Electrochemical Behavior of Fluorinated Fullerenes  C 60 F x and  C 70 F x

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© 1996 ECS - The Electrochemical Society
, , Citation Ning Liu et al 1996 J. Electrochem. Soc. 143 L214 DOI 10.1149/1.1837091

1945-7111/143/9/L214

Abstract

Electrochemical properties of and have been studied by cyclic voltammetry (CV) in containing 0.1 M tetrabutylammonium hexafluorophosphate . The electrochemical reductions of are reported for the first time. The reduction potential of is more positive than that of by 1.57 V. The differences in electrochemical properties between and are parallel to the differences between and . Based on the relationship between the reduction potential and electron affinity (Ea), the Ea of is estimated to be ca. 4.42 eV, which is 1.76 eV larger than that of .

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10.1149/1.1837091