract

The partial pressures of the components, and for the Zn‐Te system were evaluated along the liquidus curve on the basis of previously derived activities for a regular associated solution. Results are in good agreement with available experimental data. The minimum pressure of was calculated from and the free energy function, , of and the component gases. The thermodynamic data for needed for these calculations have also been critically reassessed or evaluated. By a combination of the measurements of Thomas and Sadowski with the values of along the liquidus, a retrograde solidus for was calculated. The calculated maximum solid solubility of Te in is approximately .

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10.1149/1.2412294